Dynamic electrochemical assessment of redox reactions in natural micas between 613 and 1373 K at 105 Pa

American Mineralogist

Volumn 84, Issue 4, 1999, Pages 493-505

  Burkhard, Dorothee J M ^a   Ulmer, Gene C ^b   Redhammer, Günther ^c,d   Myer, George H ^b  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

^b TEMPLE UNIVERSITY   (United States)

^c UNIVERSITY OF SALZBURG   (Austria)

^d RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

DIFFERENTIAL THERMAL ANALYSIS; MICA; ZIRCONIA;

ARGON ATMOSPHERES; DEHYDROXYLATIONS; DYNAMIC TECHNIQUES; DYNAMIC TRACKING; ELECTROCHEMICAL METHODS; EMF MEASUREMENT; NEW APPLICATIONS; THREE TEMPERATURE;

REDOX REACTIONS;

BIOTITE; ELECTROCHEMISTRY; EXPERIMENTAL MINERALOGY; MICA; REDOX POTENTIAL;

EID: 0032870353     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-1999-0403     Document Type: Article

References (61)

1. Annersten, H. (1974) Mössbauer studies of natural biotites. American Mineralogist, 59, 143-151.
2. 2, Physics Status Solidi (b) 48, K137-K138.
3. Arculus, R.J. and Delano, J.W. (1980) Implications for the primative atmosphere of the oxidation state of earth's upper mantle. Nature, 288, 72-74.
4. 2 oxygen sensors. In N. Claussen, M. Rühle, and A. Heuer, Eds., Advances in Ceramics, 12, Science and technology of zirconia II, 598-606. The American Ceramic Society, Columbus, Ohio.
5. Bagin, V.I., Gendler, T.S., Dainyak, L.G., and Kuz'min, R.N. (1980) Mössbauer, thermo-gravimetric, and X-ray study of cation ordering and high-temperature decomposition in biotite. Clays and Clay Minerals, 28, 188-196.
6. 2, on metal surfaces. Detection of an intrinsic precursor dissociation. In M. Grunze and H. Kreuzer, Eds., Kinetics of Interface Reaction, p. 164-174. Springer Series in Surface Sciences, Berlin.
7. 2, Pd hydrides, and Ir oxides. In G.C. Ulmer and H.L. Barnes, Eds., Hydrothermal Experimental Techniques, p. 157-188. Wiley-Interscience Publications, New York.
8. Burkhard, D.J.M. (1993) Biotite crystallization temperatures and redox states in granitic rocks as indicator for tectonic setting. Geologie en Mijnbouw, 79, 337-349.
9. Burkhard, D.J.M. and Ulmer, G.C. (1995a) Kinetics and equilibria of redox systems at temperatures as low as 300°C. Geochimica et Cosmochimica Acta, 59, 1699-1714.
10. _(1995b) Dynamic tracking of mica breakdown reactions by electrochemical measurements. Physics and Chemistry of Minerals, 22, 507-510.
11. 2, oxygen sensors: an evaluation of behavior at temperatures as low as 300°C. Solid State Ionics, 48, 333-339.
12. Claussen, N., Rühle, M., and Heuer, A. (1984) Advances in Ceramic Sciences and technology of zirconia II, 842 p. The American Ceramic Society, Columbus, Ohio.
13. H2 -sensor technique. American Mineralogist, 81, 475-484.
14. Deines, P., Nafziger, R.H., Ulmer, G.C., and Woermann, E. (1974) Temperature-oxygen fugacity tables for selected gas mixtures in the system C-H-O at one atmosphere total pressure. Bulletin of the earth and mineral sciences experimental station. 88. Pennsylvania State University, Pennsylvania.
15. Dyar, M.D. (1990) Mössbauer spectra of biotites from metapelites. American Mineralogist, 75, 656-666.
16. 3+ and cation ordering. American Mineralogist, 72, 102-112.
17. Elliott, W.C., Grandstaff, D.E., Ulmer, G.C., Buntin, T.J., and Gold, D.P. (1982) An intrinsic oxygen fugacity study of platinum-carbon associations in layered intrusions. Economic Geology, 77, 209-226.
18. Ericson, T. and Wäppling, R. (1976) Texture effects in 3/2-1/2 Mössbauer spectra. Journal of Physics (Paris) 12-C6, 719-723.
19. Eugster, H.P. and Wones, D.R. (1962) Stability relations of the ferruginous biotite, annite. Journal of Petrology, 3, 82-125.
20. Farmer, V.C., Russell, J.D., and McHardy, W.J. (1971) Evidence for loss of protons and octahedral iron from oxidized biotites and vermiculites. Mineralogical Magazine, 38, 121-137.
21. Ferrow, E. (1987) Mössbauer and X-ray studies on the oxidation of annite and ferriannite. Physics and Chemistry of Minerals, 14, 270-275.
22. Friel, J. and Ulmer, G.C. (1974) Oxygen fugacity geometry of the Oka complex. American Mineralogist, 59, 314-318.
23. Hatch, R.A., Humphrey, R.A., Eitel, W., and Comeforo, J.E. (1957) Synthetic mica investigations IX: Review of progress from 1947 to 1955. Report investigations 5337, 79 p. U.S. Department of Interior, Bureau of Mines, Washington, D.C.
24. Huebner, S. (1987) The use of gas mixtures at low pressure to specify oxygen and other fugacities of furnace atmospheres. In G.C. Ulmer and H.L. Barnes, Eds., Hydrothermal experimental techniques, p. 20-60. Wiley-Interscience Publications, New York.
25. Huijsmans, J.P.P., van der Meulen, S.B., and Siewers, E.J. (1989) Membrane based thin-layered SOFC components. In G. With, R.A. Terpsta, and R. Metselaar, Eds., Euro-ceramics, vol. 3, 3626-3530. Elsevier, London.
26. Hogg, C.S. and Meads, R.E. (1975) A Mössbauer study of thermal decomposition of biotites. Mineralogical Magazine, 40, 79-88.
27. Knauth, L.P. and Epstein, S. (1982) The nature of water in hydrous silica. American Mineralogist, 67, 510-520.
28. Kozul, J., Ulmer, G.C., and Hewins, R.H. (1988) Intrinsic oxygen fugacity measurements of some Allende Type B inclusions. Geochimica et Cosmochimica Acta, 52, 2707-2716.
29. Lottermoser, W., Kaliba, P., and Forcher, K (1992) MOESALZ - A computer program for Mössbauer analyses; personal communication exchange software.
30. Mackenzie, R.C. (1957) Differential thermal analyses of clays. Central Press, Aberdeen, Scotland.
31. Mackenzie R.C., Ed. (1970) Differential thermal analysis, vol. 1. Academic Press, London.
32. 5 Pa from 1300 to 700°C. Geochimica et Cosmochimica Acta, 60, 2917-2920.
33. Muse, S. and Soejima, S. (1983) A method of producing oxide sensing ceramics. European Patent no. 0-345-824-Al granted to NGK Insulators, Ltd. and extended to Germany, France and England.
34. Niedrach, L.W. (1982) Use of a high temperature pH sensor as a "pseudo-reference electrode" in the monitoring of corrosion and redox potentials at 285°C. Journal of the Electrochemical Society, 212, 672-684.
35. 2 buffer. Contributions to Mineralogy and Petrology, 114, 296-314.
36. Ramberg, H. (1952) Chemical bonds and the distribution of cations in silicates. Journal of Geology, 60, 331-355.
37. Rancourt, D.G. (1994a) Mössbauer spectroscopy of minerals I. Inadequacy of Lorentzian-line doublets in fitting spectra arising from quadrupole splitting distributions. Physics and Chemistry of Minerals, 21, 244-249.
38. 2+ sites. Physics and Chemistry of Minerals, 21, 250-257.
39. mica +H. Oxidation reaction in bulk single-crystal biotite studied by Mössbauer spectroscopy. Physics and Chemistry of Minerals, 20, 276-284.
40. 2+ site populations in synthetic annite by Mössbauer spectroscopy. American Mineralogist, 79, 51-62.
41. 2+ quadrupole splitting distribution in the phlogopite-annite series. Physics and Chemistry of Minerals, 21, 258-267.
42. Redhammer, G.J., Beran, A., Dachs, E., and Amthauer, G. (1993) A Mössbauer and X-ray diffraction study of annites synthesized at different oxygen fugacities and crystal chemical implications. Physics and Chemistry of Minerals, 20, 382-394.
43. 2. Physics and Chemistry of Minerals, 22, 282-293.
44. Rimsaite, J. (1970) Structural formulae of oxidized and hydroxyl-deficient micas and decomposition of the hydroxyl group. Contributions to Mineralogy and Petrology, 25, 225-240.
45. Rinne, F. (1924) Bemerkungen über strukturchemische Silikatformeln und den kristallographisch-chemischen Ab-und Umbau von Glimmer durch Entwässerung, Oxidation und Reduktion. Akademische Wissenschaften Leipzig. Verhandlung, 76, 1-11.
46. Ross, G.J. and Rich, C.I. (1974) Effect of oxidation and reduction on potassium echange of biotite. Clays and Clay Minerals, 22, 355-360.
47. - in the octahedral sheet of phlogopites. American Mineralogist, 64, 119-126.
48. Sanz, J., Gonzalez-Carreno, T., and Gancedo, R. (1983) On dehydroxylation mechanisms of biotite in vacuo and in oxygen. Physics and Chemistry of Minerals, 9, 14-18.
49. Sato, M. (1965) Electrochemical geometry; a possible new method of geothermometry with electroconductive minerals. Economic Geology, 60, 812-818.
50. _(1971) Electrochemical measurements and control of oxygen fugacity and other gaseous fugacities with solid electrolyte sensors. In G.C. Ulmer, Ed., Research techniques for high pressure and high temperature, p. 43-99. Springer, New York.
51. _(1972) Intrinsic oxygen fugacities of iron-bearing oxide and silicate minerals under low total pressure. Geological Society of America, Memoir, 135, 279-306.
52. Sato, M. and Valenza, M. (1980) Oxygen fugacities of the layered series of the Skaergaard intursion, east greenland. American Journal of Science, 280A, 134-158.
53. Tripathi, R.P., Chandra, U., Chandra, R., and Lokanathan, S. (1978) A Mössbauer study of the effect of heating biotite, phlogopite and vermiculite. Journal of inorganic nuclear chemistry, 40, 1293-1298.
54. 2 oxygen and hydrogen sensors: a geologic perspective. In Advanced Ceramics 12, Science and Technology of Zirconia II, p. 660-671. American Ceramic Society.
55. Ulmer, G.C., Rosenhauer, M., Woermann, E., Ginder, J., Drory-Wolff, A., and Wasilewski, P. (1976) Applicability of electrochemical oxygen fugacity measurements to geothermometry. American Mineralogist, 61, 661-670.
56. Ulmer, G.C., Grandstaff, D.E., Weiss, D., Moats, M., Buntin, T.J., Gold, D.P., Hatton, C.J., Kadik, A., Koseluk, R.A., and Rosenhauer, M. (1987) The mantle redox state; an unfinished story? Geological Society of America, Special Papers, 215, 5-23.
57. Vedder, W. and Wilkins, R.W.T. (1969) Dehydroxylation and rehydroxylation, oxidation and reduction of micas. American Mineralogist, 54, 482-509.
58. Veith, J.A. and Jackson, M.L. (1974) Iron oxidation and reduction effects on structural hydroxyl and layer charge in aqueous suspensions of micaceous vermiculites. Clays and Clay Minerals, 22, 345-353.
59. 57Fe Mössbauer study of mantle-derived ilmenites. Geochimica et Cosmochimica Acta, 52, 1781-1794.
60. Wones, D.R. and Eugster, H.P. (1965) Stability of biotite: experiment, theory, and application. American Mineralogist, 50, 1228-1269.
61. Yoder, H.S. and Eugster, H.P. (1954) Phlogopite synthesis and stability range. Geochimica et Cosmochimica Acta, 6, 157-185.