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12
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84920344644
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note
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b proved the relative stereochemistry in each case. (Equation presented)
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13
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0025608552
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14
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84920348387
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The regiochemistry of the acetoxybromides 11 and 12 was proved using an HMBC experiment: a crosspeak was observed between the carbonyl carbon and CHOAc
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The regiochemistry of the acetoxybromides 11 and 12 was proved using an HMBC experiment: a crosspeak was observed between the carbonyl carbon and CHOAc.
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15
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84920344162
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The acetoxybromides 11 and 12 and the hydroxybromides 17 and 19 epimerised on standing
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The acetoxybromides 11 and 12 and the hydroxybromides 17 and 19 epimerised on standing.
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16
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37049131258
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(a) Golding, B. T.; Hall, D. R.; Sakrikar, S. J. Chem Soc., Perkin Trans. 1 1973, 1214;
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18
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84920352415
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note
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b in the oxetane 18. (Equation presented)
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-
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20
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84920354533
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note
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cHex) and 1.30 (3H, d, J=7.2, Me).
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22
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0025010836
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(b) Wilson, F. X.; Fleet, G. W. J.; Vogt, K.; Wang, Y; Witty, D. R.; Choi, S.; Storer, R.; Meyers, P. L.; Wallis, C. J. Tetrahedron Lett. 1990, 31, 6931.
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Choi, S.6
Storer, R.7
Meyers, P.L.8
Wallis, C.J.9
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