New stable metallic salt based on a donor molecule containing peri-ditellurium bridges, TMTTeN(SCN)0.88

Chemistry Letters

Volumn , Issue 8, 1999, Pages 845-846

  Ojima, Emiko ^a   Narymbetov, Bakhyt Zh ^a   Fujiwara, Hideki ^a   Kobayashi, Hayao ^a   Kobayashi, Akiko ^b   Takimiya, Kazuo ^c   Otsubo, Tetsuo ^c   Ogura, Fumio ^d  

^a GRADUATE UNIVERSITY FOR ADVANCED STUDIES   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

^c HIROSHIMA UNIVERSITY   (Japan)

^d KINKI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0033245601     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1999.845     Document Type: Article

References (14)

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2. M. R. Bryce, Chem. Soc. Rev., 20, 355 (1991); J. M. Williams, J. R. Ferraro, R. J. Thorn, K. D. Carlson, U. Geiser, H. H. Wang, A. M. Kini, and M. -H. Whangbo, "Organic Superconductors," Prentice Hall, New Jersey (1992), pp. 275-277;
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11. I. F. Shchegolev and E. B. Yagubskii, in "Extended Linear Chain Compounds," ed by J. S. Miller, Plenum Press, New York (1982), Vol. II, pp. 385-434; P. Shibaeva, in "Extended Linear Chain Compounds," ed by J. S. Miller, Plenum Press, New York (1982), Vol. II, pp. 435-467.
12. I. F. Shchegolev and E. B. Yagubskii, in "Extended Linear Chain Compounds," ed by J. S. Miller, Plenum Press, New York (1982), Vol. II, pp. 385-434; P. Shibaeva, in "Extended Linear Chain Compounds," ed by J. S. Miller, Plenum Press, New York (1982), Vol. II, pp. 435-467.
13. -3. 2013 unique reflections and 1223 observed [1> 3.00σ(I)]. The final R (Rw) and GOF values are 0.035 (0.034) and 1.24, respectively.
14. Slater type atomic orbitals were used for the calculation of molecular orbitals. The exponent ζ and the ionization potential (eV) are: Te 5s, 2.112, -20.00; Te 5p, 1.827.-11.00; Te 5d, 1.500, -6.80; C 2s, 1.625, -21.4; C 2p, 1.625,-11.4; H 1s, 1.0-13.6.