Naphthyldiamine diradical dications. Triplet dications of 2,7- bis(amino)naphthalene and 2,7-bis(phenylenediamino)naphthalene [2]

Journal of the American Chemical Society

Volumn 121, Issue 30, 1999, Pages 7152-7153

  Selby, Trent D ^a   Blackstock, Silas C ^a  

^a UNIVERSITY OF ALABAMA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATION; DIAMINE DERIVATIVE; NAPHTHALENE DERIVATIVE; PHENYLENEDIAMINE DERIVATIVE;

CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIC POTENTIOMETRY; ELECTRON SPIN RESONANCE; LETTER; STRUCTURE ANALYSIS;

EID: 0033523231     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja984169c     Document Type: Letter

References (16)

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10. 2: C, 60.67; H, 4.46; N, 4.42. Found: C, 60.90; H, 4.38; N, 4.56.
11. -) is a shock-sensitive explosive solid and should be handled with due care. For preparation and properties see Murata, Y.; Shine, H. J. J. Org. Chem. 1969, 34, 3368.
12. (a) Evans, D. F. J. Chem. Soc. 1959, 2003.
13. (b) Live, D. H.; Chan, S. I. Anal. Chem. 1970, 42, 791.
14. eff values for the cations and dications.
15. Borden, W. T. Diradicals; Wiley: New York, 1982; Chapter 1.
16. For a potential application of 2,7-naphthyl-connected polyarylamine polymers as dopable high-spin cluster materials see: Bushby, R. J.; Gooding, D. J. Chem. Soc., Perkin Trans. 2 1998, 1069.