The crystal structure of a low-silica dehydrated NaX zeolite

European Journal of Mineralogy

Volumn 11, Issue 2, 1999, Pages 333-343

  Porcher, Florence ^a   Souhassou, Mohamed ^a   Dusausoy, Yves ^a   Lecomte, Claude ^a  

^a Nancy University CNRS   (France)

Author keywords

Cation distribution; Crystal structure; Dehydrated zeolite NaX; Faujasite type; Si Al ordering

Indexed keywords

ALUMINUM COMPOUNDS; CHEMICAL ANALYSIS; COPPER METALLOGRAPHY; CRYSTAL STRUCTURE; POSITIVE IONS; SILICA; SILICON WAFERS; SINGLE CRYSTALS; SODIUM COMPOUNDS; ZEOLITES;

CATION DISTRIBUTIONS; CHEMICAL COMPOSITIONS; FAUJASITES; MICRO-PROBES; NMR ANALYSIS; SYNTHETIC ANALOGUES; TETRAHEDRAL SITES; ZEOLITE NAX;

CRYSTAL SYMMETRY;

CRYSTAL STRUCTURE; ZEOLITE;

EID: 0033066084     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/ejm/11/2/0333     Document Type: Article

References (29)

1. Blessing, R.H. (1989): Data reduction and error analysis for single crystal diffractometer data (DREADD). J. Appl. Cryst., 22, 396-397.
2. Calestani, G., Bacca, G., Andretti, G.D. (1987): Structural study of zeolite X exchanged with f transition elements. I. Crystal structure of reference hydrated Na-X. Zeolites, 7, 4-58.
3. 23Na NMR spectrum of hydrated NaY zeolite. Zeolites, 11, 265-269.
4. Charnell, J. (1971): Gel growth of large crystals of sodium A and sodium X zeolites. J. Cryst. Growth, 8, 291.
5. Eulenberger, G.R., Shoemaker, D.P., Keil, J.G. (1967): The crystal structure of hydrated and dehydrated synthetic zeolites with faujasite aluminosilicate frameworks. The dehydrated sodium, potassium, and silver forms. J. Phys. Chem., 71, 1812-1819.
6. Fyfe, C.A., Gobbi, G.C., Hartman, J.S., Klinowski, J., Thomas, J.M. (1982): Solid-state magic-angle spinning aluminium-27 nuclear magnetic resonance studies of zeolites using a 400-MHz high-resolution spectrometer. J. Phys. Chem., 86, 1247-1250.
7. Gabe, E J., Lepage, Y., Charland, J.P., Lee, F.L., White, P.S. (1989): An interactive program system for structure analysis. J. Appl. Cryst., 22, 384-387.
8. Ghermani, N.E., Lecomte, C., Dusausoy, Y. (1996): Electrostatic properties in zeolite-type materials from high-resolution X-ray diffraction: The case of natrolite. Phys. Rev., B53, 9, 5231.
9. + exchanged zeolite X. Zeolites, 18, 325-333.
10. Klinowski. J. (1991): Solid-state NMR studies of molecular sieve catalysts. Chem. Rev., 91, 1459-1479.
11. Klinowski, J., Subramaniam, R., Thomas, J. M. (1982): A re-examination of Si. Al ordering in zeolites NaX and NaY. J. Am. Chem. Soc., Faraday Trans. 2, 78, 1025-1050.
12. Lievens, J. L., Mortier, W. J., Chaos, K. J. (1992): Cation site energies in high silica FAU-type zeolites. J. Phys. Chem. Solids, 53, 1163-1169.
13. 29Si NMR spectroscopy. J. Am. Chem. Soc., 103, 4992-4996.
14. Löwenstein, W. (1954): The distribution of aluminum in the tetrahedra of silicates and aluminates. Am. Mineral., 39, 92.
15. Mortier, W.J., Van den Bossche, E., Uytterhoeven, J. B. (1984): Influence of the temperature and water adsorption on the cation location in Na-Y zeolites. Zeolites, 4, 41-44.
16. Olson, D.H. (1970): A reinvestigation of the crystal structure of the zeolite hydrated NaX. J. Phys. Chem., 74, 2758-2764.
17. _ (1995): The crystal structure of dehydrated NaX. Zeolites, 15, 439-443.
18. Pluth, J.J. & Smith, J. V. (1980): Accurate redetermination of crystal structure of dehydrated Zeolite A. Absence of near zero coordination of sodium. Refinement of Si, Al-ordered superstructure. J. Am. Chem. Soc., 102, 4704-4708.
19. Porcher, F., Souhassou, M., Dusausoy, Y., Lecomte, C. (1998): Structure cristalline sur monocristal de la zéolithe LiA totalement échangée et déshydratée. Compt. Rend. Acad. Sci. Paris, Sér. II, Tome 1, no 11, fascicule C, 701-708.
20. 92-X. Bull. Korean Chem. Soc., 16, 539-542.
21. Shannon, R.D. (1976): Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Cryst., A32, 761-767.
22. Smolin, Y.I., Shepelev, Y.F., Butikova, I.K., Petranovskii, V. P. (1983): The crystal structure of Na-X zeolite in hydrated and dehydrated forms. Sov. Phys. Cristallogr., 28, 36-39.
23. Smolin, Y.I., Shepelev, Y.F., Butikova, I.K., Zhdanov, S.P., Samulevitch, N. N. (1979): The crystal structure of hydrated zeolite NaX at t = 20 and -165°C. Sov. Phys. Cristallogr., 24, 266-270.
24. Ståhl, K. & Hanson, J. (1994): Real-time X-ray synchrotron powder diffraction studies of the dehydration processes in scolecite and mesolite. J. Appl. Cryst., 27, 543-550.
25. Sun, T., Seff, K., Ho Heo, N., Petranovskii, V.P. (1994): A cationic cesium continuum in zeolite X. J. Phys. Chem., 98, 5768-5772.
26. Takaishi, T. (1996): Ordered distribution of Na ions in dehydrated NaX zeolite. Zeolites, 17, 389-392.
27. Van Dun, J.J., Dhaeze, K., Mortier, W.J. (1988): Temperature dependent cation distribution in zeolites. II. Dehydrated NaxH-Y (x = 13, 23, 42 and 54), Ca15H-Y and Sr27Y. J. Phvs. Chem., 92, 6747-6754.
28. Van Dun, J.J., Dhaeze, K., Mortier, W.J., Vaughan, D.E.W. (1989): The influence of isomorphous substitution on the cation distribution in faujasite type zeolites: the structures of dehydrated Na-LZ210 and hydrated KgaY. J. Phys. Chem. Solids, 50, 469-477.
29. Van Dun, J.J. & Mortier, W.J. (1988): Temperature dependent cation distribution in zeolites. I. A statistical thermodynamical model. J. Phys. Chem., 92, 6740-6746.