How does organic structure determine organic reactivity? The effect of ortho-dimethyl groups on the nucleophilic substitution and alkene-forming elimination reactions of ring-substituted cumyl derivatives

Canadian Journal of Chemistry

Volumn 77, Issue 5-6, 1999, Pages 922-933

  Amyes, Tina L ^a   Mizerski, Tadeusz ^a   Richard, John P ^a  

^a UNIVERSITY AT BUFFALO   (United States)

Author keywords

Carbocation; Elimination; Ortho substituent effects; Solvolysis; Steric effects

Indexed keywords

ADDITION REACTIONS; ETHANOL; HYDROCARBONS; RATE CONSTANTS; TRAPPED IONS;

AZIDE ION; CARBOCATIONS; ELIMINATION; NUCLEOPHILIC ADDITIONS; ORGANIC STRUCTURES; ORTHO METHYL GROUP; ORTHO-SUBSTITUENT EFFECT; SOLVOLYSES; STERIC EFFECT; SUBSTITUENT EFFECT;

SOLVENTS;

ALKENE; BENZYL DERIVATIVE; CUMENE; METHYL GROUP; SOLVENT;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; KINETICS; PROTON NUCLEAR MAGNETIC RESONANCE; REVERSED PHASE HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; SYNTHESIS;

EID: 0033306138     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v99-084     Document Type: Article

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