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Volumn 21, Issue , 2000, Pages 139-162

Mechanisms of inversion at pyramidal sulfur atoms in three-coordinate sulfur compounds

Author keywords

Dissociative mechanism; Inversion mechanism; Kinetic parameter; Nondissociative mechanism; Pyramidal sulfur atom; Stereodynamics; Sulfur inversion

Indexed keywords


EID: 0033482516     PISSN: 09156151     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (15)

References (64)
  • 5
    • 0009442564 scopus 로고
    • (Eds.) F. Bernardi, I. G. Csizmadia and A. Mangini Elsevier, Amsterdam
    • S. Oae: in Organic Sulfur Chemistry, (Eds.) F. Bernardi, I. G. Csizmadia and A. Mangini (Elsevier, Amsterdam, 1985), pp. 29.
    • (1985) Organic Sulfur Chemistry , pp. 29
    • Oae, S.1
  • 8
    • 0009314802 scopus 로고
    • (Eds.) H. Ohtaki and H. Yamatera Elsevier, Amsterdam
    • M. Ōki: Structure and Dynamics of Solutions, (Eds.) H. Ohtaki and H. Yamatera (Elsevier, Amsterdam, 1992), pp. 279.
    • (1992) Structure and Dynamics of Solutions , pp. 279
    • Oki, M.1
  • 17
    • 21144456444 scopus 로고    scopus 로고
    • note
    • For example, the coalescence method and the band width analysis are known as simplified techniques to obtain rate constants. The former gives an approximate value of the rate constants only at the coalescence temperature.
  • 18
    • 21144455099 scopus 로고    scopus 로고
    • note
    • Computer programs for the simulation of lineshape changes are available from QCPE, Indiana University, Bloomington. For example, DNMR3 (QCPE #165) by D. Kleier and G. Binsch, and DNMR5 (QCPE #365) by D. S. Stephenson and G. Binsch.
  • 23
    • 21144440469 scopus 로고    scopus 로고
    • Ref. 10, Chap. 4
    • Ref. 10, Chap. 4.
  • 32
    • 33846576141 scopus 로고
    • (e) S. Rozak, K. Strasburger and H. Chojnacki: J. Mol. Struct. 227 187 (1991) [3-21G 82, 6-31G 77, 6-31G* 129, 6-31G**+2d 135, MP2/6-31G* 133]. Values in brackets are inversion barriers in kJ/mol determined with the calculated methods.
    • (1991) J. Mol. Struct. , vol.227 , pp. 187
    • Rozak, S.1    Strasburger, K.2    Chojnacki, H.3
  • 35
    • 21144451554 scopus 로고    scopus 로고
    • note
    • The Gaussian 98 program is commercially available from Gaussian, Inc.
  • 41
    • 21144439204 scopus 로고    scopus 로고
    • Unpublished results
    • 2v) structures are 135 and 945 kJ/mol, respectively, above that of the pyramidal structure at the initial state at the HF/6-31G* level.
    • Toyota, S.1    Sakaue, T.2
  • 43
    • 0004018410 scopus 로고
    • VCH, Cambridge
    • T(30) are often used as a scale of solvent polarity. Gutman's donor number (DN) is a scale of solvent donicity. The details of these solvent parameters are described in C. Reichardt: Solvents and Solvent Effects in Organic Chemistry, 2nd ed. (VCH, Cambridge, 1988).
    • (1988) Solvents and Solvent Effects in Organic Chemistry, 2nd Ed.
    • Reichardt, C.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.