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Volumn 38, Issue 3, 1999, Pages 331-335

HCSiF and HCSiCl: The first detection of molecules with formal C≡Si triple bonds

Author keywords

Ab initio calculations; Mass spectrometry; Silicon; Silynes

Indexed keywords

SILICON DERIVATIVE;

EID: 0033083442     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19990201)38:3<331::aid-anie331>3.0.co;2-8     Document Type: Article
Times cited : (37)

References (49)
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    • For comprehensive reviews, see: a) The Chemistry of Organic Silicon Compounds (Eds.: S. Patai, Z. Rappoport), Wiley, New York, 1989; b) The Chemistry of Organic Silicon Compounds, Vol. 2 (Eds.: Z. Rappoport, Y. Apeloig), Wiley, New York, 1998.
    • (1989) The Chemistry of Organic Silicon Compounds
    • Patai, S.1    Rappoport, Z.2
  • 2
    • 0003670973 scopus 로고    scopus 로고
    • Wiley, New York
    • For comprehensive reviews, see: a) The Chemistry of Organic Silicon Compounds (Eds.: S. Patai, Z. Rappoport), Wiley, New York, 1989; b) The Chemistry of Organic Silicon Compounds, Vol. 2 (Eds.: Z. Rappoport, Y. Apeloig), Wiley, New York, 1998.
    • (1998) The Chemistry of Organic Silicon Compounds , vol.2
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    • 0001536931 scopus 로고    scopus 로고
    • (Eds.: Z. Rappoport, Y. Apeloig), Wiley, New York
    • b) H. Sakurai in The Chemistry of Organic Silicon Compounds, Vol. 2 (Eds.: Z. Rappoport, Y. Apeloig), Wiley, New York, 1998, p. 827;
    • (1998) The Chemistry of Organic Silicon Compounds , vol.2 , pp. 827
    • Sakurai, H.1
  • 14
    • 33748574465 scopus 로고
    • G. Maier, J. Glatthaar, Angew. Chem. 1994, 106, 486; Angew. Chem. Int. Ed. Engl. 1994, 33, 473.
    • (1994) Angew. Chem. Int. Ed. Engl. , vol.33 , pp. 473
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    • note
    • [13]
  • 28
    • 0005483231 scopus 로고    scopus 로고
    • 2,Si] at other levels of theory, see: a) M. T. Nguyen, D. Sengupta, L. G. Vanquickenborne, Chem. Phys. Lett. 1995 244. 83; b) R. Stegmann, G. Frenking, J. Comput. Chem. 1996, 17, 78.
    • (1996) J. Comput. Chem. , vol.17 , pp. 78
    • Stegmann, R.1    Frenking, G.2
  • 36
    • 0345538350 scopus 로고    scopus 로고
    • note
    • The term "formal" pays tribute to the fact that the silynes have bent structures, unlike the linear arrangements expected for triple bonds: for a more detailed discussion see ref. [9].
  • 38
    • 0000411401 scopus 로고    scopus 로고
    • (Eds.: Z. Rappoport, Y. Apeloig), Wiley, New York
    • 1]: D(C-H) = 105, D(C-F) = 113, D(C-Cl) = 83, D(Si-H) = 92, D(Si-F) = 152, D(Si-Cl) = 110. Data from: a) S. G. Lias, J. E. Bartmess, J. F Liebman, J. E. Holmes, R. D. Levin, W. G. Mallard, J. Phys. Chem. Ref. Data Suppl. 1 1988, 17; b) R. Becerra, R. Walsh in The Chemistry of Organic Silicon Compounds, Vol. 2 (Eds.: Z. Rappoport, Y. Apeloig), Wiley, New York, 1998, p. 153.
    • (1998) The Chemistry of Organic Silicon Compounds , vol.2 , pp. 153
    • Becerra, R.1    Walsh, R.2
  • 39
    • 0345538348 scopus 로고    scopus 로고
    • note
    • [21c] All spectra were accumulated and on-line processed with the AMD/Intectra data system: in general 5 to 50 spectra were averaged to improve the signal-to-noise ratio.
  • 45
    • 0344676119 scopus 로고    scopus 로고
    • note
    • In analogy, photolysis of 4 (X = Cl) has been speculated to yield neutral 1c, see ret. [7].
  • 48
    • 0344244608 scopus 로고    scopus 로고
    • note
    • -: data taken from refs. [19a,b,27].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.