Hydrothermal synthesis of ruthenium-substituted heteropolyanion, [SiW11O39Ru(III)(H2O)]5-as a water soluble oxidation catalyst

Chemistry Letters

Volumn , Issue 10, 1999, Pages 1093-1094

  Higashijima, Michio ^a  

^a MITSUBISHI CHEMICAL CORPORATION   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0033235175     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1999.1093     Document Type: Article

References (14)

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13. Ruthenium and silicon were analyzed by inductively coupled plasma (ICP), tungsten by X-ray fluorescence, and cesium by atomic absorption. Water was determined using Karl Fischer's reagent.
14. For example, RuCl3 · nH2O (0.092 mmol) and 2 (0.092 mmol) were used for the oxidation of p-xylene (4 mmol) to give terephtalic acid (44.2%), p-toluic acid (9.2%), p-toluic aldehyde (0.15%) and carbon dioxide (8.5%) after 2h under the same conditions.