The effect of O2 and NO2 on the ring retaining products of the reaction of toluene with hydroxyl radicals

Atmospheric Environment

Volumn 33, Issue 1, 1998, Pages 111-116

  Moschonas, Nektarios ^a   Danalatos, Demetrios ^a   Glavas, Sotirios ^a  

^a UNIVERSITY OF PATRAS   (Greece)

Author keywords

2 methyl 1,4 benzoquinone; Benzaldehyde; Benzylalcohol; Intermediate:toluene oxide; m + p cresol; o ; Phenol and benzene

Indexed keywords

AROMATIC HYDROCARBONS; BENZENE; NITROGEN OXIDES; PHENOLS;

BENZALDEHYDE; BENZYLALCOHOL; HYDROXYL RADICALS; TOLUENE OXIDE;

TOLUENE;

BENZENE; HYDROXYL RADICAL; META CRESOL; NITROGEN DIOXIDE; ORTHO CRESOL; OXYGEN; PARA CRESOL; PHENOL; TOLUENE;

ATMOSPHERIC CHEMISTRY; HYDROXYL RADICAL; TOLUENE;

ARTICLE; CHEMICAL COMPOSITION; DEGRADATION; EXHAUST GAS; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 0032890198     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1352-2310(98)00134-4     Document Type: Article

References (18)

1. Atkinson, R., 1994. Gas phase tropospheric chemistry of organic compounds, Journal of Physical and Chemical Reference Data, Monograph 2.
2. 2 concentration. International Journal of Chemical Kinetics 26, 929-944.
3. x-air photooxidation of toluene and the cresols. International Journal of Chemical Kinetics 12, 779-836.
4. 8 n-alkanes. Journal of Physical Chemistry 86, 4563-4569.
5. 2 photooxidation of selected aromatic hydrocarbons. Journal of Physical Chemistry 87, 1605-1610.
6. Atkinson, R., Aschmann, S.M., Arey, J., Carter, W.P.L., 1989. Formation of ring retaining products from the OH radical initiated reactions of benzene and toluene. International Journal of Chemical Kinetics 21, 801-827.
7. Bartolotti, L.J., Edney, E.O., 1995. Density functional theory derived intermediates from the OH initiated atmospheric oxidation of toluene. Chemical Physics Letters 245, 119-122.
8. Bierbach, A., Barnes, I., Becker, K.H., Klotz, B., Wiesen, E., 1993. OH radical initiated degradation of aromatic hydrocarbons, Sixth European Symposium on Physico-Chemical Behaviour of Atmospheric Pollutants, Vol. 1, pp. 129-136. Report EUR 15609/1 EN, Luxembourg.
9. Gery, M.W., Fox, D.L., Jeffries, H.E., Stockburger, L., Weathers, W.S., 1985. A continuous stirred tank reactor investigation of the gas phase reaction of hydroxyl radicals and toluene. International Journal of Chemical Kinetics 17, 931-955.
10. Hoshino, M., Akimoto, H., Okuda, M., 1978. Photochemical oxidation of benzene, toluene and ethylbenzene initiated by OH radicals in the gas phase. Bulletin of the Chemical Society of Japan 51, 718-724.
11. Kenley, R.A., Davenport, J.E., Hendry, D.G., 1981. Gas phase hydroxyl radical reactions. Products and pathways for the reaction of OH with aromatic hydrocarbons. Journal of Physical Chemistry 85, 2740-2746.
12. Klotz, B., Barnes, I., Becker, K.H., Golding, B.T., 1997. Atmospheric chemistry of benzene oxide/oxepin. Journal of the Chemical Society Faraday Transactions 93(8), 1507-1516.
13. 2. Berichte Bunsengeselschaft Physikalische Chemie 94, 1375-1379.
14. Koch, R., Knispel, R., Siese, R., Zetzsch, C., 1993. Absolute rate constants and products of secondary steps in the atmospheric degradation of aromatics. Sixth European Symposium on Physico-Chemical Behaviour of Atmospheric Pollutants, Vol. 1, pp. 143-149. Report EUR 15609/1 EN, Luxembourg.
15. x. Air Pollution Research Report 54, pp. 263-266. Report EUR 16171 EN, Luxembourg.
16. x free air: product distribution and mechanism. International Journal of Chemical Kinetics 28, 315-332.
17. Siese, M., Koch, R., Fittchen, C., Zetzsch, C., 1994. In: Borell, P.M., Borell, P., Cvitas, T., Seiler, W. (Eds.), Transport and Transformation of Pollutants in the Troposphere. Academic Publishing, The Hague, Netherlands, pp. 115-118.
18. Yu, J., Jeffries, H.E., Sexton, K.G., 1997. Atmospheric photooxidation of alkylbenzenes-I. Carbonyl product analyses. Atmospheric Environment 31, 2261-2280.