Kinetic simulation of living carbocationic polymerizations. I. Simulation of living isobutylene polymerization

Polymer Reaction Engineering

Volumn 7, Issue 4, 1999, Pages 553-576

  Puskas, Judit E ^a   Peng, Haihong ^a  

^a UNIVERSITY OF WESTERN ONTARIO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CATIONIC POLYMERIZATION; COMPOSITION EFFECTS; COMPUTER SIMULATION; COMPUTER SOFTWARE; INITIATORS (CHEMICAL); ORGANIC SOLVENTS; REACTION KINETICS;

LIVING CARBOCATIONIC POLYMERIZATION; POLYISOBUTYLENES; SOFTWARE PACKAGE PREDICI;

POLYBUTENES;

EID: 0033349459     PISSN: 10543414     EISSN: None     Source Type: Journal    
DOI: 10.1080/10543414.1999.10744530     Document Type: Article

References (34)

1. Brydson, J.A., "Rubber Chemistry", Applied Science Publishers, 1978.
2. Butlerow, A., W. Goriainow (1873). Ueber die Polyolene und die Umwandlung von Aethylen in Aethylalkohol, Annal. Chem. Pharm. CLX1X 1873, pp. 146-149.
3. Chen C.C., G. Kaszas, J.E. Puskas and J.P. Kennedy (1989). Living carbocationic polymerization. XXXIII. Living polymerization of isobutylene by tertiary hydroxyl/boron trichloride/electron pair donor systems, Polym. Bull., 22 (5-6), 463-470.
4. Fodor, Z., M. Györ, H.C. Wang and R.J. Faust (1993). Living carbocationic polymerization of styrene in the presence of proton trap, J. Macromol. Sci., Pure Appl. Chem., A30 (5), 349-363.
5. Györ, M., H.C. Wang and R. Faust (1992). Living carbocationic polymerization of isobutylene with blocked bifunctional initiators in the presence of di-tert-butylpyridine as a proton trap, J. Macromol. Sci., Pure Appl. Chem., A29, 639-653.
6. Kamigaito, M., K. Yamaoka, M. Sawamoto and T. Higashimura (1992). Living cationic polymerization of isobutyl vinyl ether by benzoic acid derivatives/zinc chloride initiating systems: slow interconversion between dormant and activated growing species, Macromolecules, 25, 6400-6406.
7. Kaszas G., M. Györ, J.P. Kennedy and F. Tüdös (1982/83). Quasiliving carbocationic polymerization. XII. Forced ideal copolymerization of isobutylene with styrene, J Macromol. Sci. Chem., A18, 1367-1382.
8. 4 complexes, Makromol. Chem., Macromol. Symp., 13-14, 473-493.
9. Kaszas, G., J.E. Puskas, J.P. Kennedy, and C. C. Chen (1989). Electron-pair donors in carbocationic polymerization. III. Carbocation stabilization by external electron-pair donors in isobutylene polymerization, J. Macromol. Sci., Pure Appl. Chem., A26, 1099-1114.
10. Kaszas, G., J.E. Puskas, J.P. Kennedy and W.G. Hager (1991). Polyisobutylene-containing block polymers by sequential monomer addition. II. Polystyrene-polyisobutylene-polystyrene triblock polymers: synthesis, characterization, and physical properties, J. Polym. Sci. C, 29 (3), 427-435.
11. Kaszas, G. and J.E. Puskas (1994). Kinetics of the carbocationic homopolymerization of isobutylene with reversible chain termination, Polymer Reaction Engineering, 2 (3), 251-273.
12. Kennedy, J.P., "Cationic Polymerization of Olefins: A Critical Inventory", Wiley-Intersci., New York, 1975.
13. Kennedy, J.P., L.R., Ross, J.E., Lackey, and O., Nuyken (1981). New telechelic polymers and sequential copolymers by polyfunctional initiator-transfer agents (inifers). 10. Three-arm star telechelic polyisobutylenes carrying chlorine, olefin, or primary alcohol endgroups, Polym. Bull., 4(1-2), 67-74.
14. Kennedy, J.P., I. Majoros and A. Nagy (1994). Conventional and living carbocationic polymerizations united. I. A comprehensive model and new diagnostic method to probe the mechanism of homopolymerizations, Adv. Polym. Sci., 112, 1-143.
15. Keszler, B., V.S.C. Chang and J.P. Kennedy (1984). Styryl-telechelic polyisobutylenes. I. Synthesis of linear and tri-arm star styryl-telechelic polyisobutylenes, J. Macromol. Sci., Pure Appl. Chem., A21 (3), pp. 307-318.
16. Müller, A.H.E., D. Yan and M. Wulkow (1997). Molecular parameters of hyperbranched polymers made by self-condensing vinyl polymerization. 1. Molecular weight distribution, Macromolecules, 30 (23), 7015-7023.
17. Nuyken, O., F. Gruber, S.D. Pask, A. Riederer and M. Walter (1993). The synthesis of α-tert-butyl-ω-(p-vinyl phenyl)-terminated macromonomers. Makromol. Chem. 194 (12), 3415-3432
18. Puskas, J.E., G. Kaszas and M. Litt (1991). Chain carriers and molecular weight distributions in living isobutylene polymerizations, Macromolecules, 24, 5278-5282.
19. Puskas, J.E. and G. Kaszas (1996). Polyisobutylene-based thermoplastic elastomers: a review, Rubber Chem. & Tech., 69 (3), 462-475.
20. Puskas, I.E. and C.J. Wilds (1998). Multiarm-star polyisobutylenes by living carbocationic polymerization, J. Polym. Sci. C, 36 (1), 85-92.
21. 4 reaction order in living isobutylene polymerizations, Macromolecules, 31, 8684-8690.
22. Puskas, J.E., M.G. Lanzendörfer, and Wayne E. Pattern (1998). Mid-IR real-time monitoring of the carbocationic polymerization of isobutylene and styrene, Polymer Bulletin, 40, 55-61.
23. Puskas, J.E., and M. Grassmüller (1998). Star-branched and hyperbranched polyisobutylenes, Macromol. Symp., 132, 117-126.
24. Roth, M. and H. Mayr (1996). A novel method for the determination of propagation rate constants: carbocationic oligomerization of isobutylene, Macromolecules, 29, 6104-6109.
25. Roth, M., M. Patz, H. Preter and H. Mayr (1997). Living oligomerization of isobutylene using di- and triisobutylene hydrochlorides as initiators, Macromolecules, 30, 722-725.
26. Storey, R.F., B.J. Chisolm and E. Mowbray (1993). Kinetic study of the living cationic polymerization of isobutylene using dicumyl chloride titanium tetrachloride/pyridine initiating system, Polym. Prepr., 34 (1), 568-569.
27. Storey, R.F., and K.A. Shoemake (1994). Synthesis and characterization of polyisobutylene star-branched polymers, Polym. Prepr., 35 (2), 578-579.
28. 4/pyridine initiating system, Macromolecules, 28, 4055-4061.
29. 4/2,4-DMP initiating system, Macromolecules, 30, 4799-4806.
30. 4] via real-time in situ FTIR-ATR spectroscopy, Polym. Prepr., 39 (1), 329-330.
31. Storey, R.F., A.B. Donnalley and T.L. Maggio (1998). Real-time monitoring of carbocationic polymerization of isobutylene using in situ FTIR-ATR spectroscopy with conduit and diamond-composite sensor technology, Macromolecules, 31 (5), 1523-1526.
32. Wang, L., S.T. McKenna and R. Faust (1995). Initiation via haloboration in living cationic polymerization. 3. Synthesis and characterization of functional star-branched polyisobutylenes, Macromolecules, 28, 4681-4685.
33. Wulkow, M., "PREDICI® Simulation Package for Polyreactions", 1996a.
34. Wulkow, M. (1996b). The simulation of molecular weight distributions in polyreaction kinetics by discrete Galerkin methods, Macromol. Theory Simul., 5, 393-416.