Selective isomerization of 2-allylphenol to (Z)-2-propenylphenol catalyzed by Ru(cod)(cot)/PEt3

Chemistry Letters

Volumn , Issue 5, 1999, Pages 441-442

  Sato, Takehiro ^a   Komine, Nobuyuki ^a   Hirano, Masafumi ^a   Komiya, Sanshiro ^a  

^a TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0033242009     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1999.441     Document Type: Article

References (25)

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25. A tbp geometry where the oxygen and the methine carbon occupy sites at apical and equatorial positions, respectively, and the three trimethylposphine ligands occupy two equatorial and one apical sites, is assumed. By changing O-Ru-C-C(Ph) dihedral angles in C, two distinct local minima were found. Estimated total energy of the possible two structures leading to (Z)- and (E)-isomers were 8.0 and 13.7 kcal/mol, respectively.