Efficient radical coupling of organobromides using dimanganese decacarbonyl

Synthetic Communications

Volumn 29, Issue 15, 1999, Pages 2711-2718

  Gilbert, Bruce C ^a   Lindsay, Chris I ^b   McGrail, P Terry ^b   Parsons, Andrew F ^a   Whittaker, David T E ^a  

^a UNIVERSITY OF YORK   (United Kingdom)

^b AKZO NOBEL CENTRAL RESEARCH   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

LITHIUM DERIVATIVE; MANGANESE DERIVATIVE; ORGANOBROMINE DERIVATIVE;

ARTICLE; BROMINATION; COST; ORGANIC CHEMISTRY; REACTION ANALYSIS; REDUCTION; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0033036003     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1080/00397919908086433     Document Type: Article

References (21)

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12. Purchased from Aldrich Chemical Company.
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14. For radical generation using dimanganese decarbonyl see (i) Herrick, R.S.; Herrinton, T.R.; Walker, H.W. and Brown, T.L. Organometallics, 1985, 4, 42; Wrighton, M.S. and Ginley, D.S. J. Am. Chem. Soc. 1975, 97, 2065.
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16. 2) shifting to lower frequency. This is consistent with reduced back-bonding due to the CO ligands.
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