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0000134533
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Macrocycles of type 3 and 5 contain 9,9′-diphenyl-9,9′-bi[9H-fluorene] as a partial structure. For the conformational analysis of bifluorenyls, see also a) G. A. Olah, L. D. Field, M. I. Watkins, R. Malhotra, J. Org. Chem. 1981, 46, 1761;
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0001758475
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d) W. D. Hounshell, D. A. Dougherty, J. P. Hummel, K. Mislow, J. Am. Chem. Soc. 1977, 99, 1916.
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23
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0345659396
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unpublished results
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P. Schlaf, unpublished results; R. Hosseinzadeh, unpublished results.
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Schlaf, P.1
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24
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0344364733
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unpublished results
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P. Schlaf, unpublished results; R. Hosseinzadeh, unpublished results.
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Hosseinzadeh, R.1
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25
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0345659395
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note
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4 symmetrie is possible which leads to the observation of time-averaged NMR spectra. This information serves as the basis for assigning the structures of 3 and 5.
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26
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0344364735
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note
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1H NMR spectrum. The individual assignments of all signals is difficult as they are partially hidden by substituent absorptions or overlap which each other. Therefore, the low-field and high-field signals were used for the structure elucidation.
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27
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0344364734
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note
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-1.
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28
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0344796548
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note
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Of the six chemically different protons on each fluorene ring, two can be observed separately shifted towards high field.
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29
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84989479578
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Dissociation energies of 9,9′-bifluorenyl derivatives: K. Rakus, S.-P. Verevkin, J. Schätzer, H.-D. Beckhaus, C. Rüchardt, Chem. Ber. 1994, 127, 1095-1103; E. M. Arnett, S. Venimadhavan, J. Am. Chem. Soc. 1991, 113, 6967-6975.
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Rakus, K.1
Verevkin, S.-P.2
Schätzer, J.3
Beckhaus, H.-D.4
Rüchardt, C.5
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30
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85021621670
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Dissociation energies of 9,9′-bifluorenyl derivatives: K. Rakus, S.-P. Verevkin, J. Schätzer, H.-D. Beckhaus, C. Rüchardt, Chem. Ber. 1994, 127, 1095-1103; E. M. Arnett, S. Venimadhavan, J. Am. Chem. Soc. 1991, 113, 6967-6975.
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Arnett, E.M.1
Venimadhavan, S.2
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