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Volumn 38, Issue 3, 1999, Pages 343-346

Kinetics and mechanisms of the reactions of π-allylpalladium complexes with nucleophiles

Author keywords

Allyl complexes; Carbocations; Kinetics; Palladium; Reaction mechanisms

Indexed keywords

PALLADIUM COMPLEX;

EID: 0033083563     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990201)38:3<343::AID-ANIE343>3.0.CO;2-X     Document Type: Article
Times cited : (66)

References (33)
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    • (1998)
    • Kuhn, O.1
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    • 4243514930 scopus 로고
    • In contrast, the first slep of the aminations of allylpalladium complexes containing stronger donor ligands (chloride, amines) is reversible, and the deprotonation of the allylammonium ions (e.g. 5) becomes rate-determining, resulting in a second-order dependence of the rates on amine concentration: A. Vitagliano, B. Åkermark. J. Organomet. Chem. 1988, 349, C22-C26.
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    • note
    • The solvent dependence of the reactions of cationic electrophiles with neutral nucleophiles was shown in Table 1 of ref. [3a].
  • 24
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    • a) Tricarbonyldienyliron cations: H. Mayr, K.-H. Müller, D. Rau, Angew. Chem. 1993, 105, 1732-1734; Angew. Chem. Int. Ed. Engl. 1993, 32, 1630-1632;
    • (1993) Angew. Chem. , vol.105 , pp. 1732-1734
    • Mayr, H.1    Müller, K.-H.2    Rau, D.3
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    • a) Tricarbonyldienyliron cations: H. Mayr, K.-H. Müller, D. Rau, Angew. Chem. 1993, 105, 1732-1734; Angew. Chem. Int. Ed. Engl. 1993, 32, 1630-1632;
    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 1630-1632
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    • b) ferrocenylmethylium ions: H. Mayr, D. Rau, Chem. Ber. 1994, 127, 2493-2498;
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    • Mayr, H.1    Rau, D.2
  • 30
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    • note
    • 2): δ = 1.98 (d, J = 7.3 Hz, 2 H, 4-H), 3.14 -3.47 (m, 2 H, 1-H-anti, 3-H-anti), 4.02 (d, J = 6.8 Hz, 2 H, 1-H-syn, 3-H-syn), 5.33 - 5.46 (m, 1 H, 2-H), 6.21 (d, J = 15.7 Hz, 1 H, 6-H), 6.41 -6.52 (m, 1 H, 5-H), 7.11 - 7.45 (m. Ph).
  • 32
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    • b) A. Goliaszewski, J. Schwartz, Tetrahedron 1985, 24, 5779-5789; see also: B. Henc, P. W. Jolly, R. Salz, S. Stobbe, G. Wilke, R. Benn, R. Mynott, K. Seevogel, R. Goddard, C. Krüger, J. Organomet. Chem. 1980, 191, 449-475.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.