Rate constants of the Br-initiated gas-phase oxidation of a series of alcohols, furans and benzenes at 300 ± 2 K

Atmospheric Environment

Volumn 33, Issue 18, 1999, Pages 2981-2992

  Bierbach, A ^a   Barnes, I ^a   Becker, K H ^a  

^a UNIVERSITY OF WUPPERTAL   (Germany)

Author keywords

Bromine atom; Organic compounds; Oxidation; Rate coefficient

Indexed keywords

ALCOHOLS; ATOMS; BENZENE; ETHANOL; METHANOL; ORGANIC COMPOUNDS; OXIDATION; RATE CONSTANTS;

FURANS; GAS PHASE OXIDATION; RATE COEFFICIENT;

ATMOSPHERIC CHEMISTRY;

ALCOHOL; AROMATIC HYDROCARBON; BENZENE; BROMINE; FURAN;

ALCOHOL; ATMOSPHERIC CHEMISTRY; BENZENE; BROMINE; FURAN; GAS PHASE REACTION; OXIDATION;

AIR ANALYSIS; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; DEGRADATION; GAS; OXIDATION; PHYSICAL PHASE; PLOTS AND CURVES; PRIORITY JOURNAL; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0033180877     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1352-2310(99)00084-9     Document Type: Article

References (29)

1. Atkinson, R., 1994. Gas-phase tropospheric chemistry of organic compounds. Journal of Physical and Chemical Reference Data, Monograph No. 2.
2. 2. International Journal of Chemical Kinetics 21, 499-517.
3. Barrie, L.A., Bottenheim, J.W., Schnell, R.C., Crutzen, P.J., Rasmussen, R.A., 1988. Ozone destruction and photochemical reactions at polar sunrise in the lower Arctic atmosphere. Nature 334, 138-141.
4. Barrie, L.A., den Hartog, G., Bottenheim, J.W., Landsberger, S., 1989. Anthropogenic aerosols and gases in the lower troposphere at Alert Canada in April 1986. Journal of Atmospheric Chemistry 9, 101-127.
5. Barrie, L.A., Staebler, R., Toom, D., Georgi, B., den Hartog, G., Landsberger, S., Wu, D., 1994a. Arctic aerosol size-segregated chemical observations in relation to ozone depletion during polar sunrise experiment 1992. Journal of Geophysical Research 99, 25 439-25 451.
6. Barrie, L.A., Li, S.M., Toom, D., Landsberger, S., Sturges, W., 1994b. Lower tropospheric measurements of halogens, nitrates, and sulphur oxides during polar sunrise experiment 1992. Journal of Geophysical Research 99, 25 453-25 467.
7. Bierbach, A., Barnes, L, Becker, K.H., 1992. Rate coefficients for the gas phase reactions with furan, 2-methylfuran, 2-ethylfuran and 2,5-dimethylfuran at 300 ± 2 K. Atmospheric Environment 26A, 813-817.
8. Bierbach, A., Barnes, L, Becker, K.H., 1995. Product and kinetic study of the OH-initiated gas-phase oxidation of furan, 2-methylfuran and furanaldehydes at ò 300 K. Atmospheric Environment 29A, 2651-2660.
9. Bierbach, A., Barnes, I., Becker, K.H., 1996. Rate coefficients for the gas-phase reactions of bromine radicals with a series of alkenes, dienes and aromatic hydrocarbons. International Journal of Chemical Kinetics 28, 565-577.
10. Bierbach, A., Barnes, I., Becker, K.H., 1997. FT-IR product study of the gas-phase Br-initiated oxidation of trans-2-butene under atmospheric conditions between 246 and 298 K. Tellus 49B, 566-582.
11. Bottenheim, J.W., Barrie, L.A., Atlas, E., Heidt, L.E., Niki, H., Rasmussen, R.A., Shepson, P.B., 1990. Depletion of lower tropospheric ozone during arctic spring : The polar sunrise experiment 1988. Journal of Geophysical Research 95, 18 555-18 568.
12. Buckley, E., Whittle, E., 1962. Photobromination of methanol. Part 3. Kinetics in the presence of added carbon dioxide. Transactions of Faraday Society 58, 536-542.
13. 2OH. Journal of Physical Chemistry 100, 19 864-19 873.
14. Finlayson-Pitts, B.J., Livingston, F.E., Berko, H.N., 1990. Ozone destruction and bromine photochemistry in the Arctic spring. Nature 343, 622-625.
15. Hausmann, M., Platt, U., 1994. Spectroscopic measurement of bromine oxide and ozone in the arctic during polar sunrise experiment 1992. Journal of Geophysical Research 99, 25 399-25 413.
16. 6 hydrocarbons during the polar sunrise 1992 experiment : Rvidence for Cl atom and Br atom chemistry. Journal of Geophysical Research 99, 25 355-25 368.
17. Le Bras, G., Platt, U., 1995. A possible mechanism for combined chlorine and bromine catalyzed destruction of tropospheric ozone in the Arctic. Geophysical Research Letters 22, 599-602.
18. Nava, D.F., Michael, J.V., Stief, L.J., 1981. Rate constant for the reaction of atomic bromine with formaldehyde from 223 to 480 K. Journal of Physical Chemistry 85, 1896-1899.
19. 3, ClO, BrO and IO in the troposphere. Faraday Discussions 100, 175-198.
20. Poulet, G., Laverdet, G., Le Bras, G., 1981. Discharge flow-mass spectrometric determination of the rate coefficients for the reactions of formaldehyde with bromine atoms and chlorine atoms. Journal of Physical Chemistry 85, 1892-1895.
21. 3 and global OH concentration. Science 269, 187-192.
22. Solberg, S., Hermansen, O., Joranger, E., Schmidtbauer, N., Stordal, F., Hov, O., 1994. NILU Report OR 27/94, ISBN 82-425-0575-6.
23. Ramacher, B., Rudolph, J., Koppmann, R., 1997. Hydrocarbon measurements in the spring Arctic troposphere during the ARCTOC 95 campaign. Tellus 49B, 446-465.
24. 9. Journal of Physical Chemistry 96, 9847-9855.
25. Solomon, S., Garcia, R.R., Ravishankara, A.R., 1994. On the role of iodine in ozone depletion. Journal of Geophysical Research 99, 20 491-20 499.
26. Stutz, J., Hebestreit, B., Alicke, B., Plett, U., 1998. Chemistry of halogen oxides in the troposphere: Comparison of model calculations with recent field data. Journal of Atmospheric Chemistry, submitted for publication.
27. Szilagyi, I., Dobe, S., Berces, T., Marta, F., 1996. Kinetic studies of the reactions of Br-atoms and OH-radicals with selected aldehydes and acylhalides. Poster Presentation at the "14th International Symposium on Gas Kinetics" from 7.-12. September 1996 in Leeds, Great Britain.
28. Wallington, T.J., Skewes, L., Siegl, W.O., Japar, S.M., 1989. A relative rate study of the reaction of bromine atoms with a variety of organic compounds at 295 K. International Journal of Chemical Kinetics 21, 1069-1076.
29. Yarwood, G., Peng, N., Niki, H., 1992. FTIR spectroscopic study of the Cl- and Br-atom initiated oxidation of ethene. International Journal of Chemical Kinetics 24, 369-383.