Direct conversion of aldehydes into nitriles via O-phenylcarbamoylated aldoximes

Tetrahedron

Volumn 55, Issue 40, 1999, Pages 11943-11948

  Coşkun, Necdet ^a   Arikan, Nevin ^a  

^a ULUDAG UNIVERSITY   (Turkey)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; ALDOXIME; ANIDOXIME; NITRILE; OXIME; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; DECOMPOSITION; DEHYDRATION; PRIORITY JOURNAL; SYNTHESIS;

EID: 0033213934     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(99)00692-4     Document Type: Article

References (16)

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7. 11,12
8. Compounds 3a,c,e,h-1 were prepared from the reaction of corresponding aldehydes and carbamoylated hydroxylamine tosylate at reflux in toluene for 0.5 h.
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10. Brady, O.L.; Dunn, F.P., J. Chem. Soc., 1916, 109, 650-681.
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13. Hauser, C.R.; Jordan, E., J. Am. Chem. Soc., 1935, 57, 2450-2456.
14. Brady, O.I.; McHuch, G.P., J. Chem. Soc., 1925, 127, 2414-2427.
15. Compounds 2a,d,g were obtained by this method.
16. The compound did not crystallize from ethanol water. The recrystallization was performed from chloroform-petroleem ether. If all of the literature assignments for the known carbamoylated oximes are true the compounds obtainable by our method are mainly syn.