-
1
-
-
33751553785
-
-
1 C. Bravo, P. Hervés and J. R. Leis, J. Phys. Chem., 1990, 94, 8816.
-
(1990)
J. Phys. Chem.
, vol.94
, pp. 8816
-
-
Bravo, C.1
Hervés, P.2
Leis, J.R.3
-
2
-
-
0008973458
-
-
eds. M. Grätzel and K. Kalyanasundaram, Marcel Dekker, New York, ch. 2.
-
2 (a) C. A. Bunton, in Kinetics and Catalysis in Microheterogeneus Systems, eds. M. Grätzel and K. Kalyanasundaram, Marcel Dekker, New York 1991, vol. 38, ch. 2.
-
(1991)
Kinetics and Catalysis in Microheterogeneus Systems
, vol.38
-
-
Bunton, C.A.1
-
3
-
-
0000788917
-
-
eds. K. L. Mittal and E. J. Fendler, Plenum Press, New York
-
(b) H. Chaimovich, F. M. V. Alexio, I. M. Cuccovia, D. Zanette and F. H. Quina, in Solution Behavior of Surfactants: Theorecal and Applied Aspects, eds. K. L. Mittal and E. J. Fendler, Plenum Press, New York, 1982, vol. 2, p. 949.
-
(1982)
Solution Behavior of Surfactants: Theorecal and Applied Aspects
, vol.2
, pp. 949
-
-
Chaimovich, H.1
Alexio, F.M.V.2
Cuccovia, I.M.3
Zanette, D.4
Quina, F.H.5
-
4
-
-
2142657114
-
-
3 E. Pelizzetti, E. Fisicaro, C. Minero, A. Sassi and H. Hidaka, J. Phys. Chem., 1991, 95, 1991.
-
(1991)
J. Phys. Chem.
, vol.95
, pp. 1991
-
-
Pelizzetti, E.1
Fisicaro, E.2
Minero, C.3
Sassi, A.4
Hidaka, H.5
-
8
-
-
58149405233
-
-
7 Y. Ohsawa, Y. Shimazki and S. Aoyagui, J. Electroanal. Chem., 1980, 114, 235.
-
(1980)
J. Electroanal. Chem.
, vol.114
, pp. 235
-
-
Ohsawa, Y.1
Shimazki, Y.2
Aoyagui, S.3
-
10
-
-
33847087712
-
-
9 See for example: (a) C. A. Bunton, L. S. Romsted and L. Sepulveda, J. Phys. Chem., 1980, 84, 2611;
-
(1980)
J. Phys. Chem.
, vol.84
, pp. 2611
-
-
Bunton, C.A.1
Romsted, L.S.2
Sepulveda, L.3
-
11
-
-
0000845772
-
-
(b) M. Gonsalves, S. Probst, M. C. Rezende, F. Nome, C. Zucco and D. Zanette, J. Phys. Chem., 1985, 89, 1127;
-
(1985)
J. Phys. Chem.
, vol.89
, pp. 1127
-
-
Gonsalves, M.1
Probst, S.2
Rezende, M.C.3
Nome, F.4
Zucco, C.5
Zanette, D.6
-
13
-
-
33751157055
-
-
(d) M. A. B. Marin, F. Nome, D. Zanette, C. Zucco and L. S. Romsted, J. Phys. Chem., 1995, 99, 10879.
-
(1995)
J. Phys. Chem.
, vol.99
, pp. 10879
-
-
Marin, M.A.B.1
Nome, F.2
Zanette, D.3
Zucco, C.4
Romsted, L.S.5
-
17
-
-
0345917124
-
-
12 J. N. Brönsted, Z. Phys. Chem., 1922, 102, 169 and 1925, 115, 337 .
-
(1925)
Z. Phys. Chem.
, vol.115
, pp. 337
-
-
-
18
-
-
0004165225
-
-
McGraw-Hill, London
-
13 See for example: K. J. Laidler, Chemical Kinetics, McGraw-Hill, London, 1965, p. 219.
-
(1965)
Chemical Kinetics
, vol.219
-
-
Laidler, K.J.1
-
20
-
-
0000804470
-
-
Academic Press, New York, 2nd edn.
-
15 G. Braver, Handbook of Preparative Inorganic Chemestry, Academic Press, New York, 2nd edn., 1965, vol. 2, p. 1511.
-
(1965)
Handbook of Preparative Inorganic Chemestry
, vol.2
, pp. 1511
-
-
Braver, G.1
-
21
-
-
0009052659
-
-
4-Cyanopyridine was purified by recrystallization in a 1:1 ethanol-water mixture using standard procedures
-
16 4-Cyanopyridine was purified by recrystallization in a 1:1 ethanol-water mixture using standard procedures.
-
-
-
-
22
-
-
37049099006
-
-
17 R. Juretic, D. Paulovic and S. Asperger, J. Chem. Soc., Dalton Trans., 1979, 2029.
-
(1979)
J. Chem. Soc., Dalton Trans.
, pp. 2029
-
-
Juretic, R.1
Paulovic, D.2
Asperger, S.3
-
23
-
-
0008972379
-
-
The first term on the right hand side of eqn. (12) would correspond to the Debye-Hückel law of variation of activity coefficient. The Φ([T]) term corresponds to the so-called "excluded volume effects". This term corrects the approximation used in obtaining the Debye-Hückel equation: in deriving this equation all the ions in the solution, except the central one, are considered as point charges. This is a good approximation when one is dealing with dilute solutions of small ions. Otherwise, it is necessary to correct the Debye-Hückel equation because of the effects derived from this approximation. In fact, when the excluded volume effects are corrected by fitting the experimental data, as in this paper, other effects are also corrected such as those derived from changes in the dielectric constant of the medium caused by the supporting electrolytes (or micelles)
-
18 The first term on the right hand side of eqn. (12) would correspond to the Debye-Hückel law of variation of activity coefficient. The Φ([T]) term corresponds to the so-called "excluded volume effects". This term corrects the approximation used in obtaining the Debye-Hückel equation: in deriving this equation all the ions in the solution, except the central one, are considered as point charges. This is a good approximation when one is dealing with dilute solutions of small ions. Otherwise, it is necessary to correct the Debye-Hückel equation because of the effects derived from this approximation. In fact, when the excluded volume effects are corrected by fitting the experimental data, as in this paper, other effects are also corrected such as those derived from changes in the dielectric constant of the medium caused by the supporting electrolytes (or micelles).
-
-
-
-
24
-
-
0004122451
-
-
Methuen, London
-
19 J. Koryta, J. Dvorak and V. Bohackova, Electrochemistry, Methuen, London, 1970, p. 32.
-
(1970)
Electrochemistry
, pp. 32
-
-
Koryta, J.1
Dvorak, J.2
Bohackova, V.3
-
25
-
-
0008970684
-
-
1/2) ≫ 1 and the term containing the square roots in eqn. (14) has a constant value of A/B
-
1/2) ≫ 1 and the term containing the square roots in eqn. (14) has a constant value of A/B.
-
-
-
|