Pyrolusite surface transformations measured in real-time during the reactive transport of Co(II)EDTA2-

Geochimica et Cosmochimica Acta

Volumn 63, Issue 19-20, 1999, Pages 3049-3057

  Fendorf, Scott ^a   Jardine, Philip M ^b   Patterson, Ronald R ^a   Taylor, David L ^b   Brooks, Scott C ^b  

^a UNIVERSITY OF IDAHO   (United States)

^b OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT; OXIDATION; RADIOACTIVE WASTE;

EID: 0033390580     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(99)00232-X     Document Type: Article

References (53)

1. Amacher M. C. and Baker D. A. Redox reactions involving chromium, plutonium, and manganese in soils, final report DE-ASO8-77DPO4515; Institute for Research on Land & Water Resources, Penn. State University. (1982).
2. 2O at 25°C and one atmosphere total pressure. Am. Mineral. 50:1965;1296-1354.
3. Brooks S.C., Taylor D.L., Jardine P.M. Reactive transport of EDTA-complexed cobalt in the presence of ferrihydrite. Geochim. Cosmochim. Acta. 60:1996;1899-1908.
4. Brown, G. E., Jr. (1990) Spectroscopic studies of chemisorption reaction mechanisms at the oxide-water interfaces. In Mineral-Water Interface Geochemistry (eds. Hochella, M. F. and White, A. F). Reviews in Mineralogy, Vol. 23. pp. 309-364. Mineralogical Society of America, Washington, D.C.
5. Charlet, L., Manceau A.(1993) Structure, formation, and reactivity of hydrous oxide particles: Insights from X-ray absorption spectroscopy. In Environmental Particles (eds. Buffle J. and van Leeuwen H. P.). Vol. 2., pp. 117-164. New York. Lewis Publishers.
6. Chung J.-B., Zasoski R.J., Lim S.-U. Kinetics of chromium(III) oxidation by various manganese oxides. Korean Agri. Chem. Biotech. 37:1994;414-420.
7. Crowther D.L., Dillard J.G., Murray J.W. The mechanism of Co(II) oxidation on synthetic birnessite. Geochim. Cosmochim. Acta. 47:1983;1399-1403.
8. Fendorf S., Jardine P. M., Taylor D. L., Brooks S. C., and Rochette E. A. Auto-inhibition of pyrolusite oxidative reactivity toward Co(II)EDTA. In Kinetics and Mechanisms of Reactions at the Mineral-water Interface (eds D. L. Sparks, and T. Grundl.). ACS Symposium Series 715, pp. 358-371. American Chemical Society, Washington, D.C.
9. 2. I Characterization . Environ. Sci. Technol. 26:1992;79-85.
10. Fendorf S.E., Zasoski R.J., Burau R.G. Competing metal ion influences on chromium(III) oxidation by birnessite. Soil Sci. Soc. Am. J. 57:1993;1508-1515.
11. Foster A.L., Brown G.E. Jr, Parks G.A. X-ray absorption fine-structure spectroscopy study of photocatalyzed, heterogeneous As(III) oxidation on kaolin and anatase. Environ. Sci. Technol. 32:1998;1444-1452.
12. Francis A.J., Iden C.R., Nine B.J., Chang C.K. Characteristics of organics in leachate from the low-level radioactive waste disposal sites. Nucl. Technol. 50:1980;158-163.
13. 3. Soil Sci. Soc. Am. J. 57:1993;47-56.
14. Golden D.C., Dixon J.B., Chen C.C. Ion exchange, thermal transformation, and oxidizing properties of birnessite. Clays Clay Minerals. 34:1986;511-520.
15. Hem J.D. Redox processes at the surfaces of manganese oxide and their effects on aqueous metal ions. Chem. Geol. 21:1978;199-218.
16. Hem J.D. Rates of manganese oxidation in aqueous systems. Geochim. Cosmochim. Acta. 45:1981;1369-1374.
17. Hem J.D., Lind C.J. Nonequilibrium models for predicting forms of precipitated manganese oxides. Geochim. Cosmochim. Acta. 47:1983;2037-2046.
18. Hem J.D., Roberson C.E., Fournier R.B. Stability of βnOOH and manganese oxide deposition from springwater. Water Res. Research. 18:1982;563-570.
19. Jardine P.M., Jacobs G.K., O'Dell J.D. Unsaturated transport processes in undisturbed heterogeneous porous media II. Co-contaminants . Soil Sci. Soc. Am. J. 57:1993;954-962.
20. Jardine P.M., Taylor D.L. Kinetics and mechanisms of cobalt(II)EDTA oxidation by pyrolusite. Geochim. Cosmochim. Acta. 59:1995;4193-4203.
21. Johnson C.A., Xyla A.G. The oxidation of chromium(III) to chromium(VI) on the surface of manganate (γMnOOH). Geochim Cosmochim Acta. 55:1991;2861-2866.
22. Junta J.L., Hochella M.F. Jr. Manganese (II) oxidation at mineral surfaces A microscopic and spectroscopic study . Geochim. Cosmochim. Acta. 58:1994;4985-4999.
23. Killey R.W.D., McHugh J.O., Champ D.R., Cooper E.L., Young J.L. Subsurface cobalt-60 migration from a low-level waste disposal pit. Environ. Sci. Technol. 18:1984;148-157.
24. 2 Effect of co-solutes on initial and quasi-steady-state kinetics . Environ. Sci. Technol. 31:1997;2642-2649.
25. Kostka J.E., Luther G.W. III, Nealson K.H. Chemical and biological reduction of Mn(III)-pyrophosphate complexes Potential importance of dissolved Mn(III) as an environmental oxidant . Geochim. Cosmochim. Acta. 59:1995;885-894.
26. Manceau A., Combes J.M. Structure of Mn and Fe oxides and oxyhydroxides A topological approach by EXAFS . Phy. Chem. Minerals. 15:1988;283-295.
27. Marcus M.A., Flood W. A procedure for the manufacture of EXAFS samples of concentrated materials. Rev. Sci. Instrum. 62:1991;839-840.
28. McBride M.B. Oxidation of 1, 2- and 4-dihydroxybenzene by birnessite in acidic aqueous suspension. Clays Clay Minerals. 37:1989;479-486.
29. Means J.L., Crerar D.A., Borscik M.P., Duguid J.O. Adsorption of Co and selected actinides by Mn and Fe oxides in soils and sediments. Geochim. Cosmochim. Acta. 42:1978;1763-1773.
30. Moore J.W., Pearson R.G. Kinetics and Mechanisms. 1981;Wiley and Sons, NY.
31. Murray J.W., Dillard J.G. The oxidation of cobalt(II) adsorbed on manganese dioxide. Geochim. Cosmochim. Acta. 43:1979;781-787.
32. Murray J.W., Dillard J.G., Giovanoli R., Moers H., Stumm W. Oxidation of Mn(II) Initial mineralogy, oxidation state and aging . Geochim. Cosmochim. Acta. 49:1985;463-470.
33. Murray, D. J., Healy T. W., Fuerstenau D. W. (1968) The adsorption of aqueus metal on colloidal hydrous manganese oxide. In Adsorption from Aqueous Solution (eds. W. J. Weber, Jr. and E. Matijevic). ACS Series 79. American Chemical Society, Washington, D.C.
34. 2 precipitation. Am. Mineral. 83:1998;305-315.
35. Olsen C.R., Lowry P.D., Lee S.Y., Larsen I.L., Cutshall N.H. Geochemical and environmental processes affecting radionuclide migration from a formerly used seepage trench. Geochim. Cosmochim. Acta. 50:1986;593-607.
36. Oscarson D.W., Huang P.M., Defosse C., Herbillon A. Oxidative power of Mn(IV) and Fe(III) oxides with respect to As(III) in terrestrial and aquatic environments. Nature. 291:1981;50-51.
37. Pickering I.J., Brown G.E. Jr, Tokunaga T.K. Quantitative speciation of selenium in soils using x-ray absorption spectroscopy. Environ. Sci. Technol. 29:1995;2456-2459.
38. Pourbaix M. Atlas of Electrochemical Equilibria in Aqueous Solution. 1974;Nat. Assoc. Corrosion Engineers.
39. Schulze D.G., McCay-Buis T., Sutton S.R., Huber D.M. Determination of manganese oxidation states in soils using X-ray absorption near-edge structure (XANES) spectroscopy. Soil Sci. Soc. Am. J. 59:1995;1540-1548.
40. Stern E.A., Heald S.M. X-ray filter assembly for fluorescence measurements of x-ray absorption fine structure. Rev. Sci. Intrum. 50:1979;1579-1582.
41. Stöhr, J. 1992. NEXAFS Spectroscopy. Springer-Verlag, NY/Berlin.
42. Stone A.T. Reductive dissolution of manganese(III)/IV) oxides by substituted phenols. Environ. Sci. Technol. 21:1987;979-988.
43. Stone A.T., Ulrich H.-J. Kinetics and reaction stoichiometry in the reductive dissolution of manganese(IV) dioxide and Co(III) oxide by hydroquinone. J. Colloid Interface Sci. 132:1989;509-522.
44. Stone A.T., Morgan J.J. Reduction and dissolution of manganese(III) and manganese(IV) oxides by organics. 2. Survey of the reactivity of organics. Environ. Sci. Technol. 18:1984;617-624.
45. Szecsody J.E., Zachara J.M., Bruckhart P.L. Adsorption-dissolution reactions affecting the distribution and stability of Co(II)EDTA in iron oxide-coated sand. Environ. Sci. Technol. 28:1994;1706-1716.
46. Taylor D.L., Jardine P.M. Analysis of cobalt(II)EDTA and cobalt(III)EDTA in pore water by ion chromatography. J. Environ. Qual. 24:1995;789-792.
47. Vairavamurthy A., Zhou W., Eglinton T., Manowitz B. Sulfonates A novel class of organic sulfur compounds in marine sediments . Geochim. Cosmochim. Acta. 58:1994;4681-4687.
48. Waldo G.S., Carlson R.M.K., Moldowan J.M., Peters D.E., Penner-Hahn J.E. Sulfur speciation in heavy petroleums Information from x-ray absorption near-edge structure . Geochim. Cosmochim. Acta. 55:1991;801-814.
49. 2 Oxidation product and factors affecting oxidation rate . Environ. Sci. Technol. 29:1995;1504-1510.
50. Xue Y., Traina S.J. Oxidation kinetics of Co(II)-EDTA in aqueous and semi-aqueous goethite suspensions. Environ. Sci. Technol. 30:1996;1975-1981.
51. Xyla A.G., Sulzberger B., Luther G.W. III, Hering J.G., Van Cappellen P., Stumm W. Reductive dissolution of manganese(III,IV) (hydr)oxides by oxalate The effect of pH and light . Langmuir. 8:1992;95-103.
52. 2- complexes in subsurface materials with iron and manganese oxide grain coatings. Geochim. Cosmochim. Acta. 5:1995;4449-4463.
53. Zachara J.M., Smith S.C., Kuzel L.S. Adsorption and dissociation of Co-EDTA complexes in iron oxide-containing subsurface sands. Geochim. Cosmochim. Acta. 59:1995;4825-4839.