Aqueous phase catalytic oxidation of phenol in a trickle bed reactor: Effect of the pH

Water Research

Volumn 33, Issue 4, 1999, Pages 1005-1013

  Miro C ^a   Alejandre, A ^a   Fortuny, A ^a   Bengoa, C ^a   Font, J ^a   Fabregat, A ^a  

^a UNIVERSITAT ROVIRA I VIRGILI   (Spain)

Author keywords

Copper catalyst; pH; Phenol oxidation; Trickle bed regime; Waste water; Wet oxidation

Indexed keywords

ALUMINA; CATALYST DEACTIVATION; CATALYST SUPPORTS; CATALYSTS; CHEMICAL REACTORS; COPPER; LEACHING; OXIDATION; PH EFFECTS; PHENOLS; SILICA;

CATALYTIC OXIDATION; COPPER CATALYSTS; TRICKLE BED REACTORS; WET OXIDATION;

WASTEWATER TREATMENT;

ALUMINUM OXIDE; COPPER DERIVATIVE; OXIDIZING AGENT; PHENOL; SILICON DIOXIDE;

AIR; ARTICLE; CATALYST; OXIDATION; PH; PRIORITY JOURNAL; REACTOR; WASTE WATER MANAGEMENT;

EID: 0033104580     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0043-1354(98)00296-6     Document Type: Article

References (38)

1. Alejandre A., Medina F., Fortuny A., Salagre P. and Sueiras J. E. (1998) Characterisation of copper catalysts and activity for the oxidation of phenol aqueous solutions. Appl. Catal. B Environ. 16, 53-67.
2. Baillot C. R., Faith B. M. and Masi O. (1982) Fate of specific pollutant during wet oxidation and ozonation. Environ. Prog. 1, 217-227.
3. 3. J. Photochem. Photobiol. A Chem. 81, 199-203.
4. Comninellis Ch. (1992) Electrochemical treatment of waste water containing phenol. Trans. I Chem. E 70(Part B), 219-224.
5. 2 anodes. J. Appl. Electrochem. 23, 108-112.
6. Devlin H. R. and Harris I. J. (1984) Mechanism of the oxidation of aqueous phenol with dissolved oxygen. Ind. Eng. Chem. Fundam. 23, 387-392.
7. Dietrich M. J., Randall T. L. and Canney P. J. (1985) Wet air oxidation of hazardous organics in wastewater. Environ. Prog. 4, 171-177.
8. Earhart J. P., Won K. W., Wong H. Y., Prausnitz J. M. and King C. J. (1977) Recovery of organic pollutants via solvent extraction. Chem. Eng. Prog. 73(5), 67-73.
9. Flynn B. L. and Flemington W. V. (1979) Wet air oxidation of waste streams. Chem. Eng. Prog. 75, 66-69.
10. Fortuny A., Ferrer C., Bengoa C., Font J. and Fabregat A. (1995) Catalytic removal of phenol from aqueous phase using oxygen or air as oxidant. Catal. Today 24, 79-83.
11. Gianetto A. and Specchia V. (1992) Trickle-bed reactors: state of art and perspectives. Chem. Eng. Science 47, 3197-3213.
12. Greminger D. C., Burns G. P., Lynn S., Hanson D. N. and King C. J. (1982) Solvent extraction of phenols from water. Ind. Eng. Chem. Process Des. Dev. 21, 51-54.
13. Gurol M. D. and Nekouinaini S. (1984) Kinetic behavior of ozone in aqueous solutions of substituted phenols. Ind. Eng. Chem. Fundam. 23, 54-60.
14. Gurol M. D. and Vatistas R. (1987) Oxidation of phenolic compounds by ozone and ozone + UV radiation: a comparative study. Water Res. 21, 895-900.
15. Joglekar H. S., Samant S. D. and Joshi J. B. (1991) Kinetics of wet air oxidation of phenol and substituted phenols. Water Res. 25, 135-145.
16. Kochetkova R. P., Babikov A. F., Shpilevskaya L. I., Shiverskaya I. P., Eppel S. A. and Shmidt F. K. (1992) Liquid phase catalytic oxidation of phenol. Chem. Technol. Fuels Oils 28, 225-229.
17. Lanouette K. H. (1997) Treatment of phenolic wastes. Chem. Eng. October 17, 99-106.
18. Lee S. H. and Carberry J. B. (1992) Biodegradation of PCP enhanced by chemical oxidation pretreatment. Water Environ. Res. 64, 682-690.
19. Levee J. (1990) Catalytic oxidation of toxic organics in aqueous solution. Appl. Catal. 63, L1-L5.
20. Lim P. K., Cha J. A. and Patel C. P. (1983) Aerobic coupling of aqueous phenol catalyzed by cuprous chloride: basis of a novel dephenolization scheme for phenolic wastewaters. Ind. Eng. Chem. Process Des. Dev. 22, 477-482.
21. Ohta H., Goto S. and Teshima H. (1980) Liquid-phase oxidation of phenol in a rotating catalytic basket reactor. Ind. Eng. Chem. Fundam. 19, 180-185.
22. Pintar A. and Levee J. (1992a) Catalytic oxidation of organics in aqueous solution. I. Kinetics of phenol oxidation. J. Catal. 135, 345-357.
23. Pintar A. and Levec J. (1992b) Catalytic liquid-phase oxidation of refractory organics in waste water. Chem. Eng. Sci. 47, 2395-2400.
24. Pintar A. and Levee J. (1994) Catalytic liquid-phase oxidation of phenol aqueous solutions: a kinetic investigation. Ind. Eng. Chem. Res. 33, 3070-3077.
25. Pruden B. B. and Le H. (1976) Wet air oxidation of soluble components in waste water. Can. J. Chem. Eng. 54, 319-325.
26. Sadana A. and Katzer J. R. (1974a) Catalytic oxidation of phenol in aqueous solution over copper oxide. Ind. Eng. Chem. Fundam. 13, 127-134.
27. Sadana A. and Katzer J. R. (1974b) Involvement of free radicals in the aqueous-phase catalytic oxidation of phenol over copper oxide. J. Catal. 35, 140-152.
28. 2. Kinet. Catal. 10, 832-836.
29. Shibaeva L. V., Metelitsa D. I. and Denisov E. T. (1969b) Oxidation of phenol with molecular oxygen in aqueous solutions. II. The role of hydrogen peroxide in the oxidation of phenol with oxygen. Kinet. Catal. 10, 1022-1026.
30. Singer P. C. and Gurol M. D. (1983) Dynamics of the ozonation of phenol. I. Experimental observations. Water Res. 17, 1163-1171.
31. Susnitzky D. W. and Barry Carter C. (1991) The formation of copper aluminate by solid-state reaction. J. Mater. Res. 6, 1958-1963.
32. Thornton T. D. and Savage P. E. (1992a) Phenol oxidation pathways in supercritical water. Ind. Eng. Chem. Res. 31, 2451-2456.
33. Thornton T. D. and Savage P. E. (1992b) Kinetics of phenol oxidation in supercritical water. AIChE J. 38, 321-327.
34. Tukac V. and Hanika J. (1995) Purification of phenolic waste waters by catalytic oxidation. Collect. Czech. Chem. Commun. 60, 482-488.
35. Wang Y. T. (1992) Effect of chemical oxidation on anaerobic biodegradation of model phenolic compounds. Water Environ. Res. 64, 268-273.
36. Wei T.-Y. and Wan C.-C. (1991) Heterogeneous photocatalytic oxidation of phenol with titanium dioxide powders. Ind. Eng. Chem. Res. 30, 1293-1300.
37. Wilhelmi A. R. and Knopp P. V. (1979) Wet air oxidation: an alternative to incineration. Chem. Eng. Progress 75, 46-52.
38. Norme Française NFT90-101 Octobre 1988 (ISSN 0335-3931). Essais des Eaux: Détermination de la Demande Chimique en Oxygène.