Probing the location of the terminal groups of dendrimers in dilute solution

Macromolecules

Volumn 32, Issue 21, 1999, Pages 7226-7231

  Topp, Andreas ^a   Bauer, Barry J ^a,b,c   Klimash, June W ^a,c   Spindler, Ralph ^a,b   Tomalia, Donald A ^a,b,c   Amis, Eric J ^a,b,c  

^a NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

^b MICHIGAN MOLECULAR INSTITUTE   (United States)

^c Materials Research   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

MACROMOLECULES; NEUTRON SCATTERING;

DENDRIMERS; POLYAMIDO AMINE; SMALL-ANGLE NEUTRON SCATTERING (SANS);

POLYAMIDES;

EID: 0033204186     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma990125s     Document Type: Article

References (46)

1. Certain commercial materials and equipment are identified in this paper in order to specify adequately the experimental procedure. In no case does such identification imply recommendation by the National Institute of Standards and Technology nor does it imply that the material or equipment identified is necessarily the best available for this purpose.
2. For reviews on the synthesis of dendrimers and dendritic macromolecules see: (a) Tomalia, D. A.; Naylor, A. M.; Goddard, W. A. Angew. Chem., Int. Ed. Engl. 1990,29, 138.
3. (b) Hawker, C. J.; Wooley, K. L.; Fréchet, J. M. J. J. Chem. Soc., Perkin Trans. 1993,1,1287.
4. Fréchet, M. J. J. Science 1994,263,1710.
5. Tomalia, D. A. Adv. Mater. 1994,6,529.
6. (e) Issberner, J.; Moors, R.; Vögtle, F. Angew. Chem., Int. Ed. Engl. 1994, 33, 2413.
7. (f) Voit, B. I.; Turner, S. R. Angew. Makromol. Chem. 1994, 223, 13.
8. (g) Ardoin, N.; Astruc, D. Bull. Soc. Chim. Fr. 1995,132, 875.
9. (h) de Brabander, E. M. M.; Brackman, J.; Mure-Mak, M.; de Man, H.; Hogeweg, M.; Keulen, J.; Scherrenberg, R.; Coussens, B.; Mengerink, Y.; van der Wal, S. Macromol. Symp. 1996, 102, 9.
10. Fréchet, M. J. J.; Hawker, C. J.; Gitsov, L; Leon, J. W. J. Macromol. Sei., Pure Appl. Chem. 1996, A33, 1425.
11. de Gennes, P. G.; Hervat, H. J. Phys., Lett. 1983,44, L-351.
12. Naylor, A. M.; Goddard III, W. A. ACS Polym. Prepr. Div. Polym. Chem. 1988, 29, 215.
13. Naylor, A. M.; Goddard III, W. A.; Kiefer, G. E.; Tomalia, D. A. J. Am. Chem. Soc. 1989, 111, 2339.
14. Lescanec, R. L.; Muthukumar, M. Macromolecules 1990,23, 2280.
15. Mansfield, M. L.; Klushin, L. I. Macromolecules 1993, 26, 4262.
16. Mansfield, M. L. Polymer 1994, 35, 1827.
17. Murat, M.; Grest, G. S. Macromolecules 1996, 29, 1278.
18. Chen, Z. Y.; Gui, S.-M. Macromolecules 1996, 29, 7943.
19. Carl, W. J. Chem. Soc., Faraday Trans. 1996, 92, 4154.
20. Boris, D.; Rubinstein, M. Macromolecules 1996, 29, 7251.
21. Tomalia, D. A.; Hall, M.; Hedstrand, D. M. J. Am. Chem. Soc. 1987, 109, 1601.
22. Tomalia, D. A.; Hedstrand, D. M.; Wilson, L. R. Encyclopedia of Polymer Science and Engineering, 2nd ed.; Wiley: New York, 1990; Index Vol., pp 46-92.
23. Caminati, G.; Turro, N. J.; Tomalia, D. A. J. Am. Chem. Soc. 1990, 112, 8515.
24. Gopidas, K. R.; Leheny, A. R.; Caminati, G.; Turro, N. J.; Tomalia, D. A. J. Am. Chem. Soc. 1991, 113, 7335.
25. Meltzer, A. D.; Tirrell, D. A.; Jones, A. A.; Inglefield, P. T.; Hedstrand, D. M.; Tomalia, D. A. Macromolecules 1992, 25, 4541.
26. Meltzer, A. D.; Tirrell, D. A.; Jones, A. A.; Inglefield, P. T. Macromolecules 1992, 25, 4549.
27. Bauer, B. J.; Hammouda, B.; Barnes, J. D.; Briber, R. M.; Tomalia, D. A. ACS Polym. Mater. Sei. Eng. Proc. 1994, 71, 704.
28. Bauer, B. J.; Topp, A.; Prosa, T. J.; Amis, E. J.; Yin, R.; Quin, D.; Tomalia, D. A. ACS Polym. Mater. Sei. Eng. Proc. 1997, 77, 87.
29. Prosa, T. J.; Bauer, B. J.; Amis, E. J.; Tomalia, D. A.; Scherrenberg, R. J. J. Polym. Sei., Polym. Phys. Ed. 1997, 35 2913
30. Bauer, B. J.; Briber, R. M.; Hammouda, B.; Tomalia, D. A. ACS Polym. Mater. Sei. Eng. Proc. 1992, 67, 428.
31. Bauer, B. J.; Hammouda, B.; Briber, R. M.; Tomalia, D. A. ACS Polym. Mater. Sei. Eng. Proc. 1994, 71, 342.
32. See ref 2a and references therein for details.
33. Values for the densities are as given in the product specification by the manufacturer; no attempt was undertaken to verify the values.
34. v, and it would be called the "number-average relative molecular mass". The conventional notation, rather that the ISO notation, has been employed for this publication.
35. Prask, H. J.; Rowe, J. M.; Rush, J. J.; Schröder, I. G. J. Res. Natl. Inst. Stand. Technol. 1993, 98, 1.
36. Hammouda, B.; Krueger, S.; Glinka, C. J. Res. Natl. Inst. Stand. Technol. 1993, 98, 31.
37. Glinka, C. J.; Barker, J. G.; Hammouda, B.; Krueger, S.; Moyer, J. J.; Orts, W. J. J. Appl. Crystallogr. 1998, 31, 430.
38. Note: Different instruments and configurations were used to investigate possible artifacts as described in section 3.3.
39. SANS Data Reduction and Imaging Software; Cold Neutron Research Facility, NIST: Gaithersburg, MD 20899, 1996.
40. Guinier, A.; Fournet, G. Small Angle Scattering of X-rays; Wiley: New York, 1955.
41. Topp, A.; Bauer, B. J.; Prosa, T. J.; Scherrenberg, R.; Amis, .E. J., to be published.
42. Higgins, J. S.; Benoît, H. C. Polymers and Neutron Scattering; Oxford Universty Press: New York, 1994.
43. Uppuluri, S.; Tomalia, D. A.; Dvornic, P. R. ACS Polym. Mater. Sei. Eng. Proc. 1997, 77, 87.
44. Personal correspondence with M. L. Mansfield.
45. Wooley, K. L.; Mug, C. A.; Tasaki, K. Schaefer, J. J. Am. Cliem. Soc. 1997, 119, 53.
46. Welch, P.; Muthukumar, M. Macromolecules 1998,31,5892.