Circular dichroism at the edge: Large X-ray natural CD in the 1s → 3d pre-edge feature of 2[Co(en)3Cl3]·NaCl·6H2O [12]

Journal of the American Chemical Society

Volumn 121, Issue 43, 1999, Pages 10233-10234

  Stewart, Brian ^a   Peacock, Robert D ^b   Alagna, Lucilla ^c   Prosperi, Tommaso ^c   Turchini, Stefano ^c   Goulon, José ^d   Rogalev, Andrei ^d   Goulon Ginet, Chantal ^e  

^a UNIVERSITY OF THE WEST OF SCOTLAND   (United Kingdom)

^b UNIVERSITY OF GLASGOW   (United Kingdom)

^c CNR   (Italy)

^d EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

^e UNIV GRENOBLE ALPES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE DERIVATIVE; COBALT DERIVATIVE; SODIUM CHLORIDE; WATER;

ABSORPTION SPECTROPHOTOMETRY; CHEMICAL STRUCTURE; CIRCULAR DICHROISM; CONTROLLED STUDY; ENANTIOMER; LETTER; MATHEMATICAL ANALYSIS;

EID: 0033520696     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9920720     Document Type: Letter

References (30)

1. Alagna, L.; Prosperi, T.; Turchini, S.; Goulon, J.; Rogalev, A.; Goulon-Ginet, C.; Natoli, C. R.; Peacock, R. D.; Stewart, B. Phys. Rev. Lett. 1998, 80, 4799-4802.
2. Goulon, J.; Goulon-Ginet, C.; Rogalev, A.; Gotte, V.; Malgrange, C.; Brouder, C.; Natoli, C. R. J. Chem. Phys. 1998, 108, 6394-6403.
3. (a) Saito, Y.; Nakatsu, K.; Shiro, M.; Kuroya, H. Acta Crystallogr. 1954, 7, 636.
4. (b) Saito, Y.; Nakatsu, K.; Shiro, M.; Kuroya, H. Acta Crystallogr. 1955, 8, 729-730.
5. (a) Mathieu, J.-P. C. R. Acad. Sci. 1953, 236, 2395-2397.
6. (b) McCaffery, A. J.; Mason, S. F. Mol. Phys. 1963, 6, 359-371.
7. (c) Peacock, R. D.; Stewart, B. Coord. Chem. Rev. 1982, 46, 129-157.
8. Moffit, W. J. J. Chem. Phys. 1956, 25, 1189-1198.
9. Mason, S. F.; Seal, R. H. Mol. Phys. 1976, 31, 755-775.
10. (a) Strickland, R. W.; Richardson, F. S. Inorg. Chem. 1973, 12, 1025-1036.
11. (b) Richardson, F. S. Chem. Rev. 1979, 79, 17-38.
12. Evans, R. S.; Schriener, A. F.; Hauser, P. J. Inorg. Chem. 1974, 13, 2185-2192.
13. Westre, T. E.; Kennepohl, P.; DeWitt, J. G.; Hedman, B.; Hodgson, K. O.; Solomon, E. I. J. Am. Chem. Soc 1997, 119, 6297-6314.
14. a line.
15. Goulon, J.; Brookes, N. B.; Gauthier, C.; Goedkoop, J.; Goulon-Ginet, C.; Hagelstein, M.; Rogalev, A. Physica B 1995, 209, 199-202.
16. Siddons, D. P.; Hart, M.; Amemiya, Y.; Hastings, J. B. Phys. Rev. Lett. 1990, 64, 1967-1970.
17. Chiu, Y. N. J. Chem. Phys. 1970, 52, 1042-1053.
18. Buckingham, A. D.; Dunn, M. B. J. Chem. Soc. (A) 1971, 1988-1991.
19. Barron, L. D. Mol. Phys. 1971, 21, 241-246.
20. Pickering, I. J.; George, G. N. Inorg. Chem. 1995, 34, 3142-3152.
21. yz are components of, respectively, the electric dipole, magnetic dipole, and electric quadrupole operators.
22. 24 for the RCHF part. Using an extended basis set, scf convergences were carried out for the ground state and the K-shell ionised cation.
23. Vanquickenborne, L. G.; Coussens, B.; Ceulmans, A.; Pierloot, K. Inorg. Chem. 1991, 30, 2978-2986.
24. Ernst, M. C.; Royer, D. J. Inorg Chem. 1993, 32, 1226-1232.
25. 2O, Farrugia, L. J.; Peacock, R. D.; Stewart, B. Acta Crystallogr., Sect. C, submitted.
26. Dykstra, C. E.; Augspurger, J. D. MAGOPS: one-electron operator program, Quantum Chemistry Program Exchange, program no. 585.
27. Yokoyama, T.; Kosugi, N.; Kuroda, H. Chem. Phys.1986, 103, 101-109; Kosugi, N.; Yokoyama, T.; Asakura, K.; Kuroda, H. Chem. Phys. 1984, 91, 249-256.
28. Yokoyama, T.; Kosugi, N.; Kuroda, H. Chem. Phys.1986, 103, 101- 109; Kosugi, N.; Yokoyama, T.; Asakura, K.; Kuroda, H. Chem. Phys. 1984, 91, 249-256.
29. Schirmer, J.; Braunstein, M.; McKoy, V. Phys. Rev. A 1990, 41, 283-300; Schmitt, A.; Schirmer, J. Chem. Phys. 1992, 164, 1-9.
30. Schirmer, J.; Braunstein, M.; McKoy, V. Phys. Rev. A 1990, 41, 283- 300; Schmitt, A.; Schirmer, J. Chem. Phys. 1992, 164, 1-9.