Novel utilization of carbon dioxide for direct conversion of methane to ethane and ethylene

Journal of the Chinese Institute of Chemical Engineers

Volumn 30, Issue 6, 1999, Pages 439-447

  Ohtsuka, Yasuo ^c   Asamil, Kenji ^b   Wang, Ye ^a  

^a TOHOKU UNIVERSITY   (Japan)

^b Osaka City University   (Japan)

^c NONE

Author keywords

C2 hydrocarbons; Carbon dioxide; Metal oxide catalysts; Methane; Natural gas

Indexed keywords

CARBON DIOXIDE; CATALYST; CHEMICAL REACTION; METHANE;

CARBON DIOXIDE; CATALYST SUPPORTS; CERIUM COMPOUNDS; CHROMIUM COMPOUNDS; ETHANE; ETHYLENE; INDIUM COMPOUNDS; LANTHANUM COMPOUNDS; LIME; METHANE; NATURAL GAS; REDOX REACTIONS;

METAL OXIDE CATALYSTS;

CATALYSIS;

EID: 0033216472     PISSN: 03681653     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (25)

1. 2 in the Oxidative Coupling of Methane over PbO-MgO and PbO-CaO," J. Chem. Soc., Chem. Commun., 70 (1988).
2. Arai, H., T. Kunisaki, Y. Shimizu and T. Seiyama, "Electrical Properties of Calcia-Doped Ceria with Oxygen Ion Conduction," Solid State Ionics, 20, 241 (1986).
3. Asami, K., T. Shikada and K. Fujimoto, "Effect of Oxidant on the Oxidative Coupling of Methane over a Lead Oxide Catalyst," Bull. Chem. Soc. Japan., 64, 266 (1991).
4. 2 Hydrocarbons over Metal Oxides," Appl. Catal. A: General, 126, 245 (1995).
5. Asami, K., K. Kusakabe, N. Ashi and Y. Ohtsuka, "Formation of Ethane and Ethylene by the Reaction of Methane and Carbon Dioxide over Unsupported Metal Oxides," Stud. Surf. Sci. Catal., 107, 279 (1997a).
6. Asami, K., K. Kusakabe, N. Ashi and Y. Ohtsuka, "Synthesis of Ethane and Ethylene from Methane and Carbon Dioxide over Praseodymium Oxide Catalysts," Appl. Catal. A: General, 156, 43 (1997b).
7. 3/ZnO Catalyst," Catal. Lett., 42, 149 (1996).
8. Jones, C. A., J. J. Leonard and J. A. Sofranko, "Fuels for the Future:Remote Gas Conversion," Energy Fuels, 1, 12 (1987).
9. Lunsford, J. H., "The Catalytic Oxidative Coupling of Methane," Angew. Chem., Int. Ed. Engl., 34, 970 (1995).
10. Maitra, A.M., I. Campbell and R.J. Tyler, "Influence of Basicity on the Catalytic Activity for Oxidative Coupling of Methane," Appl. Catal. A: General., 85, 27 (1992).
11. Maitra, A. M., "Critical Performance Evaluation of Catalysts and Mechanistic Implications for Oxidative Coupling of Methane," Appl. Catal. A: General, 104, 11 (1993).
12. Martin, G. A. and C. Mirodatos, "Surface Chemistry in the Oxidative Coupling of Methane," Fuel Process. Technol., 42, 179 (1995).
13. Minachev, Kh. M., "The Catalytic Activity of Rare Earth Oxides," Catalysis (J. W. Hightower, Ed.), Vol. 1, Proc., Fifth International Congress on Catalysis, p. 9/219, North-Holland, Amsterdam (1973).
14. 2 as an Oxidant over PbO-MgO," J. Catal., 122, 346 (1990).
15. Omata, K., S. Hashimoto, H. Tominaga and K. Fujimoto, "Oxidative Coupling of Methane using a Membrane Reactor," Appl. Catal., 52, 1 (1989).
16. Otsuka, K., K. Jinno and A. Morikawa, "The Catalysts Active and Selective in Oxidative Coupling of Methane," Chem. Lett., 499 (1985).
17. 6 via Oxidative Coupling of Methane," J. Catal., 100, 499 (1986).
18. Parmaliana, A., D. Sanfilippo, F. Frusteri, A. Vaccari and F. Arena (Eds.), "Natural Gas Conversion V", Stud. Surf. Sci. Catal., 119 (1998).
19. Takasu, Y., M. Matsui, H. Tamura, S. Kawamura, Y. Matsuda and I. Toyoshima, "Temperature-Programmed Desorption on te Unstable Lattice Oxygen of Praseodymium Oxide," J. Catal., 69, 51 (1981).
20. Takasu, Y., M. Yoko-o, M. Matsui, Y. Matsuda and I. Toyoshima, "Catalytic Reactivity of the Lattice Oxygen Atoms of Terbium Oxide," J. Catal., 77, 485 (1982).
21. Tong, Y., M.P. Rosynek and J.H. Lunsford, "Secondary Reactions of Methyl Radicals with Lanthanide Oxides: Their Role in the Selective Oxidation of Methane," J. Phys. Chem., 93, 2896 (1989).
22. 2 Modified with CaO, "Appl. Catal. A: General, 172, 203 (1998a).
23. Wang. Y, Y. Takahashi and Y. Ohtsuka, "Effective Catalysts for Conversion of Methane to Ethane and Ethylene Using Carbon Dioxide," Chem. Lett., 1209 (1998b).
24. 2 Catalysts," J. Catal., 186, 160 (1999).
25. 1 Chemistry, Huangshan, China, p. 437 (1996).