Hydrolysis and polymerization of dimethyldiethoxysilane, methyltrimethoxysilane and tetramethoxysilane in presence of aluminum acetylacetonate. A complex catalyst for the formation of siloxanes

Journal of Sol-Gel Science and Technology

Volumn 16, Issue 3, 1999, Pages 209-220

  Zhang, Zuyi ^a   Sakka, Sumio ^b  

^a Nihon Yamamura Glass Co Ltd   (Japan)

^b FUKUI UNIVERSITY OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; ALUMINUM COMPOUNDS; CATALYST ACTIVITY; HYDROLYSIS; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; PROTONS;

DIMETHYLDIETHOXYSILANE; METHYLTRIMETHOXYSILANE; TETRAMETHOXYSILANE;

SILICONES;

EID: 0033321827     PISSN: 09280707     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1008761002205     Document Type: Article

References (45)

1. Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronic, and Specialty Shapes, edited by L.C. Klein (Noyes, Park Ridge, NJ, 1988). C .J. Brinker and G.W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, New York, 1990). S. Sakka, in Treatise on Materials Science and Technology, edited by M. Tomozawa and R.H. Doremus (Academic Press, New York, 1982).
2. Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronic, and Specialty Shapes, edited by L.C. Klein (Noyes, Park Ridge, NJ, 1988). C .J. Brinker and G.W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, New York, 1990). S. Sakka, in Treatise on Materials Science and Technology, edited by M. Tomozawa and R.H. Doremus (Academic Press, New York, 1982).
3. Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronic, and Specialty Shapes, edited by L.C. Klein (Noyes, Park Ridge, NJ, 1988). C .J. Brinker and G.W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, New York, 1990). S. Sakka, in Treatise on Materials Science and Technology, edited by M. Tomozawa and R.H. Doremus (Academic Press, New York, 1982).
4. E.J.A. Pope and J.D. Mackenzie, J. Non-Cryst. Solids 87, 185 (1986).
5. R.K. Iler, The Chemistry of Silica (Wiley, New York, 1979).
6. M. Yamane, S. Inoue, and A. Yasumori, J. Non-Cryst. Solids 63, 13 (1984). S. Sakka, H. Kozuka, and S. Kim, in Ultrastructure Processing of Advanced Ceramics, edited by J.D. Mackenzie and D.R. Ulrich (Wiley, New York, 1988), p. 159.
7. M. Yamane, S. Inoue, and A. Yasumori, J. Non-Cryst. Solids 63, 13 (1984). S. Sakka, H. Kozuka, and S. Kim, in Ultrastructure Processing of Advanced Ceramics, edited by J.D. Mackenzie and D.R. Ulrich (Wiley, New York, 1988), p. 159.
8. D.W. Schaefer and K.D. Keefer, in Better Ceramics Through Chemistry, edited by C.J. Brinker, D.E. Clark, and D.R. Ulrich (Elsevier, New York, 1984), p. 1.
9. S. Sakka, in Better Ceramics Through Chemistry, C.J. Brinker, D.E. Clark, and D.R. Ulrich (Elsevier, New York, 1984), p. 91.
10. J. Sol-Gel Sci. Technol. 7 (1996) (Special Issue: Biochemical Aspects).
11. B.C. Dave, J.M. Miller, B. Dunn, J.S. Valentine, and J.I. Zink, J. Sol-Gel Sci. Technol. 8, 629 (1997).
12. K.J. McNeil, J.A. DiCaprio, D.A. Walsh, and R.F. Pratt, J. Am. Chem. Soc. 102, 1859 (1980).
13. A.A. Humffray and J.J. Ryan, J. Chem. Soc. B 1138 (1969).
14. E.R. Pohl and F.D. Osterholtz, in Molecular Characterization of Composite Interfaces, edited by H. Ishida and G. Kumar (Plenum, New York, 1985), p. 157.
15. Z. Zhang, Y. Tanigami, and R. Terai, J. Non-Cyst. Solids 191, 304 (1995). Z. Zhang, Langmuir 13, 473 (1997).
16. Z. Zhang, Y. Tanigami, and R. Terai, J. Non-Cyst. Solids 191, 304 (1995). Z. Zhang, Langmuir 13, 473 (1997).
17. U. Jäqlid and O. Lindqvist, Acta Chem. Scand. 44, 765 (1990). Acta Chem. Scand. 45, 887 (1991).
18. U. Jäqlid and O. Lindqvist, Acta Chem. Scand. 44, 765 (1990). Acta Chem. Scand. 45, 887 (1991).
19. S.C. Deshmukh and E.S. Aydil, J. Vac. Sci. Technol. A 13, 2355 (1995).
20. R.M. Silverstein, G.C. Bassler, and T.C. Morrill, Spectrometric Identification of Organic Compounds (Wiley, New York, 1981).
21. N. Wright and M.J. Hunter, J. Am. Chem. Soc. 69, 803 (1947). J.F. Brown, Jr., J. Am. Chem. Soc. 87, 4317 (1965) . R. Konopka and B. Stojczyk, Acta Phys. Polon. A40, 537 (1971).
22. N. Wright and M.J. Hunter, J. Am. Chem. Soc. 69, 803 (1947). J.F. Brown, Jr., J. Am. Chem. Soc. 87, 4317 (1965) . R. Konopka and B. Stojczyk, Acta Phys. Polon. A40, 537 (1971).
23. N. Wright and M.J. Hunter, J. Am. Chem. Soc. 69, 803 (1947). J.F. Brown, Jr., J. Am. Chem. Soc. 87, 4317 (1965) . R. Konopka and B. Stojczyk, Acta Phys. Polon. A40, 537 (1971).
24. C.J. Brinker and D.M. Haaland, J. Am. Ceram. Soc. 66, 758 (1983). A. Duran, J.M. Fernandez-Navarro, P. Casariego, and A. Joglar, J. Non-Cryst. Solids 85, 69 (1986).
25. C.J. Brinker and D.M. Haaland, J. Am. Ceram. Soc. 66, 758 (1983). A. Duran, J.M. Fernandez-Navarro, P. Casariego, and A. Joglar, J. Non-Cryst. Solids 85, 69 (1986).
26. L.W. Kelts, N.J. Effinger, and S.M. Melpolder, J. Non-Cryst. Solids 83, 353 (1986).
27. A.R. Siedle, in Comprehensive Coordination Chemistry, edited by S.G. Wilkinson (Pergamon, Oxford, 1987), Vol. 2, chapt. 15.4.
28. M. Sedlar and M. Sayer, J. Sol-Gel Sci. Technol. 5, 27 (1995).
29. L.L. Funck and T.R. Ortolano, Inorg. Chem. 6, 567 (1967). W.R. May and M.M. Jones, J. Inorg. Nucl. Chem. 25, 507 (1963).
30. L.L. Funck and T.R. Ortolano, Inorg. Chem. 6, 567 (1967). W.R. May and M.M. Jones, J. Inorg. Nucl. Chem. 25, 507 (1963).
31. Nuclear Magnetic Shift Reagents, edited by R.E. Sievers (Academic Press, New York, 1973).
32. T.S. Davis and J.P. Fackler, Jr., Inorg. Chem. 5, 242 (1966). G.S. Vigee and C.L. Watkins, Inorg. Chem. 16, 709 (1977).
33. T.S. Davis and J.P. Fackler, Jr., Inorg. Chem. 5, 242 (1966). G.S. Vigee and C.L. Watkins, Inorg. Chem. 16, 709 (1977).
34. M.J. Van Bommel, T.N.M. Bernards, and A.H. Boonstra, J. Non-Cryst. Solids 128, 231 (1991).
35. C.J. Brinker, J. Non-Cryst. Solids 100, 30 (1988).
36. F.D. Osterholtz and E.R. Pohl, in Silane and Other Coupling Agents, edited by K.L. Mittal (VSP, The Netherlands, 1992).
37. J. Chojnowski, S. Rubinsztajn, and L. Wilczek, Macromolecules 20, 2345 (1987).
38. H. Imura, A. Oshiro, and R. Shiga, Solvent Extr. Ion Exch. 13, 1009 (1995). C. Corvaja and G. Ciacometti, J. Mol. Struct. 2, 239 (1968).
39. H. Imura, A. Oshiro, and R. Shiga, Solvent Extr. Ion Exch. 13, 1009 (1995). C. Corvaja and G. Ciacometti, J. Mol. Struct. 2, 239 (1968).
40. J.F. Brown, Jr., J. Am. Chem. Soc. 87, 4217 (1965).
41. A.J. Barry, W.H. Daudt, J.J. Domicone, and J.W. Gilkey, J. Am. Chem. Soc. 77, 4248 (1955). L.H. Vogt, Jr. and J.F. Brown, Jr., Inorg. Chem. 2, 189 (1963).
42. A.J. Barry, W.H. Daudt, J.J. Domicone, and J.W. Gilkey, J. Am. Chem. Soc. 77, 4248 (1955). L.H. Vogt, Jr. and J.F. Brown, Jr., Inorg. Chem. 2, 189 (1963).
43. Z. Zhang, Y. Tanigami, R. Terai, H. Wakabayashi, and S. Sakka, J. Phys. Chem. B 101, 1328 (1997).
44. R.K. Iler, The Chemistry of Silica (Wiley, New York, 1979), p. 174.
45. W. Stöber, A. Fink, and E. Bohn, J. Colloid Interface Sci. 26, 62 (1968).