Emulsion Polymerization of an Epoxy-Acrylate Emulsion Stabilized with Polyacrylate. I. Influence of Salt, Initiator, Neutralizing Amine, and Stirring Speed

Journal of Applied Polymer Science

Volumn 71, Issue 8, 1999, Pages 1347-1360

  De Wet Roos, D ^a   Knoetze, J H ^a   Cooray, B ^b   Sanderson, R D ^a  

^a STELLENBOSCH UNIVERSITY   (South Africa)

^b Group Head Office   (South Africa)

Author keywords

Can coating; Conversion; Emulsion polymerization; Epoxy acrylate; Particle size; Polydispersity; Statistically designed experiments

Indexed keywords

AMINES; COMPOSITION EFFECTS; ELECTROSTATICS; EMULSION POLYMERIZATION; EPOXY RESINS; INITIATORS (CHEMICAL); PARTICLE SIZE ANALYSIS; POLYACRYLATES; SALTS; STABILIZERS (AGENTS);

POLYDISPERSITY;

PLASTIC COATINGS;

EID: 0033078317     PISSN: 00218995     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1097-4628(19990222)71:8<1347::aid-app14>3.0.co;2-1     Document Type: Article

References (28)

1. Allen, R. A.; Scott, L. W. U.S. Pat. 4,098,744 (1978).
2. Allan, R. A.; Scott, L. W. U.S. Pat, 4,098,844 (1978).
3. Evans, J. M.; Ting, V. M. U.S. Pat. 4,212,781 (1980).
4. Georgalas, N.; Keaveney, W. P. U.S. Pat. 4,341,678 (1982).
5. Dante, M. F.; Allan, R. A. U.S. Pat. 4,316,003 (1982).
6. Richardson, F. Paint and Resin, October 1986,15-25.
7. Galgoci, E. C.; Kumar, P. C. Proceedings of the Water-Borne Higher Solids Powder Coatings Symposium 1994, 21st, 54-64.
8. Bozzi, E. G. Modern Paints and Coatings 1977, 67, 57-58.
9. Darwen, S. Eur Polym Paint and Colour J 1994, 184, 65-67.
10. Ragupathy, K. Bull Electrochem 1986, 2, 361-362.
11. Elmore, J. D.; Dickman, H. T. Proceedings of the Water-Borne Higher Solids Coating Symposium 1980, 7th 86-106.
12. Woo, J. T. K.; Ting, V.; Evans, J.; Marcinko, R.; Carlson, G.; Ortiz, C. J Coat Technol 1982, 54, 41-55.
13. Isozaki, O. European Pat. 0,384,338 (1990).
14. Kojima, S.; Moriga, T.; Gotoh, H. Proceedings of the Water-Borne and Higher-Solids, and Powder Coatings Symposium, February 26-28, New Orleans, LA, USA, 146-152, 1993.
15. Hidalgo-Alvarez, R.; Martin, A.; Fernandez, A.; Bastos, D.; Martinez, F.; de las Nieves, F. J. Adv Colloid Inter Sci 1996, 67, 1-118.
16. Atkins, P. W. Physical Chemistry, 3rd ed.; Oxford University Press, Oxford, 1986.
17. El-Aasser, M. S. Advances in Emulsion Polymerization and Latex Technology, 27th Annual Short Course, Vol. 2; 1996, pp. 1-32.
18. Gilbert, R. G. Emulsion Polymerization, A Mechanistic Approach; 1995.
19. Morgan, E. Chemometrics: Experimental Design; John Wiley and Sons: Chichester, West Sussex, 1995 (published on behalf of ACOL).
20. Khuri, A. I.; Cornell, J. A. 1996, Response Surfaces, Design and Analysis, 2nd ed., revised and expanded; Marcel Dekker, New York.
21. de Wet-Roos, D.; Knoetze, J. H.; Cooray, B. Submitted.
22. Bamford, C. H.; Jenkins, A. D.; Johnston, R.; White, E. F. T. Transact Faraday Soc 1959, 55, 168-178.
23. Bamford, C. H.; White, E. F. T. Transact Faraday Soc 1956, 52, 716-726.
24. Nomura, M. J Appl Polym Sci 1981, 26, 17-26.
25. Casey, B. S.; Morrison, B. R.: Maxwell, I. A.; Gilbert, R. G.; Napper, D. H. J Polym Sci Part A: Polym Chem 1994, 32, 605-630.
26. Asua, J. M.; de La Cal, J. C. J Appl Polym Sci 1991, 42, 1869-1877.
27. Asua, J. M.; Rodriguez, V. S.; Sudol, E. D.; El-Aasser, M. S. J Polym Sci: Part A: Polym Chem 1989, 27, 3569-3587.
28. Nomura, M.; Ikoma, J.; Fujita, K. J Polym Sci: Part A: Polym Chem 1993, 31, 2103-2113.