Siderophile geochemistry of Ga, Ge, and Sn: Cationic oxidation states in silicate melts and the effect of composition in iron-nickel alloys

Geochimica et Cosmochimica Acta

Volumn 63, Issue 17, 1999, Pages 2667-2677

  Capobianco, Christopher J ^a   Drake, Michael J ^a   De'Aro, Jessie ^a  

^a UNIVERSITY OF ARIZONA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COSMOCHEMISTRY; GALLIUM; GERMANIUM; SIDEROPHILE ELEMENT; SILICATE MELT; TIN;

EID: 0033373119     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(99)00085-X     Document Type: Article

References (30)

1. Capobianco C.J., Jones J.H., Drake M.J. Metal/silicate thermochemistry at high temperatures Magma oceans and the "excess siderophile element" problem of the Earth's upper mantle . J. Geophys. Res. Planets. 98:1993;5433-5443.
2. Cheng W., Ganguly J. Some aspects of multicomponent excess free energy models with subregular binaries. Geochim. Cosmochim Acta. 58:1994;3763-3767.
3. Colson R.O. Solubility of neutral nickel in silicate melts and implications for the Earth's siderophile element budget. Nature. 357:1992;65-68.
4. de Boer F.R., Boom R., Mattens W.C.M., Miedema A.R., Niessen A.K. Cohesion in Metal; Cohesion and Structure. 1989;North-Holland.
5. Drake M.J., Newsom H.E., Reed S.J.B., Enright M.C. Experimental determination of the partitioning of gallium between solid iron metal and synthetic basaltic melt Electron and ion microprobe study . Geochim. Cosmochim. Acta. 48:1984;1609-1615.
6. Ehlers K., Grove T.L., Sisson T.W., Recca S.I., Zervas D.A. The effect of oxygen fugacity on the partitioning of nickel an cobalt between olivine, silicate melt, and metal. Geochim. Cosmochim. Acta. 56:1992;3733-3742.
7. Gokcen N.A. Statistical Thermodynamics of Alloys. 1986;Plenum.
8. Hillgren V.J. Partitioning behavior of Ni, Co, Mo, and W between basaltic liquid and Ni-rich metal Implications for the origin of the Moon and lunar core formation . Geophys. Res. Lett. 18:1991;2077-2080.
9. Hillgren V.J. Partitioning behavior of moderately siderophile elements in Ni-rich systems Implications for the Earth and Moon. Ph.D. thesis . 1993;University of Arizona.
10. Jones J.H., Drake M.J. Geochemical constraints on core formation in the Earth. Nature. 322:1986;221-228.
11. Li J., Agee C.B. Geochemistry of mantle-core formation at high pressure. Nature. 381:1996;686-689.
12. Nash P., Nash A. Ni-Sn (nickel-tin). Nash P., Phase Diagrams of Binary Nickel Alloys. 1991;310-318 ASM International.
13. Nash A., Nash P. Ge-Ni (germanium-nickel). Nash P., Phase Diagrams of Binary Nickel Alloys. 1991;145-153 ASM International.
14. Newsom H.E., Drake M.J. The metal content of the eucrite parent body Constraints from the partitioning behavior of tungsten . Geochim. Cosmochim. Acta. 46:1982;2483-2489.
15. Newsom H.E., Taylor S.R. Geochemical implications of the formation of the Moon by a single giant impact. Nature. 338:1989;29-34.
16. Okamoto H. Fe-Sn (Iron-Tin). Okamoto H., Phase Diagrams of Binary Iron Alloys. 1993;385-392 ASM International.
17. Olesinski R.W., Abbaschian G.J. The Ge-Sn (germanium-tin) system. Bull. Alloy Phase Diagrams. 5:1984;265-270.
18. 2O-CuO from emf measurements . Am. Mineralogist. 73:1988;470-486.
19. O'Neill H. The origin of the Moon and the early history of the EarthA chemical model. Part 1: The Moon . Geochim. Cosmochim. Acta. 55:1991;1135-1157.
20. Rammensee W., Wänke H. On the partition coefficient of tungsten between metal and silicate and its bearing on the origin of the moon. Proc. Lunar Sci. Conf. 8:1977;399-409.
21. Reddy S.R., Hajra J.P. Thermodynamics and phase equilibria in the Ga-Sb system. Mater. Sci. Eng. B20:1993;308-311.
22. Righter K., Drake M.J. Core formation in Earth's Moon, Mars, and Vesta. Icarus. 124:1996;513-529.
23. Righter K., Drake M.J. Metal/silicate equilibrium in a homogeneously accreting Earth New results for Re . Earth Planet. Sci. Lett. 146:1997;541-554.
24. Righter K., Drake M.J., Yaxley G. Prediction of siderophile element metal/silicate partition coefficients to 20 GPa and 2800°C The effects of pressure, temperature, oxygen fugacity, and silicate and metallic melt compositions . Phys. Earth Planet. Int. 100:1997;115-134.
25. Ringwood A.E., Seifert S. Lunar siderophile signature and its genetic significance. Abstracts Lunar Planetary Sci. Conf. XIX:1988;984-985.
26. Schmitt W., Palme H., Wänke H. Experimental determination of metal/silicate partition coefficients for P, Co, Ni, Cu, Ga, Ge, Mo, and W and some implications for the early evolution of the Earth. Geochim. Cosmochim. Acta. 53:1989;173-185.
27. Seifert S., Ringwood A.E. Metal/silicate partition coefficients for some volatile siderophile elements and implications for lunar origin. Abstracts Lunar Planetary Sci. Conf. XVIII:1987;904-905.
28. Swartzendruber L. J., Itkin V. P., and Alcock C. B. (1991) Fe-Ni (iron-nickel). In Phase Diagrams of Binary Nickel Alloys (ed. P. Nash), Monographic Series on Alloy Phase Diagrams, ASM International. pp. 110-132.
29. Wänke H. Constitution of terrestrial planets. Philos. Trans. R. Soc. London, Ser. A. 303:1981;287-302.
30. Wohl K. Thermodynamic evaluation of binary and ternary liquid systems. Trans. Am. Inst. Chem. Eng. 42:1946;215-249.