Fluoropolyethers End-Capped by Polar Functional Groups. I. Kinetic Approach to the Reaction of Hydroxy-Terminated Fluoropolyethers with Cycloalyphatic and Aromatic Diisocyanates

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 37, Issue 5, 1999, Pages 557-570

  Mashlyakovskiy, Leonid ^a   Zaiviy, Vladimir ^a   Simeone, Giovanni ^b   Tonelli, Claudio ^b  

^a ST PETERSBURG STATE INSTITUTE OF TECHNOLOGY TECHNICAL UNIVERSITY   (Russian Federation)

^b Ausimont SpA   (Italy)

Author keywords

Catalyzed reactions with diisocyanates; Diisocyanate terminated fluoropolyether oligourethane macromers; H12MDI; Hydroxy terminated fluoropolyethers; IPDI; Kinetics; TDI

Indexed keywords

CATALYSIS; FLUORINE CONTAINING POLYMERS; INFRARED SPECTROSCOPY; KETONES; MOLECULAR STRUCTURE; ORGANIC SOLVENTS; REACTION KINETICS; SOLUBILITY;

ETHYL ACETATE; FLUOROPOLYETHERS; HEXAFLUOROXYLENE; METHYL ISOBUTYL KETONE;

POLYETHERS;

EID: 0033100457     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(19990301)37:5<557::AID-POLA6>3.0.CO;2-I     Document Type: Article

References (48)

1. Lynn, M. M.; Worm, A. T. Encyclopedia of Polymer Science Engineering; Kroschwitz, J. I., Ed.; Interscience: New York, 1987; Vol. 7, p 256.
2. Chambers, R. D. Fluorine in Organic Chemistry; Wiley Interscience Publication: London, 1973; p 5.
3. Plunkett, R. J. U.S. Pat. 2230654 (Kinetic Chemicals Inc.), 1941.
4. Bro, M. I.; Sandt, B. W. U.S. Pat. 2946763 (Du Pont de Nemours), 1960.
5. Carlson, D. P. U.S. Pat. 3536733 (Du Pont de Nemours), 1970.
6. Hecht, J. L. U.S. Pat. 3265678 (Du Pont de Nemours), 1966.
7. Dohany, J. E., Humphry, J. S., Kroschwitz, J. I., Eds. Encyclopedia of Polymer Science and Engineering, 2nd ed. (ed. Mark, Bikales, Overberger, Menges); Interscience: New York, 1989; Vol. 17; p 532.
8. Brit. Pat. 465520 (I. G. Farbenindustrie), 1937.
9. Apotheker, D.; Finlay, J. B.; Krusic, P. J.; Logothetis, A. L. Rubber Chem Technol 1982, 55, 1004.
10. Oka, M.; Tatemoto, M. Contemporary Topics in Polymer Science, Vol. 4, Plenum Press: New York, 1984; Vol. 4, p 763.
11. Silastic, Dow, Fluorosilicone Rubbers Technical Bulletin.
12. Tate, D. P. J Polym Sci Polym Symp 1974, 48, 33.
13. Sianesi, D.; Pasetti, A.; Belardinelli, G. U.S. Pat. 4451646 (Montedison), 1984.
14. Marchionni, G.; Ajroldi, G.; Pezzin, G. Comprehensive Polymer Science; 1997; Chapter 9, p 347.
15. Pilati, F.; Toselli, M.; Vallieri, A.; Tonelli, C. Polym Bull 1992, 28, 151.
16. Toselli, M.; Pilati, F.; Fusari, M.; Tonelli, C.; Castiglioni, G. J Appl Polym Sci 1994, 54, 2101.
17. Mascia, L.; Zitouni, F.; Tonelli, C. Polym Eng Sci 1995, 35, n. 13, 1069.
18. Tonelli, C.; Trombetta, T.; Scicchitano, M.; Castiglioni, G. J Appl Polym Sci 1995, 57, 1031.
19. Tonelli, C.; Trombetta, T.; Scicchitano, M.; Simeone, G.; Ajroldi, G. J Appl Polym Sci 1996, 59, 311.
20. Sbarbari del Guerra, R.; Lelli, L.; Tonelli, C.; Trombetta, T.; Cascone, M. G.; Narducci, P.; Giusti, P. J Mater Sci: Mater Med 1994, 5, 452.
21. Mitsch, R. A.; La Mar Zollinger, J. U.S. Pat. 805885 (3M), 1969.
22. Saunders, J. H.; Frish, K. F. Polyurethanes. Chemistry and Technology, Part 1 Chemistry; Interscience Publishers: New York, London, 1962; p 368.
23. Cunliffe, A. V.; Davis, A.; Farey, M.; Wrifht, J. Polymer 1985, 26, 301.
24. Schwetlick, K.; Noack, R.; Stebner, F. J Chem Soc, Perkin Trans 1994, 2, 599.
25. Schwetlick, K.; Noack, R. J Chem Soc Perkin Trans 1995, 2, 395.
26. Berlin, P. A.; Tiger, R. P.; Chirkov, Ju N.; Entelis, S. G. Kinet Catal 1987, 28, 1354.
27. Tondeur, J. J.; Vandendunghen, G.; Watelet, M. J Chem Res, Synop 1992, 262.
28. Tondeur, J. J.; Vandendunghen, G.; Watelet, M. J Chem Res, Synop 1992, 398.
29. Chirkov, Ju. N.; Tiger, R. P.; Entelis, S. G.; Tondeur, J. J. Kinet Catal 1995, 36, 612.
30. Reegen, S. L.; Frisch, K. S. J Polym Sci 1966, 4, A-1, 2321.
31. Squiller, E. P.; Rosthauser, J. Mod Paint Coat 1987, No. 6.
32. Seneker, S. D.; Potter, T. A. J Coatings Technol 1991, 63, No. 793, 19.
33. Marchionni, G.; Ajroldi, G.; Cinquina, P.; Tampellini, E.; Pezzin, G. Polym Eng Sci 1990, 30, 829.
34. Marchionni, G.; Ajroldi, G.; Righetti, M. C.; Pezzin, G. Macromolecules 1993, 26, 1751.
35. Staccione, A.; Ajroldi, G.; Marchionni, G.; Rebosio, L. J Polym Sci, Part B: Polym Phys 1997, 35, 2073.
36. Gianotti, G.; Levi, M.; Turri, S. J Appl Polym Sci 1994, 51, 973.
37. Cantow, M. J. R. Polymer fractionation; Academic Press: New York, London, 1967.
38. Turri, S.; Scicchitano, M.; Gianotti, G.; Tonelli, C. Eur Polym J 1995, 31, N. 12, 1227.
39. Frisch, K. C.; Reegen, S. L.; Thir, B. J Polym Sci, Part C 1967, 5, 2191.
40. Frisch, K. C.; Reegen, S. L.; Floutz, W. V.; Oliver, J. P. J Polym Sci, Part A: Polym Chem 1967, 5, 35.
41. Entelis, S. G.; Nesterov, O. V. Kinet Katal 1966, 7, 464.
42. Nesterov, O. V.; Zabrodin, V. B.; Chirkov, Yu N.; Entelis, S. G. Kinet Katal 1966, 7, 805.
43. Smith, H. A. J Appl Polym Sci 1963, 7, 85.
44. Baker, J. W.; Davies, M. M.; Gaunt, J. J Chem Soc 1949, 24.
45. Baker, J. W.; Holdsworth, J. B. J Chem Soc 1947, 713.
46. Baker, J. W.; Gaunt, J. J Chem Soc 1949, 9, 19, 29.
47. Hager, S. L. Polym Prepr 1980, 21, No. 2, 12.
48. Saifulin, A. S. Plast Massy 1988, No. 11, 11.