Redox behavior of iron and vanadium ions in silicate melts at temperatures up to 2000 °C

Glass Science and Technology: Glastechnische Berichte

Volumn 72, Issue 5, 1999, Pages 153-160

  Leister, Michael ^a   Ehrt, Doris ^a  

^a FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; IONS; MELTING; QUENCHING; REDOX REACTIONS; THERMAL EFFECTS;

OPTICAL ABSORPTION SPECTROSCOPY; POLYVALENT IONS; REDOX EQUILIBRIUM; SILICATE MELTS; SQUARE WAVE VOLTAMMETRY;

FUSED SILICA;

EID: 0033121937     PISSN: 09467475     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (17)

1. Schreiber, H. D.; Kozak, S. J.; Fritchman, A. L.: Redox kinetics and oxygen diffusion in a borosilicate melt. Phys. Chem. Glasses 27 (1986) no. 4, p. 152-177.
2. 2 glasses. J. Am. Ceram. Soc. 48 (1965) no. 12, p. 608-611.
3. Ehrt, D.; Leister, M.; Matthai, A. et al.: Determination of the redox states of vanadium in glasses and melts by different methods. In: Fundamentals of Glass Science and Technology 1997. Proc. 4th Conf. European Society of Glass Science and Technology, Växjö 1997. Växjö: Glafo, 1997. p. 204-211.
4. Bates, T.: Ligand field theory and absorption spectra of transition-metal ions in glasses. In: Mackenzie, J. D. (ed.): Modern aspects of the vitreous state. Vol. 2. London: Butterworths, 1962.
5. Duffy, J. A.: Bonding, energy levels & bands in inorganic solids. Harlow: Longman Scientific & Technical, 1990.
6. Leister, M.; Ehrt, D.; Gönna, G. von der, et al.: Redox states and coordination of vanadium in sodium silicates melted at high temperature. Accepted for publication in Phys. Chem. Glasses.
7. Freude, E.; Rüssel, C.: Voltammetric methods for determing polyvalent ions. Glastech. Ber. 60 (1987) no. 6, p. 202-204.
8. Claußen, O.: Square-Wave Voltammetrie zur Bestimmung polyvalenter Ionen in Glasschmelzen. Friedrich-Schiller-Univ. Jena, Ph. D. thesis 1996.
9. 3+ in glass. Phys. Chem. Glasses 9 (1968) no. 3, p. 73-83.
10. Zirkelbach K.; Brückner, R.: Spectroscopic investigations of barium aluminophosphate glasses containing vanadium, iron and manganese oxides. Glastech. Ber. 60 (1987) no. 9, p. 312-323.
11. Cable, M.; Xiang Z. D.: Cuprous-cupric equilibrium in soda-lime-silica glasses melted in air. Phys. Chem. Glasses 30 (1989) no. 6, p. 237-242.
12. Johnston, W. D.: Oxidation-reduction equilibria in iron-containing glasses. J. Am. Ceram. Soc. 47 (1964) no. 4, p. 198-201.
13. Pyare, R.; Nath, P.: Kinetics and thermodynamics of ferrous-ferric equilibrium in sodium aluminoborate glasses. J. Non-Cryst. Solids 69 (1984) p. 59-67.
14. Schaeffer H. A.: Einsatz stabiler Isotope zur Diffusionsmessung in Gläsern. Glastech. Ber. 52 (1979) no. 7, p. 155-163.
15. 6+ equilibrium in binary alkali silicate glasses. Phys. Chem. Glasses 6 (1965) no. 6, p. 197-202.
16. Rüssel, C.: Redox reactions during cooling of glass melts - A theoretical consideration. Glastech. Ber. 62 (1989) no. 6, p. 199-203.
17. 3 doped soda-lime-silica glasses during cooling - A high-temperature ESR investigation. Glastech. Ber. 62 (1989) no. 10, p. 345-350.