NMR detection of oriented association via dilution shifts in tetramethylsilane solvent. 1. n-Alkyl halides

Magnetic Resonance in Chemistry

Volumn 37, Issue 9, 1999, Pages 609-612

  Tiers, George Van Dyke ^a  

^a 3M COMPANY   (United States)

Author keywords

13C NMR; 1H NMR; Halide self association; Infinite dilution deshielding; Localized dilution shifts; NMR; Positive isotope effect; Tetramethylsilane 1H(29Si) shift

Indexed keywords

ASSOCIATION REACTIONS; CARRIER MOBILITY; CHEMICAL BONDS; ELECTRONEGATIVITY; ISOTOPES; MOLECULES; POLARIZATION; SOLVENTS;

13C NMR; 1H NMR; DESHIELDING; HALIDE SELF-ASSOCIATION; INFINITE DILUTION; INFINITE DILUTION DESHIELDING; ISOTOPE EFFECT; LOCALISED; LOCALIZED DILUTION SHIFT; POSITIVE ISOTOPE EFFECT; SELF-ASSOCIATIONS; TETRAMETHYL SILANES; TETRAMETHYLSILANE 1H(29SI) SHIFT;

DILUTION;

EID: 0033181398     PISSN: 07491581     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1097-458X(199909)37:9<609::AID-MRC516>3.0.CO;2-4     Document Type: Article

References (16)

1. 1. G. V. D. Tiers, J. Fluorine Chem. 90, 41 (1998).
2. 2. G. Filipovich and G. V. D. Tiers, J. Phys. Chem. 63, 761 (1959).
3. 3. G. V. D. Tiers, J. Phys. Chem. 62, 1151 (1958).
4. 4. G. V. D. Tiers, J. Fluorine Chem. in press (1999).
5. 5. G. V. D. Tiers, Acta Chem. Scand. 52, 1223 (1998).
6. 6. A. Allerhand and M. Dohrenwend, J. Am. Chem. Soc. 107, 6684 (1985).
7. 7. J. R. Everett, J. Chem. Soc., Perkin Trans. 2 1151 (1984).
8. 8. H. Schmidbaur, J. Am. Chem. Soc. 85, 2336 (1963).
9. 9. B. K. Hunter and L. W. Reeves, Can. J. Chem. 46, 1399 (1968).
10. 10. G. V. D. Tiers, J. Stevens and W. R. Stebbings, Magn. Reson. Chem. 37, 613-619.
11. 11. J. B. Lambert and A. R. Vagenas, Org. Magn. Reson. 17, 265 (1981).
12. 12. P. R. Seidl, K. Z. Leal, V. E. U. Costa and M. E. S. Mollmann, Magn. Reson. Chem. 36, 261 (1998).
13. 13. W. S. Warren, Science 280, 398 (1998).
14. 14. A. Marker, D. Doddrell and N. V. Riggs, Chem. Commun. 724 (1972).
15. 15. T. Steiner and G. R. Desiraju, Chem. Commun. 891 (1998).
16. 16. J. Stevens, Theochem, submitted (1999).