Exponential saturator: A novel gas-liquid partitioning technique for measurement of large limiting activity coefficients

Industrial and Engineering Chemistry Research

Volumn 38, Issue 5, 1999, Pages 2036-2043

  Dohnal, Vladimír ^a   Hovorka, Štěpán ^a  

^a INSTITUTE OF CHEMICAL TECHNOLOGY   (Czech Republic)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROPHOBICITY; SATURATION (MATERIALS COMPOSITION); SOLVENTS; WATER;

ACTIVITY COEFFICIENTS; EXPONENTIAL SATURATOR; HENRY'S LAW;

PHASE EQUILIBRIA;

AROMATIC HYDROCARBON; HALOGENATED HYDROCARBON; OXYGEN; SOLVENT; WATER;

INERT GAS; SATURATION; SOLVENT; VAPOR;

AQUEOUS SOLUTION; ARTICLE; GAS; GAS CHROMATOGRAPHY; GAS FLOW; HYDROPHOBICITY; LIQUID; MATHEMATICAL ANALYSIS; PARTITION COEFFICIENT; REPRODUCIBILITY; TEMPERATURE; VAPOR;

EID: 0032948592     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie980743h     Document Type: Article

References (33)

1. Cruickshank, A. J. B.; Windsor, M. L.; Young, C. L. The Use of Gas Liquid Chromatography to Determine Activity Coefficients and Second Virial Coefficients of Mixtures. Proc. R. Soc. London, Ser. A. 1966, 295, 259-270.
2. Orbey, H.; Sandler, S. I. Relative Measurements of Activity Coefficients at Infinite Dilution by Gas Chromatography. Ind. Eng. Chem. Res. 1991, 30, 2006-2011.
3. Eckert, C. A.; Newman, B. A.; Nicolaides, G. L.; Long, T. C. Measurement and Application of Limiting Activity Coefficients. AIChE J. 1981, 27, 33-40.
4. Dohnal, V.; Novotná, M. Infinite-Dilution Activity Coefficients by Comparative Ebulliometry: The Mixtures of Freon 112 with Oxygenated Solvents and Hydrocarbons. Fluid Phase Equilib. 1985, 23, 303-313.
5. Andon, R. J. L.; Cox, J. D.; Herington, E. F. G. The Thermodynamic Properties of Dilute Solutions of Pyridine Bases in Water. Discuss. Faraday Soc. 1953, 15, 168-174.
6. Dohnal, V.; Fenclová, D. Air-Water Partitioning and Aqueous Solubility of Phenols. J. Chem. Eng. Data 1995, 40, 478-483.
7. Tucker, E. E.; Lane, E. H.; Christian, S. D. Vapor Pressure Studies of Hydrophobic Interactions. Formation of Benzene-Benzene and Cyclohexane-Cyclohexanol Dimers in Dilute Aqueous Solution. J. Solution Chem. 1981, 10, 1-20.
8. Hutchings, R. S.; Van Hook, W. A. A New Continuous Dilution Vapor-Liquid Equilibrium Apparatus. The Activity Coefficients of Benzene and Water in Cyclohexane at 50 C. J. Solution Chem. 1985, 14, 13-26.
9. Leroi, J.-C.; Masson, J.-C.; Renon, H.; Fabrics, J.-F.; Sannier, H. Accurate Measurements of Activity Coefficients at Infinite Dilution by Inert Gas Stripping and Gas Chromatography. Ind. Eng. Chem. Process Des. Dev. 1977, 16, 139-144.
10. Hovorka, Š.; Dohnal, V. Determination of Air-Water Partitioning of Volatile Halogenated Hydrocarbons by the Inert Gas Stripping Method. J. Chem. Eng. Data 1997, 42, 924-933.
11. Hussam, A.; Carr, P. W. Rapid and Precise Method for the Measurement of Vapor/Liquid Equilibria by Headspace Gas Chromatography. Anal. Chem. 1986, 57, 793-801.
12. Dohnal, V.; Horáková, I. A New Variant of the Rayleigh Distillation Method for the Determination of Limiting Activity Coefficients. Fluid Phase Equilib. 1991, 68, 173-185.
13. Tsonopoulos, C.; Prausnitz, J. M. Activity Coefficients of Aromatic Solutes in Dilute Aqueous Solutions. Ind. Eng. Chem. Fundam. 1971, 10, 593-600.
14. Duhem, P.; Vidal, J. Extension of the Dilutor Method to Measurement of High Activity Coefficients at Infinite Dilution. Fluid Phase Equilib. 1978, 2, 231-235.
15. Vrbka, P.; Dohnal, V. Infinite-Dilution Activity Coefficients by the Inert Gas Stripping Method: Saturated Hydrocarbons in N,N-Dimethylformamide. Z. Phys. Chem. 1998, in press.
16. Li, J.; Dallas, A. J.; Eikens, D. I.; Carr, P. W.; Bergmann, D. L.; Hait, M. J.; Eckert, C. A. Measurement of Large Infinite Dilution Activity Coefficients of Nonelectrolytes in Water by Inert Gas Stripping and Gas Chromatography. Anal. Chem. 1993, 65, 3212-3218.
17. Shaw, D. G.; Haulait-Pirson, M.-C.; Hefter, G. T.; Maczynski, A.; Kapuku, F.; Kleinschmidt, M.; Mackay, D.; Maczynska, Z.; Miyamoto, H.; Shiu, W. Y.; Szafranski, A.; Tsonopoulos, C.; Young, C. L. IUPAC Solubility Data Series: Hydrocarbons with Water and Seawater, Part I: Hydrocarbons C5 to C7; Pergamon Press: Oxford, 1989.
18. CDATA-Database of Thermodynamic and Transport Properties for Chemistry and Engineering; Department of Physical Chemistry, Institute of Chemical Technology: Prague, 1991. Distributed by FIZ Chemie GmbH, Berlin.
19. Dykyj, J.; Repáě, M. Tlak nasýtenej pary organických zlúčenín; Veda: Bratislava, 1979.
20. Das, A.; Frenkel, M.; Gadalla, N. M.; Marsh, K. N.; Wilhoit, R. C. TRC Thermodynamic Tables; Thermodynamics Research Center, Texas Engineering Experiment Station, The Texas A&M University: 1994.
21. Roháč, V. Thesis, Institute of Chemical Technology, Prague, 1996.
22. Delcros, S.; Grolier, J.-P. E.; Dohnal, V.; Fenclová, D. Infinite-Dilution Activity Coefficients by Comparative Ebulliometry: Measurements and Group Contribution Calculations for Some Binary Mixtures Ether + n-Alkane and Ether + Alcohol. Chem. Eng. Sci. 1995, 50, 2957-2962.
23. Bao, J.; Huang, Q.; Chen, G.; Han, S. Determination of Large Value Activity Coefficients at Infinite Dilution. Wuli Huaxue Xuebao (Acta Phys.-chem. Sinica) 1993, 9, 724-727.
24. Srivastava, R. Experimental Measurement of Phase Equilibria in Dilute Solutions. Fluid Phase Equilib. 1989, 52, 201-208.
25. Shaw, D. G.; Haulait-Pirson, M.-C.; Hefter, G. T.; Maczynski, A.; Huyskens, P.; Kapuku, F.; Klienschmidt, M.; Mackay, D.; Maczynska, Z.; Meyers, P. A.; Shi, W. Y.; Szafranski, A.; Young, C. L. IUPAC Solubility Data Series: Hydrocarbons with Water and Seawater, Part II: Hydrocarbons C8 to C36; Pergamon Press: Oxford, 1989.
26. Sorensen, J. M.; Arlt, W. Liquid-Liquid Equilibrium Data Colection; DECHEMA Chemistry Data Series; Frankfurt/Main, 1979; Vol. V.
27. Barr, R. S.; Newsham, D. M. T. Phase Equilibria in Very Dilute Mixtures of Water and Chlorinated Hydrocarbons. Part I. Experimental Results. Fluid Phase Equilib. 1987, 35, 189-205.
28. Wright, D. A.; Sandler, S. I.; De Voll, D. Infinite Dilution Activity Coefficients and Solubilities of Halogenated Hydrocarbons in Water at Ambient Temperatures. Environ. Sci. Technol. 1992, 26, 1828-1831.
29. Horvath, A. L. Halogenated Hydrocarbons. Solubility-Miscibility with Water; Marcel Dekker, Inc.: New York, 1982.
30. Tse, G.; Orbey, H.; Sandler, S. I. Infinite Dilution Activity Coefficients and Henry's Law Coefficients of Some Priority Water Pollutants Determined by a Relative Gas Chromatographic Method. Environ. Sci. Technol. 1992, 26, 2017-2022.
31. Cooling, M. R.; Khalfaoui, B.; Newsham, D. M. T. Phase Equilibria in Very Dilute Mixtures of Water and Unsaturated Chlorinated Hydrocarbons and of Water and Benzene. Fluid Phase Equilib. 1992, 81, 217-229.
32. Horvath, A. L.; Getzen, F. W.; Jancso, G.; Ohtaki, H.; Lonnberg, H.; Vesala, A. O. IUPAC Solubility Data Series: Halogenated Benzenes, Toluenes and Phenols with Water; Pergamon Press: Oxford, 1985.
33. Nielsen, F.; Olsen, E.; Fredenslund, A. Henry's Law Constants and Infinite-Dilution Activity Coefficients for Volatile Organic Compounds in Water by Validated Batch Air Stripping Method. Environ. Sci. Technol. 1994, 28, 2133-2138.