First example of a silica gel-supported optically active Mn(III)-salen complex as a heterogeneous asymmetric catalyst in the epoxidation of olefins

Tetrahedron Asymmetry

Volumn 10, Issue 20, 1999, Pages 3883-3886

  Pini, Dario ^a   Mandoli, Alessandro ^a   Orlandi, Simonetta ^a   Salvadori, Piero ^a  

^a CNR   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; MANGANESE; SILICA GEL;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; ENANTIOMER; EPOXIDATION; OPTICAL ROTATION; PRIORITY JOURNAL;

EID: 0033433980     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(99)00426-7     Document Type: Article

References (17)

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16. The proposed structure for 4a and 4b, with both silyloxyl groups anchored to two silica surfaces, is intended as a pictorial representation: at present no evidence of the double linking of the Mn(III)-salen derivative to the silica gel is available.
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