Catalytic asymmetric acylation of racemic secondary alcohols with benzoyl chloride in the presence of a chiral diamine

Chemistry Letters

Volumn , Issue 3, 1999, Pages 265-266

  Sano, Tomohumi ^a   Imai, Keisuke ^a   Ohashi, Kousaburo ^a   Oriyama, Takeshi ^a  

^a IBARAKI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0033246941     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1999.265     Document Type: Article

References (26)

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25. D-53.8° (c 1.0, MeOH)).
26. 3N, unreacted halohydrins were obtained in the lower optical yields. 1f gave 4 f in 46% with 97% ee and 5 f in 45% with 85% ee, and 1 g gave 4 g in 45% with 97% ee and 5 g in 39% with 84% ee.