High-temperature diffusion of oxygen in synthetic diopside measured by nuclear reaction analysis

Mineralogical Magazine

Volumn 63, Issue 5, 1999, Pages 673-686

  Pacaud, L ^a   Ingrin, J ^a   Jaoul, O ^a  

^a CNRS   (France)

Author keywords

Diopside; Nuclear Reaction Analysis; Oxygen diffusion; Premelting

Indexed keywords

DIFFUSION; DIOPSIDE; OXYGEN; PYROXENE;

EID: 0033389223     PISSN: 0026461X     EISSN: None     Source Type: Journal    
DOI: 10.1180/002646199548835     Document Type: Article

References (34)

1. 3 spinels. J. Amer. Ceram. Soc., 66, C131-2.
2. Azough, F. and Freer, R. (1998) An ion microprobe study of cation diffusion in diopside with applications to thermobarometry. Abstract, Mineralogical Society (London) Winter Meeting: Microbeam Techniques in the Geosciences, London, Jan. 1998.
3. Béjina, F. and Jaoul, O. (1996) Silicon self-diffusion in quartz and diopside measured by nuclear microanalysis methods. Phys. Earth Planet. Int., 97, 145-62.
4. Cawley, J. D. (1984) Oxygen diffusion in alpha alumina. Unpubl. PhD, Case Western Reserve University, 73 pp.
5. Connolly, C. and Muehlenbachs, K. (1988) Contrasting oxygen diffusion in nepheline, diopside and other silicates and their relevance to isotopic systematics in meteorites. Geochim. Cosmochim. Acta, 52, 1585-91.
6. Dimanov, A. and Ingrin, J. (1995) Premelting and high-temperature diffusion of Ca in synthetic diopside: an increase of the cation mobility. Phys. Chem. Min., 22, 437-42.
7. Dimanov, A., Jaoul, O. and Sautter, V. (1996) Calcium self-diffusion in natural diopside single crystals. Geochim. Cosmochim. Acta, 60, 21, 4095-106.
8. Elphick, S.C. and Graham, C.M. (1988) The effect of hydrogen on oxygen diffusion in quartz: Evidence for fast proton transients? Nature, 335, 243-5.
9. Elphick, S.C. and Graham, C.M. (1990) Hydrothermal oxygen diffusion in diopside at 1 kb, 900-1200°C, a comparison with oxygen diffusion in forsterite, and constraints on oxygen isotope disequilibrium in peridotite nodules. Terra Abstr., 7, 72.
10. Farver, J.R. (1989) Oxygen self-diffusion in diopside with application to cooling rate determinations. Earth Planet. Sci. Lett., 92, 386-96.
11. Farver, J.R. and Yund, R.A. (1990) The effect of hydrogen, oxygen and water fugacity on oxygen diffusion in alkali feldspar. Geochim. Cosmochim. Acta, 54, 2953-64.
12. Farver, J.R. and Yund, R.A. (1991) Oxygen diffusion in quartz: dependence on temperature and water fugacity. Chem. Geol., 90, 55-70.
13. 4 olivines. Phys. Chem. Min., 18, 469-79.
14. Gérard, O. and Jaoul, O. (1989) Oxygen diffusion in San Carlos olivine. J. Geophys. Res., 94, 4119-28.
15. Giletti, B.J. (1985) The nature of oxygen transport within minerals in the presence of hydrothermal water and the role of diffusion. Chem. Geol., 53, 197-206.
16. Giletti, B.J. and Yund, R.A. (1984) Oxygen diffusion in quartz. J. Geophys. Res., 89, 4039-46.
17. Huebner, J.S. and Voigt, D.E. (1988) Electrical conductivity of diopside: Evidence for oxygen vacancies. Amer. Mineral., 73, 1235-54.
18. Ingrin, J., Latrous, K., Doukhan, J.C. and Doukhan, N. (1989) Water in diopside: an electron microscopy and infrared spectroscopy study. Eur. J. Mineral., 1, 327-41.
19. 2 precipitation. J. Geophys. Res., 99, 9423-39.
20. Jaoul, O., Froidevaux, C., Durham, W.B. and Michaut, M. (1980) Oxygen self-diffusion in forsterite: implications for the high-temperature creep mechanism. Earth Planet. Sci. Lett., 47, 391-7.
21. 18O diffusion in magnesium orthosilicate by nuclear microanalysis. J. Geophys. Res., 88, 613-24.
22. Jaoul, O., Sautter, V. and Abel, F. (1991) Nuclear microanalysis: a powerful tool for measuring low atomic diffusivity with mineralogical applications. In Diffusion, Atomic Ordering, and Mass Transport: Selected Topics in Geochemistry (J. Ganguly, ed.). Advances in Physical Geochemistry, 8, pp. 198-220. Springer-Verlag, Berlin, Heidelbeg, New York.
23. L'Hoir, A., Schmaus, D., Cawley, J. and Jaoul, O. (1981) Depth profiling light nuclei in single crystals: a combined nuclear reaction and RBS technique to minimize unwanted channeling effects. Nucl. Inst. Methods, 191, 357-66.
24. Reddy, K.P.R., Oh, S.M., Major, Jr., L.D. and Cooper, A.R. (1980) Oxygen diffusion in forsterite. J. Geophys. Res., 85, 322-6.
25. 2. J. Geophys. Res., 96, 445-56.
26. Richet, P., Ingrin, J., Mysen, B.O., Courtial, P. and Gillet, P. (1994) Premelting effects in minerals: an experimental study. Earth Planet. Sci. Lett., 121, 589-600.
27. Richet, P., Mysen, B.O. and Ingrin, J. (1998) High-Temperature X-ray diffraction and Raman spectroscopy of diopside and pseudowollastonite. Phys. Chem. Min., 25, 401-14.
28. Ryerson, F.J. and McKeegan, K.D. (1994) Determination of oxygen self-diffusion in akermanite, anorthite, diopside, and spinel: Implication for oxygen isotopic anomalies and the thermal histories of Ca-Al-rich inclusions. Geochim. Cosmochim. Acta, 58, 3713-34.
29. Sneeringer, M., Hart, S.R. and Shimizu, N. (1984) Strontium and samarium diffusion in diopside. Geochim. Cosmochim. Acta, 48, 1589-608.
30. Stocker, R.L. (1978) Influence of oxygen pressure on defect concentrations in olivine with a fixed cationic ratio. Phys. Earth Planet. Inter., 17, 118-29.
31. Stocker, R.L. and Smyth, D.M. (1978) Effect of enstatite activity and oxygen partial pressure on the point-defect chemistry of olivine. Phys. Earth Planet. Int., 16, 145-56.
32. Weast, R.C. and Astle, M.J. (1979) Handbook of Chemistry and Physics. CRC Press Inc., Boca Raton, Florida.
33. York, D. (1966) Least-squares fitting of a straight line. Canad. J. Phys., 44, 1079-86.
34. Ziegler J.F. and Biersack, J.P. (1985) The Stopping and Range of Ions in Solids. Pergamon Press, New York.