Reversible stretching of a polymer-supported cobalt-chelate film in response to oxygen

Bulletin of the Chemical Society of Japan

Volumn 72, Issue 5, 1999, Pages 1123-1127

  Nishide, Hiroyuki ^b   Mizuma, Hiroyuki ^b   Tsuchida, Eishun ^b   McBreen, James ^a  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

^b WASEDA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPLEX; N,N' DI(SALICYLIDENE)ETHYLENEDIAMINATOCOBALT(II); OXYGEN; POLYMER; UNCLASSIFIED DRUG;

ARTICLE; CHELATION; INFRARED SPECTROSCOPY; OXIDATION; POLYMERIZATION; STRETCHING; X RAY ANALYSIS;

EID: 0032983288     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.72.1123     Document Type: Article

References (23)

1. a) P. Pfeiffer, E. Breith, E. Lube, and T. Tsumaki, Justus Liebigs Ann. Chem., 503, 84 (1933);
2. b) T. Tsumaki, Bull. Chem. Soc. Jpn., 13, 252 (1938).
3. a) M. Calvin, R. H. Bailes, and W. K. Wilmarth, J. Am. Chem. Soc., 68, 2254 (1946);
4. b) M. Calvin and C. H. Barklew, J. Am. Chem. Soc., 68, 2267 (1946);
5. c) A. E. Martell and M. Calvin, "Chemistry of the Metal Chelate Compounds," Prentice-Hall Inc., New York (1952), pp. 336-357.
6. a) E. Tsuchida and H. Nishide, Adv. Polym. Sci., 24, 1 (1977);
7. b) E. Tsuchida, "Macromolecular Complexes," VCH Publishers, New York (1991);
8. c) N. Toshima, "Polymers for Gas Separation," VCH Publishers, New York (1992);
9. d) F. Ciardelli, E. Tsuchida, and D. Wöhrle, "Macromolecule-Metal Complexes," Springer Verlag, Heidelberg (1995).
10. a) M. L. Hitchman, "Measurement of Dissolved Oxygen," John Wiley, New York (1978);
11. b) Z. Zhujun and W. R. Seitz, Anal. Chem., 58, 220 (1986);
12. c) F. Klauer and E. Turowski, Angew. Chem., 54, 494 (1941);
13. d) I. Bergmann, Nature, 218, 396 (1968).
14. a) A. Wasserman, "Size and Shape Changes of Contractile Polymers," Pergamon Press, Oxford (1960);
15. b) Y. Osada, J.P. Gong, and Y. Tanaka, "Polymer Gels," in "Funct. Monomers Polym.," 2nd ed, ed by K. Takemoto, R. M. Ottenbrite, and M. Kamachi, Marcel Dekker, New York (1997), pp. 497-528.
16. J. McBreen and I. C. Lin, Electrochem. Soc., 139, 960 (1992).
17. M. Vaarkamp, J. C. Linders, and D. C. Koningsberger, Physica B, B208 &209, 159 (1995).
18. J. J. Rehr, J. Mustrede Leon, S.I. Zabinsky, and R. C. Albers, J. Am. Chem. Soc., 113, 5135 (1991).
19. K. Ueno and A. E. Martell, J. Phys. Chem., 60, 1270 (1956).
20. Reversible oxygen-binding to the [Co(salen)] fixed in the film was measured by near-IR reflectance spectroscopy. The spectrum in the absence of oxygen gave the absorption peak at 1190 nm which has been ascribed to Co(II)(salen). (Ref.: C. Busetto, F. Cariati, A. Fusi, M. Gullotti, F. Morazzoni, A. Pasini, R. Ugo, and V. Valenti, J. Chem. Soc., Dalton Trans., 1973, 754.) After exposure of the film to oxygen, the [Co(salen)] turned black and the overall absorption in the visible and near-IR region increased; this deoxyoxy-spectral change was reversible and responded to oxygen.
21. H. Nishide, E. Soda, H. Mizuma, and E. Tsuchida, Macromol. Symp., 105, 191 (1996).
22. 0 = 1.0).
23. The plate-like single crystal was obtained from 0.35 wt% chloroform solution of [Co(salen)] in the absolutely absence of oxygen and was analyzed using a Rigaku AFC-5R four-circle diffractometer. The crystal packing structure showed that four deoxy-[Co(salen)] molecules existed in a unit cell and a solvated chloroform molecule was attached to each [Co(salen)], as has been reported by Schaffer and Marsh: W. P. Schaffer and R. E. Marsh, Acta Crystallogr., Sect. B, B25, 1675 (1969).