Preparation and reactivity of some functionalized halomethylzinc carbenoids

Tetrahedron Letters

Volumn 40, Issue 1, 1999, Pages 33-36

  Charette, André B ^a   Beauchemin, André ^a   Marcoux, Jean François ^a  

^a UNIVERSITÉ DE MONTRÉAL   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; HALOGEN; IODIDE; REAGENT; ZINC DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; ENANTIOMER; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY;

EID: 0032889887     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)80012-9     Document Type: Article

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24. In this case, the reaction mixture had to be irradiated in order to push the metal-halogen exchange process between the mixed diorganozinc and chloroiodomethane to completion: (a) Miyano, S.; Yamashita, J.; Hashimoto, H. Bull. Chem. Soc. Jpn. 1972, 45, 1946.
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26. 1H NMR, quenched and analyzed by GC.