Synthesis, structural characterization, electrochemistry, and reactivities of heptaosmium carbonyl clusters bearing thioxane ligands

European Journal of Inorganic Chemistry

Volumn , Issue 10, 1999, Pages 1757-1763

  Leung, Kelvin Sze Yin ^a   Wong, Wing Tak ^a  

^a UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

Cluster; Electrochemistry; Osmium

Indexed keywords

CARBON MONOXIDE; CHELATION; CHLORINE COMPOUNDS; LIGANDS; OSMIUM;

AIR STABLE; CARBONYL CLUSTERS; CATHODIC SHIFTS; CLUSTER; ELECTROCHEMICAL STUDIES; METAL SKELETONS; REDUCTION WAVE; STABLE CLUSTERS; STRUCTURAL CHARACTERIZATION; TETRAHEDRA;

ELECTROCHEMISTRY;

LIGAND; OSMIUM DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHEMOREACTIVITY; CRYSTAL STRUCTURE; ELECTROCHEMISTRY; ISOMER; MOLECULAR MODEL; STRUCTURE ACTIVITY RELATION; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0032861284     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (29)

1. [1a] D. F. Shriver, H. D. Kaesz, R. D. Adams, The Chemistry of Metal Cluster Complexes, VCH, New York, 1992.
2. [1b] G. Gonzale-Moraga, Cluster Chemistry, Springer-Verlag, Berlin, 1994.
3. C. R. Eady, B. F. G. Johnson, J. Lewis, J. Chem. Soc., Dalton Trans. 1975, 2606.
4. B. F. G. Johnson, J. Lewis, M. McPartlin, J. Morris, G. L. Powell, P. R. Raithy, M. D. Vargas, J. Chem. Soc., Chem. Commun. 1986, 429.
5. [4a] B. F. G. Johnson, J. Lewis, J. A. Lunniss, D. Braga, F. Grepioni, J. Chem. Soc., Chem. Commun. 1988, 972.
6. [4b] D. Braga, F. Grepioni, B. F. G. Johnson, J. Lewis, J. A. Lunniss, J. Chem. Soc., Dalton Trans. 1991, 2223.
7. D. Braga, F. Grepioni, B. F. G. Johnson, J. Lewis, J. A. Lunniss, J. Chem. Soc., Dalton Trans. 1992, 1101.
8. B. F. G. Johnson, J. Lewis, J. A. Lunniss, D. Braga, F. Grepioni, J. Organomet. Chem. 1991, 401, C46.
9. [7a] K. S.-Y. Leung, W-T. Wong, J. Chem. Soc., Dalton Trans. 1997, 4357.
10. [7b] K. S.-Y. Leung, W-T. Wong, J. Chem. Soc., Dalton Trans. 1998, 1939.
11. [8a] Y. -K. Au, K. -K. Cheung, W. -T. Wong, Inorg. Chim. Acta. 1995, 238, 193.
12. [8b] Y. -K Au, K. -K. Cheung, W. -T. Wong, J. Chem. Soc., Dalton Trans. 1995, 1047.
13. [8c] Y. -K Au, K. -K. Cheung, W. -T. Wong, Inorg. Chim. Acta. 1995, 225, 267.
14. C. R. Eady, B. F. G. Johnson, J. Lewis, R. Mason, P. B. Hitchcock, K. Thomas, J. Chem. Soc., Chem. Commun. 1977, 385.
15. J. Lewis, C. -K. Li, C. A. Morewood, M. C. R. de. Arellano, P. R. Raithby, W. -T. Wong, J. Chem. Soc., Dalton Trans. 1994, 2159.
16. S. M. Waterman, M. G. Humphrey, D. C. R. Hockless, Organometallics 1996, 15, 1745.
17. [12a] C. E. Housecroft, A. L. Rheingold, Organometallics 1987, 6, 1332.
18. [12b] C. E. Housecroft, A. L. Rheingold, P. Zanello, J. Organomet. Chem. 1991, 408, 7.
19. D. L. Sunick, P. S. White, C. K. Schauer, Inorg. Chem. 1993, 32, 5665.
20. C. E. Housecroft, M. S. Shongwe, A. L. Rheingold, Organometallics 1989, 8, 2651.
21. B. F. G. Johnson, J. Lewis, Adv. Inorg. Chem. Radiochem. 1981, 24, 225.
22. D. M. P. Mingos, J. Chem. Soc., Chem. Commun. 1983, 706.
23. R. D. Adams, D. F. Foust, P. Mathur, Organometallics 1983, 2, 990.
24. Y. C. Lin, C. B. Knobler, H. D. Kaesz, J. Organomet. Chem. 1981, 213, C41.
25. G. R. John, B. F. G. Johnson, J. Lewis, J. Organomet. Chem., 1979, 181, 143.
26. K. S.-Y. Leung, W.-T. Wong, J. Chem. Soc., Dalton Trans., submitted for publications.
27. D. D. Perrin, W. L. F. Armarego, Purification of Laboratory Chemicals, 3rd ed., Pergamon, Oxford, 1988.
28. SIR92, A. Altomare, M.C. Burla, M. Camalli, M. Cascarano, C. Giacovazzo, A. Guagliardi, G. Polidori, J. Appl. Crystallogr, 1994, 27, 435.
29. TEXSAN, Crystal Structure Analysis Package, Molecular Structure Corporation, Houston, TX, 1985 and 1992.