Synthesis and structure of triphenylscandium-bis(tetrahydrofuran)

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 625, Issue 11, 1999, Pages 1777-1778

  Putzer, Markus A ^a,b   Bartholomew, Glenn P ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b BAYER AG   (Germany)

Author keywords

Ab initio calculations; Aryl complex; Crystal structure; Scandium complex

Indexed keywords

EID: 0033411527     PISSN: 00442313     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3749(199911)625:11<1777::AID-ZAAC1777>3.0.CO;2-J     Document Type: Article

References (13)

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6. 2 = 0.1309, GOF = 1.014. Detailed crystallographic data have been deposited with the Cambridge Crystallographic Data Center. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: int.code+(12 23)3 36-0 33; e-mail: teched@chemcrys.cam.ac.uk) on quoting the depository number CCDC 125063.
7. 0 metal complexes, the more electron-withdrawing ligands prefer to occupy the axial positions in a trigonal-bipyramidal coordination sphere. For details see: A. R. Rossi, R. Hoffmann, Inorg. Chem. 1975, 14, 365.
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10. Intermolecular distances (Å): H(2) ⋯ H(14) 2.560, H(18) ⋯ H(8) 2.572, H(12) ⋯ H(6) 2.485.
11. 3 using Hartree-Fock model with the 3-21G* basis set.
12. Inorganic Syntheses, J. P. Fackler, Jr. (ed), John Wiley & Son, New York, 1982, Vol. 21, p. 139.
13. M. Schlosser, V. Ladenberger, J. Organomet. Chem. 1967, 8, 193.