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LUMO energies of 1(trifluoromethyl phenyl ketone), 2(difluoromethyl phenyl ketone), and difluoroenol silyl ether 3 were estimated to be -0.97eV, - 0.87eV, and -0.41eV, respectively, suggesting different reducabilities between 1 and 3, but similar ones between 1 and 2.
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