Enantio-differentiating hydrogenation of methyl 2-furoylacetate and its analogs over tartaric acid-modified Raney nickel

Chemistry Letters

Volumn , Issue 10, 1999, Pages 1055-1056

  Nakagawa, Satoshi ^a   Haruna, Noriko ^a   Acosta, Delicia E ^b   Endo, Tadateru ^a   Sugimura, Takashi ^a   Tai, Akira ^a  

^a UNIVERSITY OF HYOGO   (Japan)

^b UNIVERSIDAD NACIONAL DE SALTA   (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0033235134     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1999.1055     Document Type: Article

References (8)

1. A. Tai and T. Harada, in "Tailored Metal Catalysis," ed by Y. Iwasawa, Reidel, Dordrecht (1986), pp. 265-324.
2. A. Tai, T. Kikukawa, T. Sugimura, Y. Inoue, S. Abe, T. Osawa, and T. Harada, Bull. Chem. Soc. Jpn., 67, 2473 (1994).
3. T. Sugimura, T. Osawa, S. Nakagawa, T. Harada, and A. Tai, in "Studies in Surface Science and Catalyst 101 (11th International Congress on Catalysis)," ed by J. W. Hightower, Elsevier, Amsterdam (1996), pp. 231-240.
4. S. Nakagawa, T. Sugimura, and A. Tai, Chem. Lett., 1997, 859.
5. 1H-NMR study of the isolated each isomer supported the above assignment.
6. 4 reduction of 1.
7. 3)
8. The ratios of 10/9 in the repeated runs were in a range of 1-3. Kinetic resolution of 9 during the hydrogenation was not observed.