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note
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Synthesis of 1 was as follows. ω-Aminohexanoic acid was acylated with p-nitrobenzoyl chloride and then condensed with β-lactosylamine in the presence of BOP and HOB1. The nitro function was hydrogenated with Pd/C and the product was chromatographed through Toyopearl HW40S to provide 1 in 59% yield from ω-ammohexanoic acid.
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