Soluble iron sulfide species in natural waters: Reappraisal of their stoichiometry and stability constants

Aquatic Sciences

Volumn 61, Issue 1, 1999, Pages 23-43

  Davison, William ^a   Phillips, Noel ^a   Tabner, Brian J ^a  

^a LANCASTER UNIVERSITY   (United Kingdom)

Author keywords

Freshwater; Iron; Iron sulfide; Seawater; Solubility; Solubility product; Speciation; Stability constant; Sulfide

Indexed keywords

EID: 0033030615     PISSN: 10151621     EISSN: 14209055     Source Type: Journal    
DOI: 10.1007/s000270050050     Document Type: Article

References (38)

1. Allison, J.D., D.S. Brown and K.J. Novo-Gradac, 1991. MINTEQA2/PRODEFA2, a geochemical assessment model for environmental systems. USEPA, Washington, EPA/600/3-91/021.
2. Berner, R.A., 1967. Thermodynamic stability of sedimentary iron sulfides. Am. J. Sci., 265: 773-785.
3. 2 and S(-II) in porewaters of marine and freshwater sediments. Environ. Sci. Technol., 29: 751-761.
4. Buffle, J., O. Zali, J. Zumstein and R. DeVitre, 1987. Analytical methods for the direct determination of inorganic and organic species: seasonal changes of iron, sulfur, and pedogenic and aquogenic organic constituents in the eutrophic Lake Bret, Switzerland. Sci. Total Environ., 64: 41-59.
5. Buffle, J., R.R. DeVitre, Perret, D. and G.G. Leppard, 1988. Combining field measurements for speciation in non perturbable water samples. In: Metal Speciation: Theory, Analysis and Application (ed. J.R. Kramer and H.E. Allen) Lewis, Chelsea MI, pp 99-124.
6. Daskalakis, K.D. and G.R. Helz, 1993. The solubility of sphalerite (ZnS) in sulfidic solutions at 25°C and 1 atm pressure. Geochim. Cosmochim. Acta 57: 4923-4931.
7. 2- in hypolimnetic water. Limnol. Oceanogr. 22: 746-753.
8. Davison, W., 1990. A practical guide to pH measurement in freshwaters. Tr. Anal. Chem., 9: 80-83.
9. Davison, W., 1991. The solubility of iron sulphides in synthetic and natural waters at ambient temperature. Aquat. Sci. 35: 309-329.
10. Davison, W., 1993. Iron and manganese in lakes. Earth Sci. Rev. 34: 119-163.
11. 2+ by voltammetric methods". Environ. Sci. Technol., 30: 3638-3639.
12. Davison, W., J. Buffle and R.R. DeVitre, 1998. Voltammetric characterization by laboratory and field studies of a dissolved iron sulphide species. Anal Chim. Acta, in press.
13. DeVitre, R.R., 1986. Multimethod characterization of the forms of iron, manganese, and sulphur in an eutrophic lake (Bret, Vaud, Switzerland). Ph.D. dissertation, Univ. of Geneva, Switzerland.
14. DiToro, D.M., J.D. Mahony, D.J. Hansen, K.J. Scott, M.B. Hicks, S.M. Mayr and M.S. Redmond, 1990. Toxicity of cadmium in sediments: the role of acid volatile sulfide. Environ. Tox. and Chem. 9, pp 1487-1502.
15. Douabul, A.A. and J.P. Riley, 1979. The solubility of gases in distilled water and seawater, V. Hydrogen sulphide. Deep-Sea Res. 26A: 259-268.
16. Dyrssen, D., 1985. Metal complex formation in sulphidic seawater. Mar. Chem. 24: 143-153.
17. Dyrssen, D., 1988. Sulfide complexation in surface seawater. Mar. Chem. 24: 143-153.
18. Elliott, S., 1988. Linear free energy techniques for the estimation of metal sulfide complexation constants. Mar. Chem. 24: 203-213.
19. Heaney, S.I. and W. Davison, 1977. The determination of ferrous iron in natural water with 2,2' bipyridyl. Limnol. Oceanogr., 22: 753-760.
20. Helz, G.R., J.M. Charnock, D.J. Vaughan and C.D. Garner, 1993. Multinuclearity of aqueous copper and zinc bisulfide complexes: an EXAFS investigation. Geochim. Cosmochim. Acta 57: 15-25.
21. Jacobs, L., Emerson, S. and Skei, J., 1985. Partitioning and transport of metals across the Oy1H2S interface in a permanently anoxic basin: Framvaren Fjord, Norway. Geochim. Cosmochim. Acta, 49: 1433-1444.
22. Khodakovskii, I.P., 1966. On the hydrosulphide form of heavy metal transportation in hydrothermal solutions. Geokhimiya 7: 960-971.
23. Landing, W.M. and Westerlund, S., 1988. The solution chemistry of iron (II) in Framvaren Fjord. Mar. Chem. 23: 329-343.
24. Landing, W.M., W.C. Burnett, B. Lyons and W.H. Orem, 1991. Nutrient cycling and the biogeo-chemistry of manganese, iron and zinc in Jellyfish Lake, Palau. Limnol. Oceanogr., 36: 515-525.
25. Lewis, B. L. and W.H. Landing, 1991. The biogeochemistry of Mn and Fe in the Black Sea. Deep Sea Res., 38(Suppl. 2): S773-S803.
26. Luther III, G.W. and T.G. Ferdelman, 1993. Voltammetric characterization of iron (II) sulfide complexes in laboratory solutions and in marine waters and porewaters. Environ. Sci. Technol. 27: 1154-1163.
27. 2+ by voltammetric methods". Environ. Sci. Technol., 30: 3640-3641.
28. 2+ by voltammetric methods. Env. Sci. Technol., 30: 671-679.
29. Macalady, D.L. Granland, C. P., Granlund, J.G. and Verracke, S.L., 1982. On the presence of iron (II) in oxygenated surface waters; analytical implications. Water Res., 16, pp 1277-1283.
30. Millero F.J. and D.R. Schreiber, 1982. Use of the ion pairing model to estimate activity coefficients of the ionic components of natural waters. Am. J. Sci., 282: 1508-1540.
31. Morse, J.W., F.J. Millero, J.C. Cornwell and D. Rickard, 1987. The chemistry of the hydrogen sulfide and iron sulfide systems in natural waters. Earth-Sci. 24: 1-42.
32. Olshanskii, Ya.I. and V.V. Ivanenko, 1958. Mechanism of mass transfer in the formation of hydrothermal deposits of sulphides. Tr. Inst. Geol. rudn. Mestorosh. 16: 14-46.
33. Rickard, D., 1989. Experimental concentration-time curves for the iron (II. sulphide precipitation process in aqueous solutions and their interpretation. Chem. Geol. 78: 315-324.
34. Rickard D.W., 1996. Fast pyrite formation. In fourth International Symposium on the Geochemistry of the Earth's Surface (Ed. S.H. Bottrell), University of Leeds.
35. Stumm, W and J.J. Morgan, 1996. Aquatic Chemistry, 3rd ed., Wiley, New York.
36. Thompson, R.A. and G.R. Helz, 1994. Copper speciation in sulfidic solutions at low sulfur activity: further evidence for cluster complexes? Geochim. Cosmochim. Acta 58: 2971-2983.
37. Yao, W. and F. J. Millero, 1995. The chemistry of the anoxic waters in the Framvaren Fjord, Norway. Aquat. Geochem., 1: 53-88.
38. Zhang, J.Z. and F.J. Millero, 1994. Investigation of metal sulfide complexes in seawater using cathodic stripping square wave voltammetry. Anal. Chim. Acta, 284: 497-504.