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Volumn 283, Issue 5398, 1999, Pages 57-60

Electrochemical principles of active control of liquids on submillimeter scales

Author keywords

[No Author keywords available]

Indexed keywords

DROP FORMATION; ELECTROCHEMICAL ELECTRODES; ELECTROCHEMISTRY; FILMS; FLOW OF FLUIDS; MOLECULES; OSMOSIS; REDOX REACTIONS; SOLIDS; SURFACE ACTIVE AGENTS; SURFACE TENSION; SURFACES;

EID: 0032902347     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.283.5398.57     Document Type: Article
Times cited : (433)

References (42)
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    • We have also observed rapid, redox-induced spreading of micrometer-thick films of liquid across surfaces, thus demonstrating that rapid displacement of liquids across micrometer-thick films under surface pressure gradients induced by redox-active surfactants are possible.
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    • See also Fig. 5
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    • Current passed at the anode was less than 100 μA or ∼1 nmol of electrons per second. The velocity of migration of ions through the bulk of the 0.01 M solution of electrolyte was estimated to be <10 μm/s. We have also observed electrochemically induced Marangoni phenomena with concentrations of electrolyte of 0.1 M.
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    • Application of potentials greater than 0.5 V did not give rise to velocities of fluid motion greater than ∼4 mm/s. At these overpotentials, the rate-limiting step is likely to be mass transport to the electrodes (11).
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    • Advancing and receding contact angles of aqueous solutions used in our experiments were measured to be the same on surfaces of treated gold and glass (see Fig. 5).
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    • We used gravity to drain the film of liquid from the surface; other procedures, such as spin coating, can also be used to prepare a thin film of liquid.
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    • The direction of dewetting of the liquid was not governed by gravity. For example, we electrochemically induced motion of a contact line up an inclined surface. The motion of the contact line was typically initiated near the wire that connected the array of electrodes to the external circuit. This result suggests that the direction of dewetting is likely influenced by electric fields created by the applied external potential.
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    • note
    • Whereas the columns of liquid shown in Fig. 3 were permanent, the arrays of square droplets shown in Fig. 4 persisted for ∼1 min before respreading across the electrodes. Unlike the columns, the square droplets become electrically isolated from the counter electrode after formation. Electrical contact with droplets could, however, be maintained by patterning counter electrodes on surfaces. Arrays of droplets formed in this way would be permanent, as evidenced by the permanency of the liquid columns.
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    • Past studies of the patterning of aqueous solutions on surfaces have relied on the fabrication of surfaces that have hydrophilic and hydrophobic regions [N. L. Abbott, J. P. Folkers, G. M. Whitesides, Science 257, 1380 (1992)] or regions that can be transformed electrochemically from hydrophobic to hydrophilic [N. L. Abbott, C. B. Gorman, G. M. Whitesides, Langmuir 11, 16 (1995); C. B. Gorman, H. A. Biebuyck, G. M. Whitesides, ibid., p. 2242]. The surfaces we used were not patterned with hydrophobic and hydrophilic regions.
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    • Past studies of the patterning of aqueous solutions on surfaces have relied on the fabrication of surfaces that have hydrophilic and hydrophobic regions [N. L. Abbott, J. P. Folkers, G. M. Whitesides, Science 257, 1380 (1992)] or regions that can be transformed electrochemically from hydrophobic to hydrophilic [N. L. Abbott, C. B. Gorman, G. M. Whitesides, Langmuir 11, 16 (1995); C. B. Gorman, H. A. Biebuyck, G. M. Whitesides, ibid., p. 2242]. The surfaces we used were not patterned with hydrophobic and hydrophilic regions.
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    • Past studies of the patterning of aqueous solutions on surfaces have relied on the fabrication of surfaces that have hydrophilic and hydrophobic regions [N. L. Abbott, J. P. Folkers, G. M. Whitesides, Science 257, 1380 (1992)] or regions that can be transformed electrochemically from hydrophobic to hydrophilic [N. L. Abbott, C. B. Gorman, G. M. Whitesides, Langmuir 11, 16 (1995); C. B. Gorman, H. A. Biebuyck, G. M. Whitesides, ibid., p. 2242]. The surfaces we used were not patterned with hydrophobic and hydrophilic regions.
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    • We individually addressed electrodes of the array shown in Fig. 3. The liquid only dewet the electrodes to which potentials were applied.
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    • 2+ within the film of liquid (as evidenced by the eventual respreading of drops in Fig. 4) and finite kinetics or adsorption-desorption of surfactant from the interfaces of the liquid film [H. Diamant and D. Andelman, J. Phys. Chem. 100, 13732 (1996)].
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    • note
    • We have demonstrated patterned dewetting on surfaces with electrodes as small as 30 μm.
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    • note
    • We observed the velocity of the contact line to vary between 0.5 and 1.0 mm/s from one experiment to the next. The variation in the velocity of the contact line likely reflects variations in the thicknesses of the liquid films.
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    • note
    • Partial support of this work was provided by the Camille and Henry Dreyfus Foundation, the David and Lucile Packard Foundation, the Donors of the Petroleum Research Fund, and the NSF (grants CTS-9410147 and CTS-9502263) and Office of Naval Research (PECASE award to N.L.A.). We thank A. Knoesen for helpful comments.


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