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Volumn 5, Issue 6, 1999, Pages 1766-1774

Preparation and crystal structures of manganese, iron, and cobalt complexes of the bis[di(2-pyridyl)methyl]amine (bdpma) ligand and its oxidative degradation product 1,3,3-tris(2-pyridyl)-3H-imidazo[1,5-a]-pyridin-4-ium (tpip); origin of the bdpma fragility

Author keywords

Cobalt; Iron manganese; N ligands; Oxidative degradation

Indexed keywords

1,3,3 TRIS(2 PYRIDYL) 3H IMIDAZO[1,5 A] PYRIDIN 4 IUM; BIS(DI 2 PYRIDYLMETHYL)AMINE; COBALT COMPLEX; IRON COMPLEX; MANGANESE DERIVATIVE; PYRIDINE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 0033022336     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3765(19990604)5:6<1766::aid-chem1766>3.0.co;2-z     Document Type: Article
Times cited : (52)

References (32)
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    • (1995) Angew. Chem. Int. Ed. Engl. , vol.34 , pp. 2671
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    • T. Funabiki, T. Yamazaki, A. Fukui, T. Tanaka, S. Yoshida, Angew. Chem. 1998, 110, 527; Angew. Chem. Int. Ed. 1998, 37, 513.
    • (1998) Angew. Chem. Int. Ed. , vol.37 , pp. 513
  • 13
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    • a) M. Lubben, A. Meetsma, E. C. Wilkinson, B. L. Feringa, L. Que, Jr., Angew. Chem. 1995, 107, 1610; Angew. Chem. Int. Ed. Engl. 1995, 34, 1512;
    • (1995) Angew. Chem. Int. Ed. Engl. , vol.34 , pp. 1512
  • 26
    • 0346290374 scopus 로고    scopus 로고
    • note
    • II complex 1 could be isolated (Scheme 2) and no ligand degradation was detected.
  • 27
    • 0348181018 scopus 로고    scopus 로고
    • note
    • This protonated species may be generated directly from the bdpma ligand by abstraction of 2 electrons and 1 proton. As tpip has been synthesized from the imine, the formula of the neutral form with subsequent protonation is the preferred presentation in Scheme 5.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.