Oxidative fluorination of P-H bonds in the coordination sphere of tungsten

Comptes Rendus de l'Academie des Sciences - Series IIc: Chemistry

Volumn 2, Issue 14, 1999, Pages 701-704

  Bienewald, Frank ^a   Tran Huy, Ngoc Hoa ^a   Mathey, François ^a  

^a CNRS   (France)

Author keywords

Fluorophosphines; Pentacarbonyltungsten complexes; Phosphenium ions; Primary and secondary phosphines

Indexed keywords

EID: 0033451617     PISSN: 13871609     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1387-1609(00)88464-9     Document Type: Article

References (17)

1. Recent examples: a) Goerlich J.R., Weiss J.-V., Jones P.G., Schmutzler R., Phosphorus, Sulfur, and Silicon, 66 (1992) 223; b) Fabel M., Willis A.C., Wild S.B., Angew. Chem. Int. Ed. Eng. 33 (1994) 1835.
2. Recent examples: a) Goerlich J.R., Weiss J.-V., Jones P.G., Schmutzler R., Phosphorus, Sulfur, and Silicon, 66 (1992) 223; b) Fabel M., Willis A.C., Wild S.B., Angew. Chem. Int. Ed. Eng. 33 (1994) 1835.
3. a) Riesel L., Haenel J., Z. Anorg. Allg. Chem. 603 (1991) 145;
4. b) Minkwitz R., Konrath A., Lennhoff D., Preut H., Z. Anorg. Allg. Chem. 620 (1994) 509.
5. See for example: Schumann H., Eguren L., Z. Naturforsch. B 46 (1991) 887.
6. Recent examples: a) Heuer L, Schmutzler R, J. Fluorine Chem. 39 (1988) 197; b) Schmutzler R., Heuer L., Schomburg D., Polyhedron 10 (1991) 2737; c) Meyer T.G., Jones P.G., Schmutzler R., Z. Naturforsch. B 48 (1993) 875.
7. Recent examples: a) Heuer L, SchmutzleR R, J. Fluorine Chem. 39 (1988) 197; b) Schmutzler R., Heuer L., Schomburg D., Polyhedron 10 (1991) 2737; c) Meyer T.G., Jones P.G., Schmutzler R., Z. Naturforsch. B 48 (1993) 875.
8. Recent examples: a) Heuer L, SchmutzleR R, J. Fluorine Chem. 39 (1988) 197; b) Schmutzler R., Heuer L., Schomburg D., Polyhedron 10 (1991) 2737; c) Meyer T.G., Jones P.G., Schmutzler R., Z. Naturforsch. B 48 (1993) 875.
9. For a recent study of the disproportionation of fluorophosphines, see: Schmutzler R., Heuer L., Schomburg D., Phosphorus, Sulfur, and Silicon 83 (1993) 149.
10. Review: Sanchez M., Mazières M.-R., Lamandé L., Wolf R., in: Regitz M., Scherer O.J. (Eds.), Multiple Bonds and Low Coordination in Phosphorus Chemistry, Thieme, Stuttgart, 1990, p. 129.
11. a) Hockless D.C.R., McDonald M.A., Pabel M., Wild S.B., J. Chem. Soc. Chem. Comm. (1995) 257;
12. b) Hockless D.C.R., McDonald M.A., Pabel M., Wild S.B., J. Organomet. Chem. 529 (1997) 189.
13. Snow S.S., Jiang D.X., Parry R.W., Inorg. Chem. 26 (1987) 1629.
14. a) Sommer L.H., Baumann D.L., J. Am. Chem. Soc. 91 (1969) 7076;
15. b) Chojnowski J., Fortiniak W., Stanczyk W., J. Am. Chem. Soc. 109 (1987) 7776.
16. The initial product is probably the N-protonated salt. Protonation of 10 with triflic acid results in a product with a similar chemical shift (96 ppm) which seems to be more stable.
17. Marinetti A., Mathey F., Organometallics 1 (1982) 1488.