[Me2AlBi(SiMe3)2]3 - The first structurally characterized organometallic compound containing a bond between an element of group 13 and Bi

Angewandte Chemie - International Edition

Volumn 38, Issue 7, 1999, Pages 967-968

  Schulz, Stephan ^a   Nieger, Martin ^a  

^a UNIVERSITY OF BONN   (Germany)

Author keywords

Aluminum; Bismuth; Main group elements

Indexed keywords

ALUMINUM; BISMUTH;

ARTICLE; CHEMICAL BINDING; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; INFRARED RADIATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHYSICAL PHASE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY ANALYSIS;

EID: 0033119646     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990401)38:7<967::AID-ANIE967>3.0.CO;2-C     Document Type: Article

References (36)

1. a) R. L. Wells, A. T. McPhail, M. F. Self, J. A. Laske, Organometallics 1993, 12, 3333;
2. b) R. L. Wells, R. A. Baldwin, P. S. White, W. T. Pennington, A. L. Rheingold, G. P. A. Yap, Organometallics 1996, 15, 91;
3. c) L. K. Krannich, C. L. Watkins, S. J. Schauer, C. H. Lake, Organometallics 1996, 15, 3980;
4. R. L. Wells, A. T. McPhail, L. J. Jones, M. L. Self, Polyhedron 1993, 12, 141;
5. e) J. F. Janik, R. L. Wells, V. G. Young, Jr., A. L. Rheingold, I. A. Guzei, J. Am. Chem. Soc. 1998, 120, 532;
6. f) S. M. Stuczynski, R. L. Opila, P. Marsh, J. G. Brennan, M. L. Steigerwald, Chem. Mater. 1991, 3, 379;
7. g) A. H. Cowley, R. A. Jones, Angew. Chem. 1989, 101, 1235;
8. Angew. Chem. Int. Ed. Engl. 1989, 28, 1208.
9. a) R. A. Baldwin, E. E. Foos, R. L. Wells, P. S. White, A. L. Rheingold, G. P. A. Yap, Organometallics 1996, 15, 5035;
10. b) R. L. Wells, E. E. Foos, P. S. White, A. L. Rheingold, L. M. Liable-Sands, Organometallics 1997, 16, 4771.
11. a) A. H. Cowley, R. A. Jones, C. M. Nunn, D. L. Westmoreland, Chem. Mater. 1990, 2, 221;
12. b) A. R. Barron, A. H. Cowley, R. A. Jones, C. M. Nunn, D. L. Westmorland, Polyhedron 1988, 7, 77;
13. c) A. H. Cowley, R. A. Jones, K. B. Kidd, C. M. Nunn, D. L. Westmorland, J. Organomet. Chem. 1988, 341, C1;
14. S. Schulz, T. Schoop, H. W. Roesky, L. Häming, A. Steiner, R. Herbst-Irmer, Angew. Chem. 1995, 107, 1015;
15. Angew. Chem. Int. Ed. Engl. 1995, 34, 1015.
16. a) S. Schulz, M. Nieger, Organometallics 1998, 17, 3398;
17. b) S. Schulz, M. Nieger, Organometallics 1999, in press.
18. a) C. M. Jones, M. D. Burkart, R. E. Bachman, D. L. Serra, S.-J. Hwu, K. H. Whitmire, Inorg. Chem. 1993, 32, 5136;
19. b) C. M. Jones, M. D. Burkart, K. H. Whitmire, Angew. Chem. 1992, 104, 466;
20. Angew. Chem. Int. Ed. Engl. 1992, 31, 451.
21. U. Wirringa, H. W. Roesky, M. Noltemeyer, H. G. Schmidt, Inorg. Chem. 1994, 33, 4607.
22. W. J. Evans, S. L. Gonzales, J. W. Ziller, J. Am. Chem. Soc. 1991, 113, 9880.
23. The absence of the Me resonance is not unusual for Me-substituted Al compounds.
24. The mass spectra of a single crystal did not show different peaks.
25. -3 (absorption effects). An empirical absorption correction was applied (min./max. transmission 0.2890/0.4466) Crystallographic data (exluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-106174. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge, CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
26. R. T. Sanderson, Chemical Bonds and Bond Energy, 2nd ed., Academic Press, New York, 1976, p. 67.
27. S. Schulz, M. Nieger, J. Organomet. Chem. 1998, 570, 275.
28. G. Cordier, H. Schäfer, M. Stelter, Z. Naturforsch. B 1984, 39, 727.
29. L. V. Interrante, G. A. Sigel, M. Garbauskas, C. Hejna, G. A. Slack, Inorg. Chem. 1989, 28, 252.
30. J. F. Janik, E. N. Duesler, W. F. McNamara, M. Westerhausen, R. T. Paine, Organometallics 1989, 8, 506.
31. J. F. Janik, R. L. Wells, P. S. White, Inorg. Chem. 1998, 37, 3561.
32. J. A. Laske Cooke, A. P. Purdy, R. L. Wells, P. S. White, Organometallics 1996, 15, 84.
33. T. Wartik, H. I. Schlesinger, J. Am. Chem. Soc. 1953, 75, 835.
34. G. Becker, M. Rößler, Z. Naturforsch. B 1982, 37, 91.
35. "SHELXS-90/96, Program for Structure Solution": G. M. Sheldrick, Acta Crystallogr. Sect. A 1990, 46, 467.
36. G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, Universität Göttingen, 1997.