Isopropyl alcohol dehydration over chrominophosphate catalysts-l. A kinetic study

Journal of the Chinese Institute of Chemical Engineers

Volumn 30, Issue 5, 1999, Pages 421-429

  Kuo, Yung Chih ^a   Chen, Yu Wen ^a  

^a NATIONAL CENTRAL UNIVERSITY   (Taiwan)

Author keywords

Chromia; Chrominophosphate; Dehydration; Isopropyl alcohol; Kinetics

Indexed keywords

ALCOHOLS; CATALYST ACTIVITY; CHROMIUM COMPOUNDS; PRESSURE EFFECTS; PROPYLENE; REACTION KINETICS; WATER;

CHROMINOPHOSPHATE; ISOPROPYL ALCOHOL; LANGMUIR-HINSHELWOOD MODEL;

DEHYDRATION;

ALCOHOL; CATALYST; DEHYDRATION; KINETICS;

EID: 0033493576     PISSN: 03681653     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (21)

1. Aguayo, A. T., A. Romero, and J. Bilbao, "Relationship between the Properties of Silica-Alumina Catalysts and Their Activity for the Dehydration of Alcohols," International Chem. Eng., 27, 650 (1987).
2. Balaz, P., "Influence of Thermal Activation of Chalcopyrite on Activity and Seletivity of Catalytic Decomposition of Isopropyl Alcohol," React. Kinet. Catal. Lett., 36, 287 (1988).
3. Balaz, P. and V. Vrabel, "Catalytic Decomposition of Isopropyl Alcohol on Iron (II) Sulfide," React. Kinet. Catal. Lett., 37, 101 (1988).
4. Bond, G. C., Heterogeneous Catalysis-Principles and Applications, 2nd ed., Oxford, London, UK (1987).
5. Bryant, D. E. and W. L. Kranich, "Dehydration of Alcohols over Zeolite Catalysts," J. Catal., 8, 8 (1967).
6. Butler, J. D., T. C. Poles, and B. T. Wood, "Dehydration of Propanols. A Study of the Dehydration of 1-and 2-Propanol over a Molecular Sieve 13X Catalyst," J. Catal., 16, 239 (1970).
7. Chen, Y. W., W. C. Hsu, C. S. Lin, B. C. Kang, S. T. Wu, L. J. Leu and J. C. Wu, "Hydrodesulfurization Reactions of Residual Oils over CoMo/Alumina-Aluminum Phosphate Catalysts in a Trickle Bed Reactor," Ind. End. Chem. Res., 29, 1830 (1990).
8. Chen, Y. W. and Y. C. Kuo, "The Pore Structure of Chrominophosphate Catalysts," Catal. Lett., 13, 137 (1992).
9. Froment, G. F. and K. B. Bischoff, Chemical Reactor Analysis and Design, John Wiley and Sons (1979).
10. Knozinger, H. and A. Scheglila, "The Dehydration of Alcohols on Alumina XII. Kinetic Isotope Effects in the Olefin Formation From Butanols," J. Catal., 17, 252 (1970).
11. Knozinger, H., H. Buhl, and K. Kochloefl, "The Dehydration of Alcohol on Alumina XIV. Reactivity anf Mechanism," J. Catal., 24, 57 (1972).
12. Li, C. and Y. W. Chen, "Chromia-Chrominum Phosphates as Solid Acid Catalysts," Catal. Lett., 16, 447 (1992).
13. Luy, J. C. and J. M. Parera, "Acidity Control in Alcohol Dehydration," Appl., Catal., 26, 295 (1986).
14. McDaniel, M. P., "Controlling Polymer Properties with the Phillips Chromium Catalysts," Ind. Eng. Chem. Res., 27, 1559 (1988).
15. Moffat, J. B., "Metal Phosphate Catalysts," Catal. Rev. Sci. Eng., 18, 199 (1978).
16. Ouqour, A., G. Coudurier and J. Vedrine, "Acid-Base Properties of Metallic Oxide Catalysts Studied by Conversion of Propan-2-ol," J. Chem. Soc. Faraday Trans. 89, 3151 (1993).
17. Pines, H., J. Hensel, and J. Simonik, "Reactions of Alcohols. VI. Dehydration of Primary Alkanols to Ethers in a Flow System over Supported Nickel Catalysts in the Presence of Hydrogen. Effect of Supports," J. Catal., 24, 206 (1972).
18. Pines, H. and J. Simonik, "Reactions of Alcohols VIII. Dehydration of Binary Mixtures of Primary Alkanols over Nickel-Cab-O-Sil Catalysts. Synthesis of Mixed Ethers," J. Catal., 24, 220 (1972).
19. Renkin, E. M., "Filtration, Diffusion and Molecular Sieving through Porous Cellulose Membranes," J. Gen. Physiol., 38, 225 (1954).
20. Satterfield, C. N., Heterogeneous Catalysis in Practice, 1st ed., McGraw-Hill, New York (1980).
21. Tanabe, K., "Solid Acids and Bases," Academic Press, New York, USA (1970).