Stereoselective preparation of phosphine oxides via a 2,3-sigmatropic shift of allylic diphenylphosphinites

Tetrahedron Letters

Volumn 40, Issue 27, 1999, Pages 4981-4984

  Demay, Stéphane ^a   Harms, Klaus ^b   Knochel, Paul ^a  

^a UNIVERSITY OF MUNICH   (Germany)

^b PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPOUND; DIPHENYLPHOSPHINITE DERIVATIVE; PHOSPHINE DERIVATIVE; PHOSPHINE OXIDE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; STEREOCHEMISTRY; SYNTHESIS;

EID: 0033516519     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)00952-1     Document Type: Article

References (24)

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23. X-Rays analysis were performed by measuring intensity data on a Enraf-Nonius CAD-4 diffractometer using graphite-monochromated Cu Kα radiation and the ω scan technique up to θ = 65° for compound 5a and θ = 70° for compound 10b. Lists of atomic coordinates, bond distances, bond angles, torsional angles have been deposited at the Cambridge Crystallographic Data Center (12 Union Road, Cambridge CB2 1EZ, UK). Deposition numbers of 5a and 10b are CCDC 118281 and CCDC 118282.
24. 2/MeOH 60/40/0 to 60/40/5) yielding 5a as a colorless crystalline solid (396 mg, 86 %; mp = 270-274 °C with decomposition).