A mechanism for efficient proton-transfer catalysis. Intramolecular general acid catalysis of the hydrolysis of 1-arylethyl ethers of salicylic acid

Canadian Journal of Chemistry

Volumn 77, Issue 5-6, 1999, Pages 792-801

  Barber, Sarah E ^a   Dean, Kathryn E S ^a   Kirby, Anthony J ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

Carboxyl; Catalysis; Enzyme mechanism; Hydrogen bond; Proton transfer

Indexed keywords

ETHER DERIVATIVE; SALICYLIC ACID;

ARTICLE; CATALYSIS; ENZYME ACTIVITY; HYDROGEN BOND; HYDROLYSIS; MOLECULAR INTERACTION; PKA; PROTON TRANSPORT; REACTION ANALYSIS;

ETHERS; HYDROGEN BONDS; HYDROLYSIS; PROTON TRANSFER; SALICYLIC ACID;

C-O CLEAVAGE; CARBOXYL; COOH GROUP; ENZYME MECHANISM; GENERAL ACID CATALYSIS; HALF LIVES; INTRAMOLECULAR GENERAL ACID CATALYSIS; LEAVING GROUPS; PROTON TRANSFER CATALYSIS; TERT-BUTYL ETHERS;

CATALYSIS;

EID: 0033305805     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v99-080     Document Type: Article

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