Kinetics and mechanism of the oxidation of [Fe(CN)6]4- to [Fe(CN)6]3-, induced by the reaction between Cu2+ and I- in aqueous solution. Oxidation reaction by a radical anion I2-·

Bulletin of the Chemical Society of Japan

Volumn 72, Issue 6, 1999, Pages 1293-1299

  Kimura, Masaru ^a   Shiota, Yuko ^a   Kishi, Shinobu ^a   Tsukahara, Keiichi ^a  

^a NARA WOMEN'S UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER ION; FERROCYANIDE; IODIDE ION; IODINE;

AQUEOUS SOLUTION; ARTICLE; CONCENTRATION (PARAMETERS); EQUILIBRIUM CONSTANT; INHIBITION KINETICS; ION EXCHANGE; OSCILLATION; OXIDATION; OXIDATION REDUCTION POTENTIAL; PH; REACTION ANALYSIS; STEADY STATE; STOICHIOMETRY;

EID: 0032991758     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.72.1293     Document Type: Article

References (15)

1. M. Kimura, Y. Shiga, and K. Tsukahara, Bull. Chem. Soc. Jpn., 71, 2345 (1998).
2. M. Kimura, R. Ikawa, Y. Shiota, and K. Tsukahara, Bull. Chem. Soc. Jpn., 71, 893 (1998).
3. M. F. Ruasse, J. Aubard, B. Gallard, and A. Adenier, J. Phys. Chem., 90, 4382 (1986).
4. A. D. Awtrey and R. E. Connick, J. Am. Chem. Soc., 73, 1842 (1986).
5. M. Kimura, H. Ishiguro, and K. Tsukahara, J. Phys. Chem., 94, 4106 (1990).
6. M. Kimura, M. Sato, T. Murase, and K. Tsukahara, Bull. Chem. Soc. Jpn., 66, 2900 (1993).
7. M. Kimura, A. Ohomura, F. Nakazawa, and K. Tsukahara, Bull. Chem. Soc. Jpn., 64, 1872 (1991).
8. M. Kimura, F. Nakazawa, and K. Tsukahara, Bull. Chem. Soc. Jpn., 65, 1812 (1992).
9. L. I. Grossweiner and M. S. Matheson, J. Phys. Chem., 61, 1089 (1959).
10. W. M. Latimer, "The Oxidation States of the Elements and Their Potentials in Aqueous Solutions," 2nd ed, Prentice-Hall, New York (1952).
11. A. Barkatt and M. Ottolenghi, Mol. Photochem., 6, 253 (1974).
12. A. Haim and H. Taube, J. Am. Chem. Soc., 85, 495 (1963).
13. W. H. Woodruff and D. W. Margerum, Inorg. Chem., 12, 962 (1973).
14. W. L. Reynolds, J. Am. Chem. Soc., 80, 1830 (1958).
15. "Kagaku Binran, Kisohen II," (in Japanese), ed by Chemical Society of Japan, Maruzen, Tokyo (1984), p. 473.