Ring a functionalization of terpenoids by the unusual Baeyer-Villiger rearrangement of aliphatic aldehydes

Synlett

Volumn , Issue 6, 1999, Pages 713-716

  Barrero, Alejandro F ^a   Alvarez Manzaneda, E J ^a   Alvarez Manzaneda, R ^b   Chahboun, Rachid ^a   Mencses, R ^a   Marta Aparicio, B ^b  

^a UNIVERSITY OF GRANADA   (Spain)

^b UNIVERSITY OF ALMERÍA   (Spain)

Author keywords

Baeyer Villiger rearrangement; Nor Terpenes

Indexed keywords

18 NORABIETA 8,11,13 TRIENE 4,7ALPHA DIOL; 4 HYDROXY 18 NORABIETA 8,11,13 TRIEN 7 ONE; ABIETIC ACID; TERPENOID DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CARBOHYDRATE SYNTHESIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; REACTION ANALYSIS;

EID: 0033037348     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1999-2722     Document Type: Article

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17. 3 and brine, and then it was dried and concentrated under reduced pressure to give the wor-olefin.
18. 3) δ : 36.1* (C-1), 23.6 (C-2), 38.4* (C-3), 70.7 (C-4), 46.3 (C-5), 32.3 (C-6), 70.4 (C-7), 137.9 (C-8), 144.5(C-9), 39.7 (C-10), 124.9 (C-11), 125.3 (C-12), 146.6 (C-13), 125.7 (C-14), 33.8 (C-15), 23.9 (C-16), 24.1 (C-17), 23.6 (C-19), 22.9 (C-20) (*: interchangeable signals).